Recent Progress in the Chemistry of Metal Amidinates and Guanidinates. Syntheses, Catalysis and Materials

Advances in Organometallic Chemistry

Volumn 61, Issue , 2013, Pages 55-374

  Edelmann, Frank T ^a  

^a OTTO VON GUERICKE UNIVERSITY   (Germany)

Author keywords

Amidinates; Guanidinates; Heteroallylic ligands; Homogeneous catalysis; Materials science

Indexed keywords

EID: 84883798480     PISSN: 00653055     EISSN: None     Source Type: Book Series    
DOI: 10.1016/B978-0-12-407692-1.00002-3     Document Type: Chapter

References (432)

1. Sanger A.R. Reactions of benzonitrile with lithium amides. Inorg Nucl Chem Lett 1973, 9:351.
2. Boeré R.T., Oakley R.T., Reed R.W. Preparation of N, N, N'-tris(trimethylsilyl)amidines; a convenient route to unsubstituted amidines. J Organomet Chem 1987, 331:161.
3. Chandra G., Jenkins A.D., Lappert M.F., Srivastava R.C. Amido-derivatives of metals and metalloids. Part X. Reactions of titanium(IV), zirconium(IV), and hafnium(IV) amides with unsaturated substrates, and some related experiments with amides of boron, silicon, germanium, and tin(IV). J Chem Soc 1970, 2550.
4. Dehnicke K. Chem-Ztg 1990, 114:295. Earlier review articles: (a).
5. Barker J., Kilner M. The coordination chemistry of the amidine ligand. Coord Chem Rev 1994, 133:219.
6. Edelmann F.T. N-silylated benzamidines: versatile building blocks in main group and coordination chemistry. Coord Chem Rev 1994, 137:403.
7. Edelmann F.T. Rare earth complexes with heteroallylic ligands. Top Curr Chem 1996, 179:113.
8. Bailey P.J., Pace S. The coordination chemistry of guanidines and guanidinates. Coord Chem Rev 2001, 214:91.
9. Nagashima H., Kondo H., Hayashida T., et al. Chemistry of coordinatively unsaturated organoruthenium amidinates as entry to homogeneous catalysis. Coord Chem Rev 2003, 245:177.
10. Edelmann F.T. Advances in the coordination chemistry of amidinate and guanidinate ligands. Adv Organomet Chem 2008, 57:183.
11. Schareina T., Kempe R. Synth Meth Organomet Inorg Chem 2002, 1. (a).
12. Roesky P.W. Bulky amido ligands in rare earth chemistry-syntheses, structures, and catalysis. Z Anorg Allg Chem 2003, 629:1881. and references cited therein.
13. Coles M.P. Bicyclic-guanidines, -guanidinates and -guanidinium salts: wide ranging applications from a simple family of molecules. Chem Commun 2009, 3659.
14. Patmore N.J. Recent developments in the chemistry of metal-metal multiply bonded paddlewheel compounds. J Organomet Chem 2010, 36:77.
15. Lubben T.V., Wolczanski P.T., Van Duyne G.D. Preparation of Group 4B complexes containing tri-tert-butylmethoxide (tritox), a steric cyclopentadienyl equivalent. Organometallics 1984, 3:977.
16. Wedler M., Knösel F., Pieper U., Stalke D., Edelmann F.T., Amberger H.-D. Steric cyclopentadienyl equivalents in f-element chemistry: monomeric, homoleptic lanthanide(III) tris[N, N'-bis(trimethylsilyl)benzamidinates]. Chem Ber 1992, 125:2171.
17. 3UMe. Chem Ber 1992, 125:1313.
18. Hagen C., Reddmann H., Amberger H.-D., Edelmann F.T., Pegelow U., Shalimoff G.V., Edelstein N.M. Zur Elektronenstruktur metallorganischer Verbindungen der f-Elemente: XXXIV. Ist der N, N'-bis(trimethylsilyl)benzamidinato-Ligand im Falle von Lanthanoid-Zentralionen ein elektronisches Äquivalent zum η5-Cyclopentadienyl-Liganden?. J Organomet Chem 1993, 462:69.
19. Coles M.P. Application of neutral amidines and guanidines in coordination chemistry. Dalton Trans 2006, 985.
20. Franklin E.C. The ammono carbonic acids. J Am Chem Soc 1922, 44:486.
21. 4: the first structurally characterized salt of a new class of guanidinate compounds. Inorg Chem 2011, 50:3799.
22. 2. Z Naturforsch 2011, 66b:975.
23. Sawinski P.K., Dronskowski R. Solvothermal synthesis, crystal growth, and structure determination of sodium and potassium guanidinate. Inorg Chem 2012, 51:7425.
24. Chlupatý T., Padělková Z., Lyčka A., Růžička A. Structure and properties of lithium n-butyl amidinates. J Organomet Chem 2011, 696:2346.
25. Han H., Li W., Li H. Bis[μ(2)-1,1-(butane-1,4-diyl)-2,3-dicyclohexylguanidinato]bis-[(tetrahydrofuran)-lithium](Li-Li). Acta Crystallogr 2010, E66:m1579.
26. Aharonovich S., Kapon M., Botoshansky M., Eisen M.S. N, N'-Bis-silylated lithium aryl amidinates: synthesis, characterization, and the gradual transition of coordination mode from σ toward π originated by crystal packing interactions. Organometallics 1869, 2008:27.
27. Aharonovich S., Botoshansky M., Rabinovich Z., Waymouth R.M., Eisen M.S. Lithium furyl and pyridyl amidinates as building blocks in coordination polymers ladder and cage structures. Inorg Chem 2010, 49:1220.
28. Multani K., Stanlake L.J.E., Stephan D.W. Ti and Zr complexes of ferrocenyl amidinates. Dalton Trans 2010, 39:8957.
29. 3 with Nitriles and the synthesis, structure, and reactivity of Zirconium Mono- and Tris[2-(2-pyridyl)tetrafluorobenzimidazolate] complexes. Inorg Chem 2010, 49:9217.
30. 3SiF elimination. Coordination chemistry, reactivity, and mechanism. Inorg Chem 2009, 48:5269.
31. Qian F., Liu K., Ma H. Amidinate aluminium complexes: synthesis, characterization and ring-opening polymerization of rac-lactide. Dalton Trans 2010, 39:8071.
32. II complexes with trimethylsilylethinylamidinate ligands. Z Anorg Allg Chem 2012, 638:116.
33. Willcocks A.M., Robinson T.R., Roche C., et al. Multinuclear copper(I) guanidinate complexes. Inorg Chem 2012, 51:246.
34. Benndorf P., Preuß C., Roesky P.W. Synthesis of enantiomeric pure lithium and potassium benzamidinate complexes. J Organomet Chem 2011, 696:1150.
35. Dastgir S., Lavoie G.G. Coordination study of a new class of imine imidazol-2-imine ligands to titanium(IV) and palladium(II). Dalton Trans 2010, 39:6943.
36. Wasslen Y.A., Kurek A., Johnson P.A., et al. Heteroleptic iminopyrrolidinates of aluminium. Dalton Trans 2010, 39:9046.
37. Khalaf M.S., Coles M.P., Hitchcock P.B. A structural, theoretical and coordinative evaluation of the bicyclic guanidinate derived from 1,4,6-triazabicyclo[3.3.0]oct-4-ene. Dalton Trans 2008, 4288.
38. Yakovenko M.V., Cherkasov A.V., Fukin G.K., Cui D., Trifonov A.A. Lanthanide complexes coordinated by a dianionic bis(amidinate) ligand with a rigid naphthalene linker. Eur J Inorg Chem 2010, 2010:3290.
39. Tolpygin A.O., Shavyrin A.S., Cherkasov A.V., Fukin G.K., Trifonov A.A. Chloro and alkyl rare-earth complexes supported by ansa-bis(amidinate) ligands with a rigid O-phenylene linker. Ligand steric bulk: a means of stabilization or destabilization?. Organometallics 2012, 31:5405.
40. 2. Russ Chem Bull Int Ed Engl 2011, 60:803.
41. Rad'kov V.Yu., Skvortsov G.G., Lyubov D.M., et al. Dialkyl rare earth complexes supported by potentially tridentate amidinate ligands: synthesis, structures, and catalytic activity in isoprene polymerization. Eur J Inorg Chem 2012, 2012:2289.
42. Sinenkov M., Kirillov E., Roisnel T., Fukin G., Trifonov A., Carpentier J.-F. Rare-earth complexes with multidentate tethered phenoxy-amidinate ligands: synthesis, structure, and activity in ring-opening polymerization of lactide. Organometallics 2011, 30:5509.
43. Kirillov E., Roisnel T., Carpentier J.-F. Synthesis and structural diversity of group 4 metal complexes with multidentate tethered phenoxy-amidine and phenoxy-amidinate ligands. Organometallics 2012, 31:3228.
44. Zhou M., Li P., Tong H., et al. Syntheses of 2,4-disubstituted 1,3,5-triazapentadienyl ligands having two guanidinato moieties and their use in the isolation of copper(I) complexes. Inorg Chem 1886, 2008:47.
45. Mansfield N.E., Grundy J., Coles M.P., Hitchcock P.B. Phospha(III)guanidinate complexes of titanium(IV) and zirconium(IV) amides. Polyhedron 2010, 29:2481.
46. Harder S., Naglav D. Bora-amidinate complexes of lanthanide(II) metals. Eur J Inorg Chem 2010, 2010:2836.
47. Dröse P., Hrib C.G., Edelmann F.T. Carboranylamidinates. J Am Chem Soc 2010, 132:15540.
48. Yao Z.-J., Su G., Jin G.-X. Chem Eur J 2011, 17:13298-13307.
49. Yao Z.-J., Jin G.-X. Synthesis, reactivity, and structural transformation of mono- and binuclear carboranylamidinate-based 3D metal complexes and metallacarborane derivatives. Organometallics 2012, 31:1767-1774.
50. Yao Z.-J., Xu B., Su G., Jin G.-X. B-H bond activation half-sandwich Ir and Ru complexes containing carboranylamidinate selenolate ligands. J Organomet Chem 2012, 721:31-35.
51. Cheng J. Di-μ-chlorido-bis-{[N, N'-dicyclohexyl-N″, N″-bis-(trimethylsilyl)guanidinato-κN, N'](tetrahydrofuran-κO)magnesium(II)}. Acta Crystallogr 2011, E67:m987.
52. Day B.M., Mansfield N.E., Coles M.P., Hitchcoxk P.B. Bicyclic guanidinate compounds of magnesium and their activity as pre-catalysts in the Tishchenko reaction. Chem Commun 2011, 47:4995.
53. Ciobanu O., Fuchs A., Reinmuth M., et al. Reactions between boron and magnesium halides and the bicyclic guanidine hpph (1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine): guanidinates with new structural motifs. Z Anorg Allg Chem 2010, 636:543.
54. Barrett A.G.M., Crimmin M.R., Hill M.S., et al. Carbodiimide insertion reactions of homoleptic heavier alkaline earth amides and phosphides. Dalton Trans 2010, 39:7393.
55. Hu H., Cui C. Synthesis of calcium and ytterbium complexes supported by a tridentate imino-amidinate ligand and their application in the intermolecular hydrophosphination of alkenes and alkynes. Organometallics 2012, 31:1208.
56. Cameron T.M., Xu C., Dipasquale A.G., Rheingold A.L. Synthesis and structure of strontium and barium guanidinates and mixed-ligand guanidinate pentamethylcyclopentadienyl complexes. Organometallics 2008, 27:1596.
57. Barrett A.G.M., Crimmin M.R., Hill M.S., et al. β-Diketiminato calcium acetylides: synthesis, solution dimerization, and catalytic carbon-carbon bond formation. Organometallics 2008, 27:6300.
58. Barrett A.G.M., Crimmin M.R., Hill M.S., Hitchcock M.S., Procopiou P.A. Insertion reactions of β-diketiminate-stabilised calcium amides with 1,3-dialkylcarbodiimides. Dalton Trans 2008, 4474.
59. Al-Shboul T.M.A., Volland G., Görls H., Westerhausen M. Bis(tetrahydrofuran-O)-bis(1,3-dialkyl-2-diphenylphosphanyl-1,3-diazaallyl)calcium]-synthesis and crystal structures of calcium bis[phospha(III)guanidinates] and investigations of catalytic activity. Z Anorg Allg Chem 2009, 635:1568.
60. Yang L., Ren X., Wang H., Zhang N., Hong S. Res Chem Intermed 2012, 38:113.
61. 2 and CO and other small molecules. J Am Chem Soc 2010, 132:13559.
62. Braunschweig H., Dewhurst R.D., Schwab K., Wagner K. {N',N″-Bis[2,6-bis-(1-methyl-ethyl)phen-yl]-N,N-dimethyl-guanidinato-κN',N″}dibromido-borane. Acta Crystallogr 2010, E66:o610.
63. Jones C., Mills D.P., Stasch A., Woodul W.D. Synthesis and characterization of neutral and cationic boron guanidinate complexes. Main Group Chem 2010, 9:23.
64. Findlater M., Hill N.J., Cowley A.H. Synthesis and structure of two new (guanidinate)boron dichlorides and their attempted conversion to boron(I) derivatives. Dalton Trans 2008, 4419.
65. Rudolf D., Storch G., Kaifer E., Himmel H.-J. Synthesis of molecular gallium hydrides by means of low-temperature catalytic dehydrogenation. Eur J Inorg Chem 2012, 2012:2368.
66. Rudolf D., Kaifer E., Himmel H.-J. Novel bi- and trinuclear gallium halides and hydrides with acyclic and bicyclic guanidinate substituents: synthesis and reactivity. Eur J Inorg Chem 2010, 2010:4952.
67. Ciobanu O., Emeljanenko D., Kaifer E., Mautz J., Himmel H.-J. First dinuclear B(II) monocations with bridging guanidinate ligands: synthesis and properties. Inorg Chem 2008, 47:4774.
68. 3. Eur J Inorg Chem 2009, 2009:4809.
69. 5(+) analogue by protonation of a double base-stabilized diborane(4). Angew Chem Int Ed Engl 2009, 48:5538.
70. Koller J., Bergman R.G. Synthesis, characterization, and reactivity of aluminum alkyl/amide complexes supported by guanidinate and monoanionic OCO-Pincer ligands. Organometallics 2010, 29:3350.
71. Lei Y., Chen F., Luo Y., Xu P., Wang Y., Zhang Y. Bimetallic amidinate aluminum methyl complexes: synthesis, crystal structure and activity for e{open}-caprolactone polymerization. Inorg Chim Acta 2011, 368:179.
72. Holtrichter-Rößmann T., Rösener C., Hellmann J., et al. Generation of weakly bound Al-N Lewis pairs by hydroalumination of ynamines and the activation of small molecules: phenylethyne and dicyclohexylcarbodiimide. Organometallics 2012, 31:3272.
73. Li H., Xiang Y., Han H. [1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III). Acta Crystallogr 2010, E66:m1598.
74. Riddlestone I.M., Urbano J., Phillips N., et al. Salt metathesis for the synthesis of M-Al and M-H-Al bonds. Dalton Trans 2013, 42:249.
75. 2: formation of fused triazaalane heterocycles. Organometallics 2012, 31:197.
76. Maheshwari K., Rajendran N.M., Meyer J., Reddy N.D. Reactions of an aluminum amide with aromatic nitriles: formation of Al-N-C frameworks. Organometallics 2010, 29:3799.
77. Jin G., Jones C., Junk P.C., Stasch A., Woodul W.D. Group 13 metal(I) and (II) guanidinate complexes: effect of ligand backbone on metal oxidation state and coordination sphere. New J Chem 2008, 32:835.
78. Linti G., Zessin T. Synthesis, structure and reactions of an amidinate stabilised trigallane. Dalton Trans 2011, 40:5591.
79. Kühl O. N-heterocyclic germylenes and related compounds. Coord Chem Rev 2004, 248:411.
80. Sen S.S., Khan S., Nagendran S., Roesky H.W. Interconnected bis-silylenes: a new dimension in organosilicon chemistry. Acc Chem Res 2012, 45:578.
81. Yao S., Xiong Y., Driess M. Zwitterionic and donor-stabilized N-heterocyclic silylenes (NHSis) for metal-free activation of small molecules. Organometallics 2011, 30:1748.
82. So C.-W., Roesky H.W., Gurubasavaraj P.M., et al. Synthesis and structures of heteroleptic silylenes. J Am Chem Soc 2007, 129:12049.
83. Azhakar R., Ghadwal R.S., Roesky H.W., Wolf H., Stalke D. A début for base stabilized monoalkylsilylenes. Chem Commun 2012, 48:4561.
84. Jana A., Samual P.P., Tavčar G., Roesky H.W., Schulzke C. Selective aromatic C-F and C-H bond activation with silylenes of different coordinate silicon. J Am Chem Soc 2010, 132:10164.
85. Jana A., Azhakar R., Sarish S.P., et al. Reactions of stable amidinate chlorosilylene and [1+4]-oxidative addition of n-heterocyclic silylene with n-benzylideneaniline. Eur J Inorg Chem 2011, 2011:5006.
86. Jana A., Sarish S.P., Roesky H.W., Leusser D., Objartel I., Stalke D. Pentafluoropyridine as a fluorinating reagent for preparing a hydrocarbon soluble β-diketiminatolead(II) monofluoride. Chem Commun 2011, 47:5434.
87. 2 toward diazobenzene and N-benzylideneaniline. Organometallics 2012, 31:8608.
88. Sarish S.P., Jana A., Roesky H.W., et al. Synthesis of a lewis base stabilized dimer of N-substituted hydrosila hydrazone and a silaaziridine. Organometallics 2011, 30:912.
89. 2SiCl]. Chem Eur J 2011, 17:4283.
90. 2) toward selected azides. Organometallics 2013, 32:358.
91. Khan S., Michel R., Sen S.S., Roesky H.W., Stalke D. A P4 chain and cage from silylene-activated white phosphorus. Angew Chem Int Ed Engl 2011, 50:11786.
92. Ghadwal R.S., Azhkar R., Roesky H.W., et al. Donor-acceptor-stabilized silicon analogue of an acid anhydride. J Am Chem Soc 2011, 133:17552.
93. Zhang S.-H., Xi H.-W., Lim K.H., So C.-W. Synthesis and characterization of an amidinate-stabilized siladithiocarboxylate and its Germanium(II) complex. Organometallics 2011, 30:3686.
94. Inoue S., Epping J.D., Irran E., Driess M. Formation of a donor-stabilized tetrasilacyclobutadiene dication by a Lewis acid assisted reaction of an N-heterocyclic chloro silylene. J Am Chem Soc 2011, 133:8514.
95. Yang Y.-F., Cheng G.-J., Zhu J., Zhang X., Inoue S., Wu Y.-D. Silicon-containing formal 4π-electron four-membered ring systems: antiaromatic, aromatic, or nonaromatic?. Chem Eur J 2012, 18:7516.
96. Junold K., Baus J.A., Burschka C., Tacke R. Bis[N, N'-diisopropylbenzamidinato(-)]silicon(II): a silicon(II) compound with both a bidentate and a monodentate amidinato ligand. Angew Chem Int Ed Engl 2012, 51:7020.
97. Sen S.S., Jana A., Roesky H.W., Schulzke C. A remarkable base-stabilized bis(silylene) with a silicon(I)-silicon(I) bond. Angew Chem Int Ed Engl 2009, 48:8536.
98. 2 rings bridged by two oxygen atoms, with five-coordinate silicon atoms in both ring systems. Organometallics 2010, 29:2343.
99. 2) and a heteroleptic chloro silylene (LSiCl) with benzil: formation of bis(siladioxolene) and monosiladioxolene analogue with five-coordinate silicon atoms in both ring systems. Organometallics 2010, 298:3930.
100. 2SiL]. Chem Eur J 2010, 16:12956.
101. Sen S.S., Roesky H.W., Meindl K., et al. Synthesis, structure, and theoretical investigation of amidinato supported 1,4-disilabenzene. Chem Commun 2010, 46:5873.
102. Zhang S.-H., Yeong H.-X., Xi H.-W., Lim K.-H., So C.-W. Hydrosilylation of a silicon(II) hydride: synthesis and characterization of a remarkable silylsilylene. Chem Eur J 2010, 16:10250.
103. Mao J.-W., Wang T., Liu R.-Q., Bai S.-D., Guo J.-P., Liu D.-S. Synthesis of four-membered bissilylene-linked bisamidines. Mendeleev Commun 2013, 23:86.
104. Yeong H.-X., Zhang S.-H., Xi H.-W., et al. An amidinate-stabilized germatrisilacyclobutadiene ylide. Chem Eur J 2012, 18:2685.
105. Samuel P.P., Singh A.P., Sarish S.P., et al. Oxidative addition versus substitution reactions of group 14 dialkylamino metalylenes with pentafluoropyridine. Inorg Chem 2013, 52:1544.
106. Zhang S.-H., So C.-W. Synthesis and characterization of an amidinate-stabilized bisgermylene oxide and sulfide. Organometallics 2011, 30:2059.
107. I compound with and without cleavage of the Ge-Ge bond. Inorg Chem 2010, 49:5786.
108. Matioszek D., Katir N., Ladeira S., Castel A. Novel stable silyl, germyl, and stannyl germanium(II) compounds containing an amidinato ligand. Organometallics 2011, 30:2230.
109. Azhakar R., Ghadwal R.S., Roesky H.W., Hey J., Stalke D. Facile access to transition-metal-carbonyl complexes with an amidinate-stabilized chlorosilylene ligand. Chem Asian J 2012, 7:528.
110. Jones C., Bonygady S.J., Holzmann N., Frenking G., Stasch A. Preparation, characterization, and theoretical analysis of group 14 element(I) dimers: a case study of magnesium(I) compounds as reducing agents in inorganic synthesis. Inorg Chem 2011, 50:12315.
111. Chlupatý T., Padělková Z., Lyčka A., Brus J., Růžička A. Reactivity of lithium n-butyl amidinates towards group 14 metal(II) chlorides providing series of hetero- and homoleptic tetrylenes. Dalton Trans 2012, 41:5010.
112. Phomphrai K., Pongchan-o C., Thumrongpatanaraks W., Sangtrirutnugul P., Kongsaeree P., Pohmakotr M. Synthesis of high-molecular-weight poly(e{open}-caprolactone) catalyzed by highly active bis(amidinate) tin(II) complexes. Dalton Trans 2011, 40:2157.
113. Chlupatý T., Padělkova Z., DeProft F., Willem R., Růžička A. Addition of Lappert's stannylenes to carbodiimides, providing a new class of tin(II) guanidinates. Organometallics 2012, 31:2203.
114. Cabeza J.A., García-Álvarez P., Polo D. Expanding the coordination chemistry of donor-stabilized group-14 metalenes. Dalton Trans 2013, 42:1329.
115. Matioszek D., Saffon N., Sotiropoulos J.-M., Miqueu K., Castel A., Escudié J. Bis(amidinato)germylenerhodium complexes: synthesis, structure, and density functional theory calculations. Inorg Chem 2012, 51:11716.
116. Jones C., Rose R.P., Stasch A. Synthesis, characterisation and reactivity of germanium(II) amidinate and guanidinate complexes. Dalton Trans 2008, 2871.
117. Brück A., Gallego D., Wang W., Irran E., Driess M., Hartwig J.F. Angew Chem Int Ed Engl 2012, 51:11478.
118. Sen S.S., Kritzler-Kosch M.P., Nagendran S., et al. Synthesis of monomeric divalent tin(II) compounds with terminal chloride, amide, and triflate substituents. Eur J Inorg Chem 2010, 2010:5304.
119. Stasch A., Forsyth C.M., Jones C., Junk P.C. Thermally stable lead(II) amidinates and guanidinates. New J Chem 2008, 32:829.
120. 3 skeletons. Dalton Trans 2011, 40:9844.
121. Junold K., Burschka C., Bertermann R., Tacke R. Novel neutral hexacoordinate silicon(IV) complexes with two bidentate monoanionic benzamidinato ligands. Dalton Trans 2010, 39:9401.
122. 6 to stable silylenes. Inorg Chem 2011, 50:358.
123. Brazeau A.L., Hänninen M.M., Tuononen H.M., Jones N.D., Ragogna P.J. Synthesis, reactivity, and computational analysis of halophosphines supported by dianionic guanidinate ligands. J Am Chem Soc 2012, 134:5398.
124. Brazeau A.L., Nikouline A.S., Ragogna P.J. A base-stabilised arsenic(III) dication. Chem Commun 2011, 47:4817.
125. Lyhs B., Bläser D., Wölper C., Schulz S. Syntheses and X-ray crystal structures of organoantimony diazides. Chem Eur J 2011, 17:4914.
126. Day B.M., Coles M.P., Hitchcock P.B. Neutral and anionic antimony(III) species supported by a bicyclic guanidinate. Eur J Inorg Chem 2012, 2012:841.
127. Lyhs B., Schulz S., Westphal U., Bläser D., Boese R., Bolte M. Heteroleptic amidinate complexes of heavy group 15 elements-synthesis x-ray crystal structures and theoretical calculations. Eur J Inorg Chem 2009, 2009:2247.
128. Lyhs B., Bläser D., Wölper C., Haack R., Jansen G., Schulz S. Structural characterization of amidinatobismuth(III) diazides. Eur J Inorg Chem 2012, 2012:4350.
129. Elkin T., Aharonovich S., Botoshanski M., Eisen M.S. Synthesis and characterization of group 4 fluorinated bis(amidinates) and their reactivity in the formation of elastomeric polypropylene. Organometallics 2012, 31:7404.
130. Sun J.-F., Chen X.-T., Lue Z.-L. Synthesis, characterization and crystal structure of zirconium complex containing amidinate, guanidinate and amide ligand sets. Inorg Chim Acta 2009, 362:4251.
131. Sun J.-F., Chen S.-J., Duan Y., Li Y.-Z., Chen X.-T., Xue Z.-L. Synthesis and characterization of group 4 amidinate amide complexes M[CyNC(Me)NCy]2(NR2)2 (R = Me, M = Ti, Zr, Hf; R = Et, M = Zr). Organometallics 2009, 28:3088.
132. Chen S.-J., Dougan B.A., Chen X.-T., Xue Z.-L. Preparation of zirconium guanidinate complexes from the direct insertion of a carbodiimine and aminolysis using a guanidine comparison of the reactions. Organometallics 2012, 31:3443.
133. Panda T.K., Tsurugi H., Pal K., Kaneko H., Mashima K. Highly reactive metal-nitrogen bond induced C-H bond activation and azametallacycle formation. Organometallics 2010, 29:34.
134. Fernández-Galán R., Antiñolo A., Carrillo-Hermosilla F., et al. New zirconium and zirconocene guanidinate complexes. J Organomet Chem 2012, 711:35.
135. Fernández-Galán R., Antiñolo A., Carrillo-Hermosilla F., et al. Migratory insertion reactions in asymmetrical guanidinate-supported zirconium complexes. Organometallics 2012, 31:8360.
136. Guiducci A.E., Boyd C.L., Clot E., Mountford P. Reactions of cyclopentadienyl-amidinate titanium imido compounds with CO2: cycloaddition-extrusion vs. cycloaddition-insertion. Dalton Trans 2009, 5960.
137. Sun J.-F., Chen X.-T., Xue Z.-L. Hypothesis, characterization and crystal structure of zirconium complex containing amidinate, guanidinate and amide ligand sets. Inorg Chim Acta 2009, 362:4251.
138. Yang Q., Zhou M., Tong H., Guo D., Liu D. Synthesis, crystal structure and catalytic activity of a novel zirconium complex bearing an unsymmetrical aliphatic benzamidinato ligand. Inorg Chem Commun 2013, 29:1.
139. Jones C., Schulten C., Nembenna S., Stasch A. Synthesis and crystal structures of bulky guanidinato zirconium(IV) and hafnium(IV) chloride complexes. J Chem Crystallogr 2012, 42:866.
140. Gott A.L., Clarkson G.J., Deeth R.J., Hammond M.L., Morton C., Scott P. Constrained geometry aminooxazolinate ligands giving chiral zirconium guanidinates; catalytic cyclohydroamination. Dalton Trans 2008, 2983.
141. Weitershaus K., Ward B.D., Kubiak R., et al. Titanium hydroamination catalysts bearing a 2-aminopyrrolinato spectator ligand: monitoring the individual reaction steps. Dalton Trans 2009, 4586.
142. 2 group transfer reactions. Organometallics 2011, 30:1182.
143. Zhang J., Han F., Han Y., Chen Z., Zhou X. Synthesis and structures of titanium and yttrium complexes with N, N'-tetramethylguanidinate ligands: different reactivity of the M-N bonds toward phenyl isocyanate. Dalton Trans 2009, 1806.
144. Maddox A.F., Erickson K.A., Tanski J.M., Waterman R. C-N bond formation via ligand-induced nucleophilicity at a coordinated triamidoamine ligand. Chem Commun 2011, 47:11769.
145. Epshteyn A., Trunkely E.F., Kissounko D.A., Fettinger J.C., Sita L.R. Experimental modeling of selective alkene oligomerization: evidence for facile metallacyclopentane dehydrogenation mediated by a transannular β-hydrogen agostic interaction. Organometallics 2009, 28:2520.
146. Bai S.-D., Guan F., Hu M., Yuan S.-F., Guo J.-P., Liu D.-S. Mononuclear titanium compounds based on the silyl-linked bis(amidinate) ligand: synthesis, characterization and ethylene polymerization. Dalton Trans 2011, 40:7686.
147. Bai S.-D., Tong H.-B., Guo J.-P., Zhou M.-S., Liu D.-S. Coordination chemistry of group 4 metal compounds with mixed-ligand, silyl-linked bis(amidinate) ligand and cyclopentadienyl. Inorg Chim Acta 2009, 362:1143.
148. 2- to zirconium center. Polyhedron 2010, 29:262.
149. Tong H.-B., Li M., Bai S.-D., et al. A bulky silyl shift-directed synthesis of a silyl-linked amidinate-amidine and its Zr(IV) complex. Dalton Trans 2011, 40:4236.
150. Cotton F.A., Ibragimov S.A., Murillo C.A., Poplaukhin P.V., Zhao Q. An unusual binding mode of a guanidinate ligand in a species with a short metal-metal single bond. J Mol Struct 2008, 890:3.
151. Ren S., Deng L., Chan H.-S., Xie Z. Synthesis and structural characterization of zirconium-carboryne complexes. Organometallics 2009, 28:5749.
152. Dong H., Meng Q., Chen B.-Z., Wu Y.-B. Theoretical studies on the multiple metal-metal bonds in the bimetallic molecules and the ultrashort V-Mn bonds in the complexes. J Organomet Chem 2012, 717:108.
153. Aharonovich S., Botoshansky M., Tumanskii B., Nomura K., Waymouth R.M., Eisen M.S. Mono- and bis-amidinate 2,6-xylylimido vanadium chlorides: synthesis, structure, and reactivity. Dalton Trans 2010, 39:5643.
154. Elorriaga D., Carillo-Hermosilla F., Antiñolo A., et al. New alkylimido niobium complexes supported by guanidinate ligands: synthesis, characterization, and migratory insertion reactions. Organometallics 2012, 31:1840.
155. Wiedmann M.K., Heeg M.J., Winter C.H. Volatility and high thermal stability in tantalum complexes containing imido, amidinate, and halide or dialkylamide ligands. Inorg Chem 2009, 48:5382.
156. 3 abstraction by an amide ligand. Inorg Chem 2012, 51:25.
157. Mohammad A. Achiral and chiral, C2-symmetric bicyclic guanidinates based on 1,5,7-triazabicyclo[4.4.0.]dec-5-ene as ligands in high- and mid-valent early transition metal chemistry. Ph.D. Thesis, University of Iowa; 2010.
158. Tomson N.C., Arnold J., Bergman R.G. Synthesis and reactivity of cationic niobium and tantalum methyl complexes supported by imido and β-diketiminato ligands. Dalton Trans 2011, 40:7718.
159. 2) complexes. Organometallics 2012, 31:345.
160. 1 states. Dalton Trans 2012, 41:13097.
161. Alberding B.G., Chisholm M.H., Gallucci J.C., Ghosh Y., Gustafson T.L. Electron delocalization in the S1 and T1 metal-to-ligand charge transfer states of trans-substituted metal quadruply bonded complexes. Proc Natl Acad Sci USA 2011, 108:8152.
162. Alberding B.G., Chisholm M.H., Gustafson T.L., Liu Y., Reed C.R., Turro C. Photophysical studies of trans-bis(phenylethynyldiisopropylamidinato)bis(acetato)dimetal complexes involving MM quadruple bonds where M = Mo or W. J Phys Chem A 2010, 114:12675.
163. Cotton F.A., Li Z., Murillo C.A. Evidence of disruption of conjugation involving delta bonds in intramolecular electronic coupling. Inorg Chem 2009, 48:11847.
164. 4- tetraanion. Chem Commun 2011, 47:4120.
165. Horvath S., Gorelsky S.I., Gambarotta S., Korobkov I. Breaking the 1.80 A barrier of the Cr-Cr multiple bond between Cr(II) atoms. Angew Chem Int Ed Engl 2008, 47:9937.
166. La Macchia G., Li Manni G., Todorova T.K., et al. On the analysis of the Cr-Cr multiple bond in several classes of dichromium compounds. Inorg Chem 2010, 49:5216.
167. Noor A., Glatz G., Müller R., Kaupp M., Demeshko S., Kempe R. Metal-metal distances at the limit: Cr-Cr 1.73 Å-the importance of the ligand and its fine tuning. Z Anorg Allg Chem 2009, 635:1149.
168. Wu P.-F., Liu S.-C., Shieh Y.-J., et al. Divergent reactivity of nitric oxide with metal-metal quintuple bonds. Chem Commun 2013, 49:4391.
169. Hsu C.-W., Yu J.-S.K., Yen C.-H., Lee G.-H., Wang Y., Tsai Y.-C. Quintuply-bonded dichromium(I) complexes featuring metal-metal bond lengths of 1.74Å. Angew Chem Int Ed Engl 2008, 47:9933.
170. Tsai Y.-C., Chen H.-Z., Chang C.-C., et al. Journey from Mo-Mo quadruple bonds to quintuple bonds. J Am Chem Soc 2009, 131:12534.
171. Liu S.-C., Ke W.-L., Yu J.-S.K., Kuo T.-S., Tsai Y.-C. An electron-rich molybdenum-molybdenum quintuple bond spanned by one lithium atom. Angew Chem Int Ed Engl 2012, 51:6394.
172. Carrasco M., Curado N., Maya C., et al. Interconversion of quadruply and quintuply bonded molybdenum complexes by reductive elimination and oxidative addition of dihydrogen. Angew Chem Int Ed Engl 2013, 52:3227.
173. Chen H.-Z., Liu S.-C., Yen C.-H., et al. Reactions of metal-metal quintuple bonds with alkynes: [2+2+2] and [2+2] cycloadditions. Angew Chem Int Ed Engl 2012, 51:19342.
174. 2. Preparations, molecular and electronic structures and reactions. Dalton Trans 2008, 1615.
175. Monillas W.H., Yap G.P.A., Theopold K.H. Synthesis and structure of bis(β-diketiminate) chromium(II) complexes. J Chem Crystallogr 2009, 39:849.
176. El-Kadri O.M., Heeg M.J., Winter C.H. Synthesis, structure, properties, volatility, and thermal stability of molybdenum(II) and tungsten(II) complexes containing allyl, carbonyl, and pyrazolate or amidinate ligands. J Organomet Chem 2009, 694:3902.
177. Reeds J.P., Yonke B.L., Zavalij P.Y., Sita L.R. Carbon monoxide-induced N-N bond cleavage of nitrous oxide that is competitive with oxygen atom transfer to carbon monoxide as mediated by a Mo(II)/Mo(IV) catalytic cycle. J Am Chem Soc 2011, 133:18602.
178. 2 and a M(II)/M(IV) cycle mediated by group 6 M(IV) terminal oxo complexes. Angew Chem Int Ed Engl 2011, 50:12342.
179. Fasulo M.E., Tilley T.D. Interligand H⋯Si interactions in tungsten silyl trihydride complexes. J Organomet Chem 2011, 696:1325.
180. Jones C. Bulky guanidinates for the stabilization of low oxidation state metallacycles. Coord Chem Rev 2010, 254:1273.
181. Bunge S.D., Bertke J.A., Cleland T.L. Synthesis, structure, and reactivity of low-coordinate 1,1,3,3-tetraethylguanidinate complexes. Inorg Chem 2009, 48:8037.
182. Woodruff D., Bodensteiner M., Sells D.O., Winpenny R.E.P., Layfield R.A. Synthesis and structure of cationic guanidinate-bridged bimetallic Li7M cubes (M = Mn, Co, Zn) with inverse crown counter anions. Dalton Trans 2011, 40:10918.
183. 2. Inorg Chim Acta 1998, 281:181.
184. Fohlmeister L., Liu S., Schulten C., et al. Low-coordinate iron(I) and manganese(I) dimers: kinetic stabilization of an exceptionally short Fe-Fe multiple bond. Angew Chem Int Ed Engl 2012, 51:8294.
185. 6+ species with divergent bicyclic guanidinate ligands and by modification of axial π interactions. Inorg Chem 2011, 50:1258.
186. 7+ units surrounded by an unsymmetrical bicyclic guanidinate. Inorg Chem 2012, 51:5257.
187. 2(8+) species. Chem Commun 2011, 47:8940.
188. Nagashima H., Kondo H., Hayashida T., et al. Chemistry of coordinatively unsaturated organoruthenium amidinates as entry to homogeneous catalysis. Coord Chem Rev 2003, 245:177.
189. Rose R.P., Jones C., Schulten C., Aldridge S., Stasch A. Synthesis and characterization of amidinate-iron(I) complexes: analogies with beta-diketiminate chemistry. Chem Eur J 2008, 14:8477.
190. Jellema E., Sciarone T.J.J., Navarrete N.M., Hettinga M.J., Meetsma A., Hessen B. Reactivity of paramagnetic FeII-bis(amidinate) complexes. Eur J Inorg Chem 2011, 2011:91.
191. 19F NMR evidence for interactions with weakly coordinating anions. Organometallics 2008, 27:2058.
192. 2(PhNCHNHPh). Z Kristallogr NCS 2008, 223:219.
193. Boyd D.A., Crutchley R.J., Fanwick P.E., Ren T. Fc-Fc electronic interaction through equatorial pathways of a diruthenium core. Inorg Chem 2010, 49:1322.
194. Lee R., Yang Y., Tan G.K., Tan C.-H., Huang K.-W. A novel heteroleptic paddlewheel diruthenium bicyclic guanidinate complex: synthesis, structure, and scope. Dalton Trans 2010, 39:723.
195. 6+ species caused by the variations of the bite angle of guanidinate ligands: tuning magnetic behavior. Inorg Chem 2010, 49:3051.
196. Pap J.S., Snyder J.L., Piccoli P.M.B., Berry J.F. Chloro and azido diruthenium complexes bearing electron-rich N, N', N″-triphenylguanidinate ligands. Inorg Chem 2009, 48:9846.
197. Singh T., Kishan R., Nethaji M., Thirupathi N. Synthesis, reactivity studies, structural aspects, and solution behavior of half sandwich ruthenium(II) N, N', N″-triarylguanidinate complexes. Inorg Chem 2012, 51:157.
198. García-Álvarez R., Suárez F.J., Déz J., et al. Ruthenium(II) arene complexes with asymmetrical guanidinate ligands: synthesis, characterization, and application in the base-free catalytic isomerization of allylic alcohols. Organometallics 2012, 31:8301.
199. 2-C rearrangement. J Organomet Chem 2009, 694:795.
200. Takemoto S., Kobayashi T., Ito T., et al. Synthesis and reactivity of coordinatively unsaturated dinuclear ruthenium bridging imido complexes. Organometallics 2011, 30:2160.
201. Cummings S.P., Cao Z., Fanwick P.E., Kharlamova A., Ren T. Diruthenium(III, III) ethynyl-phenyleneimine molecular wires: preparation via on-complex schiff base condensation. Inorg Chem 2012, 51:7561.
202. Ying J.-W., Liu I.P.-C., Xi B., et al. Linear trimer of diruthenium linked by butadiyn-diyl units: a unique electronic wire. Angew Chem Int Ed Engl 2010, 49:964.
203. Li J., Wu J., Zhou C., et al. On the relative stability of cobalt- and nickel-based amidinate complexes against β-migration. Int J Quantum Chem 2009, 109:756.
204. Jones C., Schulten C., Rose R.P., et al. Amidinato- and guanidinato-cobalt(I) complexes: characterization of exceptionally short Co-Co interactions. Angew Chem Int Ed Engl 2009, 48:7406.
205. Jones C., Mills D.P., Stasch A. Flexible coordination of bulky amidinates and guanidinates towards rhodium(I): conversion of kinetic to thermodymanic isomers. Dalton Trans 2008, 4799.
206. Chartrand D., Hanan G.S. Facile synthesis of multinuclear complexes based on a tetra(4-pyridyl)amidinate dirhodium(II) dimer. Chem Commun 2008, 727.
207. Chifotides H.T., Dunbar K.R. Head-to-head right-handed cross-links of the antitumor-active bis(μ-N, N'-di-p-tolylformamidinato)dirhodium(II, II) unit with the dinucleotides d(GpA) and d(ApG). Chem Eur J 2008, 14:9902.
208. 2. Chem Commun 2012, 48:2876.
209. 2 reactivity, and (alkene)peroxoiridium(III) intermediates. Inorg Chem 2013, 52:2564.
210. Liu Y., Ye K., Fan Y., Song W., Wang Y., Hou Z. Amidinate-ligated iridium(III) bis(2-pyridyl)phenyl complex as an excellent phosphorescent material for electroluminescence devices. Chem Commun 2009, 3699.
211. Ri V.K., Nishiura M., Takimoto M., Zhao S., Liu Y., Hou Z. Bis-cyclometalated Iridium(III) complexes bearing ancillary guanidinate ligands. Synthesis, structure, and highly efficient electroluminescence. Inorg Chem 2012, 51:822.
212. Rai V.K., Nishiura M., Takimoto M., Hou Z. Guanidinate ligated iridium(III) complexes with various cyclometalated ligands: synthesis, structure, and highly efficient electrophosphorescent properties with a wide range of emission colours. J Mater Chem C 2013, 1:677.
213. 2 reactivity of iridium(I) complexes supported by guanidinato ligands. Inorg Chem 2008, 47:11461.
214. Rohde J.-U., Lee W.-T. Stabilization of iridium(IV) by monoanionic dialkyldiarylguanidinato ligands. J Am Chem Soc 2009, 131:9162.
215. Jones C., Schulten C., Fohlmeister L., et al. Bulky guanidinato nickel(I) complexes: synthesis, characterization, isomerization, and reactivity studies. Chem Eur J 2011, 17:1294.
216. Chiarella G.M., Cotton F.A., Murillo C.A. Acetonitrile activation promoted by divalent nickel species with bicyclic guanidinate ligands. J Cluster Sci 2012, 23:673.
217. Peters A., Wild U., Hübner O., Kaifer E., Himmel H.-J. Mono- and diprotonation of the superbasic bisguanidine 1,2-Bis(N, N, N', N'-tetramethylguanidino)benzene (btmgb) and Pt II and Pt IV complexes of chelating bisguanidines and guanidinates. Chem Eur J 2008, 14:7813.
218. Grundy J., Mansfield N.E., Coles M.P., Hitchcock P.B. Phosphaguanidines as scaffolds for multimetallic complexes containing metal-functionalized phosphines. Inorg Chem 2008, 47:2258.
219. Chen M.-T., Wu K.-M., Chen C.-T. C-H bond activation of palladium complexes that feature pendant benzamidinate ligands and their catalytic behaviour. Eur J Inorg Chem 2012, 2012:720.
220. Penno D., Estevan F., Fernández E., et al. Dinuclear ortho-metalated palladium(II) compounds with N, N- and N, O-donor bridging ligands. Synthesis of new palladium(III) complexes. Organometallics 2011, 30:2083.
221. 2+ complex. Inorg Chem Commun 2009, 12:1061.
222. Cornacchia D., Pelli R.Z., Intini F.P., Pacifico C., Natile G. Solution behavior of amidine complexes: an unexpected cis/trans isomerization and formation of di- and trinuclear platinum(III) and platinum(II) species. Inorg Chem 2009, 48:10800.
223. 4 clusters. Chem Eur J 2011, 17:3693.
224. Tanaka S., Mashima K. Unique stepwise substitution reaction of a mono(guanidinate)tetraplatinum complex with amidines, giving mono(amidinate)tetraplatinum complexes through mixed-ligand intermediate complexes. Dalton Trans 2013, 42:2831.
225. Mohamed A.A., Abdou H.E., Fackler J.P. Coordination chemistry of gold(II) with amidinate, thiolate and ylide ligands. Coord Chem Rev 2010, 254:1253.
226. Chiarella G.M., Melgarejo D.Y., Fackler J.P. New anionic copper(I) dihalide cyclic guanidinate compounds with H-bonded chelating guanidinium cations. Inorg Chim Acta 2012, 386:13.
227. Guo D., Qiao X., Tong H.-B., Zhou M. [μ-Bis(trimethyl-silyl)amido]bis-[μ-N, N-dimethyl-N', N″-bis-(trimethyl-silyl)guanidinato]-triangulo-tricopper(I). Acta Crystallogr 2009, E65:m405.
228. Chiarella G.M., Melgarejo D.Y., Fackler J.P. Synthesis, characterization and properties of a novel cationic hexanuclear cyclic guanidinate copper(I) cluster of high solubility in non-polar solvents. J Cluster Sci 2012, 23:823.
229. Chiarella G.M., Melgarejo D.Y., Prosvirin A.V., Dunbar K.R., Fackler J.P. Tetranuclear, oxygen centered copper(II) clusters linked together with guanidine-guanidinate ligands. J Cluster Sci 2010, 21:551.
230. Nebra N., Lescot C., Dauban P., Mallet-Ladeira S., Martin-Vaca B., Bourissou D. Intermolecular alkene aziridination: an original and efficient CuI···CuI dinuclear catalyst deriving from a phospha-amidinate ligand. Eur J Org Chem 2013, 5:984.
231. Mohamed A.A., Abdou H.E., Mayer A., Fackler J.P. A silver(I)-gold(II) hexanuclear guanidinate-benzoate cluster with short Au-Au bonds. J Cluster Sci 2008, 19:551.
232. Melgarejo D.Y., Chiarella G.M., Mohamed A.A., Fackler J.P. An octanuclear gold(I) cube with amidinate ligands containing two hyper-coordinate ylide carbon atoms. Z Naturforsch 2009, 64b:1487.
233. Melgarejo D.Y., Chiarella G.M., Fackler J.P. Novel mixed coordination of N and C donors to gold-gold centers. Organometallics 2011, 30:5374.
234. Eisenmann T., Khanderi J., Schulz S., Flörke U. Syntheses and X-ray structures of zinc amidinate complexes. Z Anorg Allg Chem 2008, 634:507.
235. Schmidt S., Schulz S., Bläser D., Boese R., Bolte M. Synthesis and structural characterization of new zinc amidinate complexes. Organometallics 2010, 29:6097.
236. Zelga K., Leszczyński M., Justyniak I., et al. Synthesis, structure and unique reactivity of the ethylzinc derivative of a bicyclic guanidine. Dalton Trans 2012, 41:5934.
237. Neuhäuser C., Reinmuth M., Kaifer E., Himmel H.-J. Synthesis of oligomeric zinc complexes with bicyclic and acyclic guanidinate ligands. Eur J Inorg Chem 2012, 2012:1250-1260.
238. 2Zn. Z Anorg Allg Chem 2012, 638:1705.
239. Jones C., Furness L., Nembenna S., Rose R.P., Aldridge S., Stasch A. Bulky guanidinato and amidinato zinc complexes and their comparative stabilities. Dalton Trans 2010, 39:8788.
240. Sánchez-Barba L.F., Alonso-Moreno C., Garcés A., et al. Synthesis, structures and ring-opening polymerization studies of new zinc chloride and amide complexes supported by amidinate heteroscorpionate ligands. Dalton Trans 2009, 8054.
241. 2 and MeZnCl. Z Anorg Allg Chem 2008, 634:2221.
242. Schmidt S., Gutschank B., Schulz S., Bläser D., Boese R., Wölper C. Synthesis and X-ray crystal structures of multinuclear zinc amidinate complexes. Eur J Inorg Chem 2011, 2011:4464.
243. 2 and iPrN=C=NiPr. Angew Chem Int Ed 2008, 47:1512.
244. Schmidt S., Gondzik S., Schulz S., Bläser S., Boese R. Zinc carbodiimide cluster complexes: synthesis, X-ray crystal structures, and reaction mechanism. Organometallics 2009, 28:4371.
245. Gutschank B., Schulz S., Bläser D., Boese R., Wölper C. Synthesis, structure, and reactivity of a tetranuclear amidinato zinc hydride complex. Organometallics 2010, 29:6133.
246. Gutschank B., Schulz S., Westphal U., Bläase D., Boese R. Synthesis and X-ray crystal structures of tetranuclear zincamidinate complexes. Organometallics 2010, 29:2093.
247. Edelmann F.T. Lanthanide amidinates and guanidinates: from laboratory curiosities to efficient homogeneous catalysts and precursors for rare-earth oxide thin films. Chem Soc Rev 2009, 38:2253.
248. Trifonov A.A. Guanidinate and amidopyridinate rare-earth complexes: towards highly reactive alkyl and hydrido species. Coord Chem Rev 2010, 254:1327.
249. Li T., Jenter J., Roesky P.W. Rare-earth metal postmetallocene catalysts with chelating amido ligands. Struct Bonding 2010, 137:165.
250. Edelmann F.T. Lanthanide amidinates and guanidinates in catalysis and materials science: a continuing success story. Chem Soc Rev 2012, 41:7657.
251. Heitmann D., Jones C., Mills D.P., Stasch A. Low coordinate lanthanide(II) complexes supported by bulky guanidinato and amidinato ligands. Dalton Trans 2010, 39:1877.
252. 2O unit. Mendeleev Commun 2011, 21:318.
253. 2-2,6)](-). Inorg Chem 2009, 48:9936.
254. Basalov I.V., Lyubov D.M., Fukin G.K., Shavyrin A.S., Trifonov A.A. A double addition of Ln-H to a carbon-carbon triple bond and competitive oxidation of ytterbium(II) and hydrido centers. Angew Chem Int Ed 2012, 51:3444.
255. Basalov I.V., Lyubov D.M., Fukin G.K., Cherkasov A.V., Trifonov A.A. Reactivity of Ytterbium(II) hydride redox reactions: ytterbium(II) vs hydrido ligand. Metathesis of the Yb-H bond. Organometallics 2013, 32:1507.
256. 3]: synthesis, molecular structures and one-electron-transfer reactions. Inorg Chem 2012, 51:4151.
257. Pan C.-L., Chen S., Song S., Zhang H., Li X. Stabilization of imidosamarium(III) cubane by amidinates. Inorg Chem 2009, 48:6344.
258. Pan C.-L., Chen W., Su S., Pan Y.-S., Wang J. Cubic and doubly-fused cubic samarium clusters from Sm(II)-mediated reduction of organic azides and azobenzenes. Dalton Trans 2011, 40:7941.
259. Pan C.-L., Pan Y.-S., Wang J., Song J.-F. A heterometallic sandwich complex of europium(II) for luminescent studies. Dalton Trans 2011, 40:6361.
260. Pan C.-L., Sheng S.-D., Hou C.-M., Pan Y.-S., Wang J., Fan Y. A new type of lanthanide complex-two divalent ytterbium species assembled from cation-π interactions. Eur J Inorg Chem 2012, 2012:779.
261. Edelmann A., Hrib C.G., Hilfert L., Blaurock S., Edelmann F.T. [N, N'-Bis(2,6-diisopropylphenyl)methanimidamidato][η-1,4-bis-(trimethylsilyl)cyclooctatetraenyl](tetrahydrofuran)-samarium(III) toluene monosolvate. Acta Crystallogr 2010, E66:m1675.
262. Dröse P., Hrib C.G., Blaurock S., Edelmann F.T. Tris(N, N'-diisopropyl-benzamidinato)cerium(III). Acta Crystallogr 2010, E66:m1474.
263. Bochkarev M.N., Maleev A.A., Balashova T.V., et al. Methyl- and propylacetamidinates of lanthanides: structures, catalytic and some physical properties. Inorg Chim Acta 2008, 361:2533.
264. Zhang J., Yi W., Chen Z., Zhou X. Room temperature C-N bond cleavage of anionic guanidinate ligand in rare-earth metal complexes. Dalton Trans 2013, 42:5826.
265. Dröse P., Hrib C.G., Edelmann F.T. Synthesis and structural characterization of a homoleptic cerium(III) propiolamidinate. J Organomet Chem 2010, 695:1953.
266. Skvortsov G.G., Lyubov D.M., Yakovenko M.V., Fukin G.K., Cherkasov A.V., Trifonov A.A. Benzonitrile insertion into silylarylamides-Ansa-Bis(benzamidinate) ligand systems with rigid o- and m-phenylene linkers in the synthesis of lithium and rare earth complexes. Russ Chem Bull Int Ed Engl 2009, 58:1126.
267. 2-2,6). Z Anorg Allg Chem 2011, 637:31.
268. Fukin G.K., Guzei I.A., Baranov E.V. Non-valent interactions and structural features of monomeric guanidinate complexes of rare earth metals: analyses and predictions based on the ligand solid angle. J Coord Chem 2008, 61:1678.
269. Kratsch J., Kuzdrowska M., Schmid M., et al. Chiral rare earth borohydride complexes supported by amidinate ligands: synthesis, structure, and catalytic activity in the ring-opening polymerization of rac-lactide. Organometallics 2013, 32:1230.
270. Bambirra S., Perazzolo F., Boot S.J., Sciarone T.J.J., Meetsma A., Hessen B. Strategies for the synthesis of lanthanum dialkyl complexes with monoanionic ancillary ligands. Organometallics 2008, 27:704.
271. Luo Y., Wang X., Chen J., Luo C., Zhang Y., Yao Y. Mono(amidinate) rare earth metal bis(alkyl) complexes: synthesis, structure and their activity for l-lactide polymerization. J Organomet Chem 2009, 694:1289.
272. Chen F., Fan S., Wang Y., Chen J., Luo Y. Unusual Si-H bond activation and formation of cationic scandium amide complexes from a mono(amidinate)-ligated scandium bis(silylamide) complex and their performance in isoprene polymerization. Organometallics 2012, 31:3730.
273. 3 and isoprene. Dalton Trans 2013, 42:4040.
274. Zhang L., Nishiura M., Yuki M., Luo Y., Hou Z. Isoprene polymerization with yttrium amidinate catalysts: switching the regio- and stereoselectivity by addition of AlMe3. Angew Chem Int Ed Engl 2008, 47:2642.
275. Karpov A.V., Shavyrin A.S., Cherkasov A.V., Fukin G.K., Trifonov A.A. Reactions of bis(alkyl)yttrium complexes supported by bulky N, N ligands with 2,6-diisopropylaniline and phenylacetylene. Organometallics 2012, 31:5349.
276. 3. Organometallics 2008, 27:1299.
277. Chu J., Lu E., Chen Y., Leng X. Reversible addition of the Si-H bond of phenylsilane to the Sc=N bond of a scandium terminal imido complex. Organometallics 2013, 32:1137.
278. Cheng J., Hou Z. Cationic terminal hydrido rare earth complexes bearing an amidinate ancillary ligand. Chem Commun 2012, 48:814.
279. Cole M.L., Deacon G.B., Junk P.C., Wang J. Bulky formamidinate-supported lanthanoid halides and alkyls, including a rare terminal La-Me species. Organometallics 2013, 32:1370.
280. Behrle A.C., Schmidt K.A.R. Insertion reactions and catalytic hydrophosphination of heterocumulenes using α-metalated n, n-dimethylbenzylamine rare-earth-metal complexes. Organometallics 2013, 32:1141.
281. Döring C., Kempe R. Synthesis and structure of aminopyridinato-stabilized yttrium and lanthanum amides and their reactivity towards alkylaluminium compounds. Eur J Inorg Chem 2009, 2009:412.
282. Litlabø R., Lee H.S., Niemeyer M., Törnroos K.W., Anwander R. Rare-earth metal bis(tetramethylaluminate) complexes supported by a sterically crowded triazenido ligand. Dalton Trans 2010, 39:6815.
283. Wang Y., Luo Y., Chen J., Xue H., Liang H. Synthesis of mono(guanidinate) rare earth metal bis(amide) complexes and their performance in the ring-opening polymerization of l-lactide and rac-lactide. New J Chem 2012, 36:933.
284. Zhang Z., Zhang L., Li Y., Hong L., Chen Z., Zhou X. Activation of bis(guanidinate)lanthanide alkyl and aryl complexes on elemental sulfur: synthesis and characterization of bis(guanidinate)lanthanide thiolates and disulfides. Inorg Chem 2010, 49:5715.
285. Chi S.-H., Chen J. {Bis[N, N'-dicyclohexyl-N″, N″-bis-(trimethylsilyl)guanidinato-κ(2)N, N']neo-dymium(III)}di-μ-chlorido-[bis-(tetrahydrofuran-κO)lithium]. Acta Crystallogr 2013, E69:m121.
286. Ajellal N., Lyubov D.M., Sinenkov M.A., et al. Bis(guanidinate) alkoxide complexes of lanthanides: synthesis, structures and use in immortal and stereoselective ring-opening polymerization of cyclic esters. Chem Eur J 2008, 14:5440.
287. 2 (Ln = Y, Lu): synthesis, structure, and reactivity. Eur J Inorg Chem 2008, 2008:2090.
288. -). Organometallics 2010, 29:6141.
289. Skvortsov G.G., Lyubov D.M., Yakovenko M.V., Fukin G.K., Cherkasov A.V., Trifonov A.A. Benzonitrile insertion into silylarylamides-ansa-bis(benzamidinate) ligand systems with rigid o- and m-phenylene linkers in the synthesis of lithium and rare earth complexes. Russ Chem Bull Int Ed 2009, 58:1126.
290. 4. Eur J Inorg Chem 2009, 2009:4864.
291. Benndorf P., Jenter J., Zielke L., Roesky P.W. Chiral lutetium benzamidinate complexes. Chem Commun 2011, 47:2574.
292. Lu E., Chen Y., Leng X. Yttrium anilido hydride: synthesis, structure, and reactivity. Organometallics 2011, 30:5433.
293. Skvortsov G.G., Tolpyguin A.O., Fukin G.K., Cherkasov A.V., Trifonov A.A. Dinuclear chlorido-, alkyl(chlorido)-, and hydridoyttrium complexes supported by μ-bridging-silyl-linked bis(amidinate) ligands. Eur J Inorg Chem 2010, 2010:1655.
294. Li W., Yakovenko M.V., Trifonov A.A., Kirillov E., Roisnel T., Carpentier J.-F. Lanthanide borohydrides supported by an ansa-bis(amidinate) ligand with a rigid naphthalene linker: synthesis, structure and catalytic activity in ring-opening polymerization of lactide. Inorg Chim Acta 2012, 383:137.
295. Wang J., Yao Y., Zhang Y., Shen Q. Bridged bis(amidinate) ytterbium alkoxide and phenoxide: syntheses, structures, and their high activity for controlled polymerization of L-lactide and epsilon-caprolactone. Inorg Chem 2009, 48:744.
296. Tu J., Li W., Xue M., Zhang Y., Shen Q. Bridged bis(amidinate) lanthanide aryloxides: syntheses, structures, and catalytic activity for addition of amines to carbodiimides. Dalton Trans 2013, 42:5890.
297. Wang J., Sun H., Yao Y., Zhang Y., Shen Q. Bridged bis(amidinate) lanthanide complexes: synthesis, molecular structure and reactivity. Polyhedron 2008, 27:1977.
298. Li W., Xue M., Xu F., Tu J., Zhang Y., Shen Q. Synthesis, characterization of bridged bis(amidinate) lanthanide amides and their application as catalysts for addition of amines to nitriles for monosubstituted N-arylamidines. Dalton Trans 2012, 41:8252.
299. Zhang X., Wang C., Xue M., Zhang Y., Yao Y., Shen Q. Syntheses of lanthanide monochloride and monoborohydride complexes supported by bridged bis(guanidinate) ligand and the use of borohydride complexes in polymerization of cyclic esters. J Organomet Chem 2012, 713:182.
300. Zhang X., Wang C., Xue M., Zhang Y., Yao Y., Shen Q. Synthesis and structure of samarium benzyl complex supported by bridged bis(guanidinate) ligand and its reactivity toward nitriles and phenyl isocyanate. J Organomet Chem 2012, 716:86.
301. Wang C., Zhang X., Xue M., Zhang Y., Shen Q. Unprecedented reaction of bridged bis(guanidinate) lanthanide complexes: sterically induced deprotonation. Dalton Trans 2013, 42:7009.
302. Yakovenko M.V., Trifonov A.A., Kirillov E., Roisnel T., Carpentier J.-F. Lanthanide borohydrides supported by an ansa-bis(amidinate) ligand with a rigid naphthalene linker: synthesis, structure and catalytic activity in ring-opening polymerization of lactide. Inorg Chim Acta 2012, 383:137.
303. 2Ln]+ cation. Inorg Chem 2010, 49:2793.
304. Yi W., Zhang J., Chen Z., Zhou X. Me-Si bond cleavage of anionic bis(trimethylsilyl)amide in scorpionate-anchored rare earth metal complexes. Inorg Chem 2012, 51:10631.
305. Jian Z., Hangaly N.K., Rong W., et al. Yttrium hydride complex bearing CpPN/amidinate heteroleptic ligands: synthesis, structure, and reactivity. Organometallics 2012, 31:4579.
306. Casely I.J., Ziller J.W., Evans W.J. C-H activation via carbodiimide insertion into yttrium-carbon alkynide bonds: an organometallic alder-ene reaction. Organometallics 2011, 30:4873.
307. 5). Organometallics 2012, 31:5591.
308. Lakehal S., Ouddai N.J. Theoretical investigation on organolanthanide guanidinate complexes. Rare-earths 2010, 28:161.
309. Zhang J., Ma L., Han Y., et al. Facile construction of the guanidine substituent or guanidinate anionic ligand through addition of the adjacent amino group to carbodiimide. Dalton Trans 2009, 3298.
310. 5 bond and subsequent isomerization. Inorg Chem 2010, 49:7632.
311. 3. Organometallics 2010, 29:1284.
312. Zhang X., Qian C., Wang C., et al. Synthesis, molecular structures, and reactivity of dianionic guanidinate lanthanide/lithium derivatives. Eur J Inorg Chem 2012, 2012:847.
313. Qian C., Zhang X., Zhang Y., Shen Q. Heterobimetallic complexes of lanthanide and lithium metals with dianionic guanidinate ligands: syntheses, structures and catalytic activity for amidation of aldehydes with amines. J Organomet Chem 2010, 695:747.
314. Zhang X., Wang C., Qian C., Han F., Xua F., Shen Q. Heterobimetallic dianionic guanidinate complexes of lanthanide and lithium: highly efficient precatalysts for catalytic addition of amines to carbodiimides to synthesize guanidines. Tetrahedron 2011, 67:8790.
315. Harder S. Syntheses and structures of bora-amidinate lanthanide(III) complexes. Dalton Trans 2010, 39:6677.
316. Yuan Y., Wang X., Li Y., et al. Rapid entry to functionalized boratabenzene complexes through metal-induced hydroboration at the anionic 1-H-boratabenzene ligand. Organometallics 2011, 30:4330.
317. Dröse P., Crozier A.R., Lashkari S., et al. Facile access to tetravalent cerium compounds: one-electron oxidation using iodine(III) reagents. J Am Chem Soc 2010, 132:14046.
318. Rabinovich E., Aharonovich S., Botoshansky M., Eisen M.S. Thorium 2-pyridylamidinates: synthesis, structure and catalytic activity towards the cyclo-oligomerization of e{open}-caprolactone. Dalton Trans 2010, 39:6667.
319. Evans W.J., Montalvo E., Ziller J.W., DiPasquale A.G., Rheingold A.L. Uranium metallocene complexes of the 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinato ligand, (hpp)(-). Inorg Chem 2010, 49:222.
320. Montalvo E., Ziller J.W., DiPasquale A.G., Rheingold A.L., Evans W.J. Utility of the 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinato ligand, (hpp)-, in stabilizing uranium metallocene mono-alkyl and "tuck-in" complexes. Organometallics 2010, 29:2104.
321. Evans W.J., Walensky J.R., Ziller J.W., Rheingold A.L. Insertion of carbodiimides and organic azides into actinide-carbon bonds. Organometallics 2009, 28:3350.
322. 5)(-). Chem Eur J 2009, 15:12204.
323. 5)(-). Inorg Chem 2010, 49:10007.
324. Evans W.J., Walensky J.R., Ziller J.W. Reactivity of methyl groups in actinide metallocene amidinate and triazenido complexes with silver and copper salts. Organometallics 2010, 29:101.
325. 2[(i)PrNC(Me)N(i)Pr]U including the isolation of a uranium complex of a monodentate acetate. Inorg Chem 2010, 49:1743.
326. Evans W.J., Walensky J.R., Ziller J.W. Aryloxide anions can form outer sphere complexes with metals as electropositive as uranium. Chem Commun 2009, 7342.
327. 2[(i)PrNC(Me)N(i)Pr]U including the isolation of a uranium complex of a monodentate acetate. J Am Chem Soc 2009, 131:17473.
328. 2U. J Am Chem Soc 2011, 133:3507.
329. 2)U. Organometallics 2011, 30:458.
330. Arndt S., Okuda J. Cationic alkyl complexes of the rare-earth metals: synthesis, structure, and reactivity. Adv Synth Catal 2005, 347:339.
331. Smolensky E., Eisen M.S. Design of organometallic group IV heteroallylic complexes and their catalytic properties for polymerizations and olefin centered transformations. Dalton Trans 2007, 5623.
332. Zhang W.-X., Hou Z. Catalytic addition of alkyne C-H, amine N-H, and phosphine P-H bonds to carbodiimides: an efficient route to propiolamidines, guanidines, and phosphaguanidines. Org Biomol Chem 2008, 6:1720.
333. Collins S. Polymerization catalysis with transition metal amidinate and related complexes. Coord Chem Rev 2011, 255:118.
334. Day B.M., Knowelden W., Coles M.P. Synthetic and catalytic intermediates in a magnesium promoted Tishchenko reaction. Dalton Trans 2012, 41:10930.
335. Sánchez-Barba L.F., Garcés A., Fernández-Baeza J., et al. Stereoselective production of poly(rac-lactide) by ROP with highly efficient bulky heteroscorpionate alkylmagnesium initiators. Organometallics 2011, 30:2775.
336. Rowley C.N., Ong T.-G., Priem J., Woo T.K., Richeson D.S. Amidolithium and amidoaluminum catalyzed synthesis of substituted guanidines: an interplay of DFT modeling and experiment. Inorg Chem 2008, 47:9660.
337. Lachs J.R., Barrett A.G.M., Crimmin M.R., et al. Heavier group-2-element catalyzed hydroamination of carbodiimides. Eur J Inorg Chem 2008, 2008:4173.
338. Rowley C.N., Ong T.-G., Priem J., Richeson D.S., Woo T.K. Analysis of the critical step in catalytic carbodiimide transformation: proton transfer from amines, phosphines, and alkynes to guanidinates, phosphaguanidinates, and propiolamidinates with Li and Al catalysts. Inorg Chem 2008, 47:12024.
339. Zhu X.H., Xu F., Shen Q. Aluminum chloride: a highly efficient catalyst for addition of amines to carbodiimides to synthesize substituted guanidines. Chin Sci Bull 2012, 57:3419.
340. Zhang W.-X., Li D., Wang Z., Xi Z. Alkyl aluminum-catalyzed addition of amines to carbodiimides: a highly efficient route to substituted guanidines. Organometallics 2009, 28:882.
341. Koller J., Bergman R.G. Highly efficient aluminum-catalyzed hydro-amination/-hydrazination of carbodiimides. Organometallics 2010, 29:5946.
342. Ghorbani N., Ghobe N.M., Torabi S., Yates B.F., Ariafard A. Theoretical investigation into the mechanism of ethylene polymerization by a cationic dinuclear aluminum complex: a longstanding unresolved issue. Organometallics 2013, 32:1687.
343. Raspolli Galletti A.M., Pampaloni G. Niobium complexes as catalytic precursors for the polymerization of olefins. Coord Chem Rev 2010, 254:525.
344. Obenauf J., Kretschmer W.P., Bauer T., Kempe R. An efficient titanium amidinate catalyzed version of Ziegler's "aufbaureaktion". Eur J Inorg Chem 2013, 2013:537.
345. Aharonovich S., Botoshansky M., Balazs Y.S., Eisen M.S. Elucidation of substituent effects in the polymerization of propylene promoted by titanium amidinates. Organometallics 2012, 31:3435.
346. Romero-Fernández J., Carrillo-Hermosilla F., Antiñolo A., et al. Oxo- and imido-alkoxide vanadium complexes as precatalysts for the guanylation of aromatic amines. Dalton Trans 2010, 39:6419.
347. 2 core. Dalton Trans 2011, 40:9358.
348. Pottabathula S., Royo B. First iron-catalyzed guanylation of amines: a simple and highly efficient protocol to guanidines. Tetrahedron Lett 2012, 53:5156.
349. Ogata k., Oka O., Toyota A., Suzuki N., Fukuzawa S.-I. Phosphine-dependent selective cross-dimerization between terminal alkylacetylene and silylacetylene by iridium(I) guanidinate complex-phosphine system. Synlett 2008, 2663.
350. Yu Z.-T., Yuan Y.-J., Cai J.-G., Zou Z.-G. Charge-neutral amidinate-containing iridium complexes capable of efficient photocatalytic water reduction. Chem Eur J 2013, 19:1303.
351. 2(amidine)] effectively catalyze the formation of tertiary amines from the reaction of primary alcohols and ammonium salts. Adv Synth Catal 2011, 353:2078.
352. Wang Y., Wang H., Peng J., Zhu Q. Palladium-catalyzed intramolecular C(sp2)-H amidination by isonitrile insertion provides direct access to 4-aminoquinazolines from N-arylamidines. Org Lett 2011, 13:4604.
353. Kantam M.L., Priyadarshini S., Joseph P.J.A., Srinivas P., Vinu A., Klabunde K.J. Catalytic guanylation of aliphatic, aromatic, heterocyclic primary and secondary amines using nanocrystalline zinc(II) oxide. Tetrahedron 2012, 68:5730.
354. Alonso-Moreno C., Carrillo-Hermosilla F., Garcés A., et al. Simple, versatile, and efficient catalysts for guanylation of amines. Organometallics 2010, 29:2789.
355. Kempe R. Rare earth polymerization catalysts supported by bulky aminopyridinato ligands. Z Anorg Allg Chem 2010, 636:2135.
356. Edelmann F.T. Homogeneous catalysis using lanthanide amidinates and guanidinates. Struct Bonding 2010, 137:109.
357. Liu D., Cui D. Highly trans-1,4 selective (co-)polymerization of butadiene and isoprene with quinolyl anilido rare earth metal bis(alkyl) precursors. Dalton Trans 2011, 40:7755.
358. Luo Y., Fan S., Yang J., Fang J., Xu P. Rare earth metal bis(amide) complexes bearing amidinate ancillary ligands: synthesis, characterization, and performance as catalyst precursors for cis-1,4 selective polymerization of isoprene. Dalton Trans 2011, 40:3053.
359. Yang Y., Wang Q., Cui D. Isoprene polymerization with indolide-imine supported rare-earth metal alkyl and amidinate complexes. J Polym Sci A Polym Chem 2008, 46:5251.
360. Luo Y., Xu P., Lei Y., Zhang Y., Wang Y. Synthesis, characterization and l-lactide polymerization behavior of bis(amidinate) rare earth metal amide complexes. Inorg Chim Acta 2010, 363:3597.
361. Yang J., Xu P., Luo Y. Bimetallic rare earth alkyl complexes bearing bridged amidinate ligands: synthesis and activity for l-lactide polymerization. Chin J Chem 2010, 28:457.
362. Liu B., Cui D. Polymerization of 2,2'-dimethyltrimethylene carbonate by lutetium complexes bearing amino-phosphine ligands. J Appl Polym Sci 2009, 112:3110.
363. Han F., Teng Q., Zhang Y., Wang Y., Shen Q. Influence of Schiff base and lanthanide metals on the synthesis, stability, and reactivity of monoamido lanthanide complexes bearing two Schiff bases. Inorg Chem 2011, 50:2634.
364. 2 as a novel precatalyst for addition of amines to carbodiimides: influence of aryloxide group. Inorg Chem 2011, 50:3729.
365. Zhu X., Xu F., Chen Q. An efficient guanylation of aromatic amines catalyzed by samarium diiodide. Chin J Chem 2009, 27:19.
366. Du Z., Li W., Zhu X., Xu F., Shen Q. Divalent lanthanide complexes: highly active precatalysts for the addition of N-H and C-H bonds to carbodiimides. J Org Chem 2008, 73:8966.
367. Liu C., Zhou S., Wang S., Zhang L., Yang G. Rare earth metal bis(trimethylsilyl)amido complexes bearing pyrrolyl-methylamide ligand. Synthesis, structure, and catalytic activity towards guanylation of amines. Dalton Trans 2010, 39:8994.
368. Wu Y., Wang S., Zhang L., et al. Efficient guanylation of aromatic and heterocyclic amines catalyzed by cyclopentadienyl-free rare earth metal amides. Inorg Chim Acta 2009, 362:2814.
369. Wang J., Li J., Xu F., Shen Q. Anionic bridged bis(amidinate) lithium lanthanide complexes: efficient bimetallic catalysts for mild amidation of aldehydes with amines. Adv Synth Catal 2009, 351:1363.
370. Qian C., Zhang X., Li J., Xu F., Zhang Y., Shen Q. Trisguanidinate lanthanide complexes: syntheses, structures, and catalytic activity for mild amidation of aldehydes with amines. Organometallics 2009, 28:3856.
371. Ge S., Meetsma A., Hessen B. Highly efficient hydrosilylation of alkenes by organoyttrium catalysts with sterically demanding amidinate and guanidinate ligands. Organometallics 2008, 27:3131.
372. Brazeau A.L., Barry S.T. Atomic layer deposition of aluminum oxide thin films from a heteroleptic amidinate-containing precursor. Chem Mater 2008, 20:7287.
373. 2: an investigation of reactive species by matrix-isolation FTIR spectroscopy and time-of-flight mass spectrometry. Polyhedron 2008, 27:1832.
374. 3 thin films from a tris-guanidinate indium precursor. Dalton Trans 2011, 40:9425.
375. 3 thin films. J Nanosci Nanotechnol 2011, 11:8094.
376. Chen T., Hunks W., Chen P.S., et al. Insertion reactions of an aminogermylene and formation of a single-source precursor for GeTe thin films. Eur J Inorg Chem 2009, 2009:2047.
377. Chen T., Hunks W., Chen P.S., Xu C., DiPasquale A.G., Rheingold A.L. Synthesis, structural characterization, and thermal properties of the first germanium N, N, N', N'-tetraalkylguanidinates. Organometallics 2010, 29:501.
378. Wasslen Y.A., Tois E., Haukka S., et al. A family of heteroleptic titanium guanidinates: synthesis, thermolysis, and surface reactivity. Inorg Chem 2010, 49:1976.
379. 2 thin films from All-N-coordinated Ti precursors for photoelectrochemical applications. Chem Vapor Depos 2013, 19:45.
380. 2. Eur J Inorg Chem 2010, 2010:1679.
381. Xu K., Milanov A.P., Devi A. Tuning the thermal properties of hafnium precursors by tailoring the ligands. ECS Trans 2009, 25:625.
382. Lee B., Choi K.J., Hande A., et al. A novel thermally-stable zirconium amidinate ALD precursor for ZrO2 thin films. Microelectron Eng 2009, 86:272.
383. 2 thin films deposited by MOCVD techniques. ECS Trans 2009, 25:901.
384. 2Cl. ECS Transactions 2009, 25:561-565. Electrochemical Socity, Pennington, NJ.
385. Potts S.E., Carmalt C.J., Blackman C.S., Abou-Chahine F., Pugh D., Davies H.O. Synthesis of zirconium guanidinate complexes and the formation of zirconium carbonitride via low pressure CVD. Organometallics 2009, 28:1838.
386. 2 films via liquid injection-MOCVD. ECS Trans 2009, 25:151.
387. 2 thin films employing a heteroleptic hafnium precursor. Chem Vapor Depos 2012, 18:27.
388. Barreca D., Milanov A., Fischer R.A., Devi A., Tondello E. Surf Sci Spectra 2007, 14:34.
389. 2 thin film. Polyhedron 2010, 29:2522.
390. Baunemann A., Bekermann D., Thiede T.B., et al. Mixed amido/imido/guanidinato complexes of niobium: potential precursors for MOCVD of niobium nitride thin films. Dalton Trans 2008, 3715.
391. Bekermann D., Barreca D., Devi A., Gasparotto A., Fischer R. MOCVD of niobium nitrides and oxy-nitrides using an all-nitrogen-coordinated precursor: thin-film deposition and mechanistic study. ECS Trans 2008, 16:235.
392. Prieur T., Brizé V., Cornier T., et al. Conformal atomic layer deposition of TA-based diffusion barrier film using a novel mono-guanidinate precursor. J Nanosci Nanotechnol 2011, 11:8383.
393. Chen T., Xu C., Baum T.H., et al. New tantalum amido complexes with chelate ligands as metalorganic (MO) precursors for chemical vapor deposition (CVD) of tantalum nitride thin films. Chem Mater 2010, 22:27.
394. Thiede T., Gwildies V., Alsamann L., Rische D., Fischer R. Novel precursors for the MOCVD of molybdenum nitride. ECS Trans 2009, 25:593.
395. Gwildies V., Thiede T.B., Amirjalayer S., Alsamman L., Devi A., Fischer R.A. All-nitrogen coordinated amidinato/imido complexes of molybdenum and tungsten: syntheses and characterization. Inorg Chem 2010, 49:8487.
396. 2)NiPr]. J Vac Sci Technol B 2008, B26:1800.
397. 2)NiPr] for chemical vapor deposition of tungsten carbonitride films. Bull Korean Chem Soc 2010, 31:2416.
398. Cwik S., Milanova A.P., Gwildies V., et al. Engineered tungsten oxy-nitride thin film materials for photocatalytical water splitting fabricated by MOCVD. ECS Trans 2010, 28:159.
399. Krisyuk V., Gleizes A.N., Aloui L., et al. Chemical vapor deposition of iron, iron carbides, and iron nitride films from amidinateprecursors. ECS Trans 2010, 157:D454.
400. Li H., Aaltonen T., Li Z., Lim B.S., Gordon R.G. Synthesis and characterization of ruthenium amidinate complexes as precursors for vapor deposition. Open In Chem J 2008, 2:11.
401. Wang H., Gordon R.G., Alvis R., Ulfig R.M. Atomic layer deposition of ruthenium thin films from an amidinate precursor. Chem Vapor Depos 2009, 15:312.
402. Li Z., Lee D.K., Coulter M., Rodriguez L.N.J., Gordon R.G. Synthesis and characterization of volatile liquid cobalt amidinates. Dalton Trans 2008, 2592.
403. Peng T., Bi H., Liu Y., et al. Very high-efficiency red-electroluminescence devices based on an amidinate-ligated phosphorescent iridium complex. J Mater Chem 2009, 19:8072.
404. Peng T., Li G., Ye K., et al. Highly efficient phosphorescent OLEDs with host-independent and concentration-insensitive properties based on a bipolar iridium complex. J Mater Chem C 2013, 1:2929.
405. Li Z., Gordon R.G., Pallem V., Li H., Shenai D.V. Direct-liquid-injection chemical vapor deposition of nickel nitride films and their reduction to nickel films. Chem Mater 2010, 22:3060.
406. Lin J.-M., Teplyakov A.V., Rodriguez-Reyes J.C.F. Competing reactions during metalorganic deposition: Ligand exchange versus direct reaction with the substrate surface. J Vac Sci Technol 2013, A31:021401.
407. Coyle J.P., Monillas W.H., Yap G.P.A., Barry S.T. Synthesis and thermal chemistry of copper (I) guanidinates. Inorg Chem 2008, 47:683.
408. Coyle J.P., Johnson P.A., DiLabio G.A., Barry S.T., Müller J. Gas-phase thermolysis of a guanidinate precursor of copper studied by matrix isolation, time-of-flight mass spectrometry, and computational chemistry. Inorg Chem 2010, 49:2844.
409. Whitehorne T.J.J., Coyle J.P., Mahmood A., Monillas W.H., Yap G.P.A., Barry S.T. Group 11 amidinates and guanidinates: potential precursors for vapour deposition. Eur J Inorg Chem 2011, 2011:3240.
410. Dai M., Kwon J., Halls M.D., Gordon R.G., Chabal Y.J. Surface and interface processes during atomic layer deposition of copper on silicon oxide. Langmuir 2010, 26:3911.
411. Krisyuk V., Aloui L., Prud'Homme N., et al. CVD of pure copper films from amidinate precursor. ECS Trans 2009, 25:581.
412. Krisyuk V., Aloui L., Prud'Homme N., et al. CVD of pure copper films from amidinate precursor. Electrochem Solid State Lett 2011, 14:D26.
413. Kim H., Bhandari H.B., Xu S., Gordon R.G. Ultrathin CVD Cu seed layer formation using copper oxynitride deposition and room temperature remote hydrogen plasma reduction. ECS Trans 2008, 155:H496.
414. Coyle J.P., Pallister P.J., Kurek A., Sirianni E.R., Yap G.P.A., Barry S.T. Copper iminopyrrolidinates: a study of thermal and surface chemistry. Inorg Chem 2013, 52:910.
415. Barrière C., Piettre K., Latour V., et al. Ligand effects on the air stability of copper nanoparticles obtained from organometallic synthesis. J Mater Chem 2012, 22:2279.
416. Shao L.-Y., Coyle J.P., Barry S.T., Albert J. Anomalous permittivity and plasmon resonances of copper nanoparticle conformal coatings on optical fibers. Opt Mater Express 2011, 1:128.
417. Lim B.S., Rahtu A., Gordon R.G. Atomic layer deposition of transition metals. Nat Mater 2003, 2:749.
418. Lim B.S., Rahtu A., Park J.-S., Gordon R.G. Synthesis and characterization of volatile, thermally stable, reactive transition metal amidinates. Inorg Chem 2003, 42:7951.
419. 3 thin film growth by atomic layer deposition. J Mater Chem 2005, 15:4224.
420. 3Ln (Ln = Ce, Eu, Tb). Z Anorg Allg Chem 2011, 637:186.
421. Milanov A.P., Fischer R.A., Devi A. Synthesis, characterization, and thermal properties of homoleptic rare-earth guanidinates: promising precursors for MOCVD and ALD of rare-earth oxide thin films. Inorg Chem 2008, 47:11405.
422. Milanov A.P., Thiede T., Hellwig M., et al. Rare-earth based oxide and nitride thin films employing volatile homoleptic guanidinate precursors. ECS Trans 2009, 25:143.
423. Milanov A.P., Thiede T.B., Devi A., Fischer R.A. Homoleptic gadolinium guanidinate: a single source precursor for metal-organic chemical vapor deposition of gadolinium nitride thin films. J Am Chem Soc 2009, 131:17062.
424. Thiede T.B., Krasnopolski M., Milanov A.P., et al. Evaluation of homoleptic guanidinate and amidinate complexes of gadolinium and dysprosium for mocvd of rare-earth nitride thin films. Chem Mater 2011, 23:1430.
425. Krasnopolski M., Hrib C.G., Seidel R.W., et al. Homoleptic gadolinium amidinates as precursors for MOCVD of oriented gadolinium nitride (GdN) thin films. Inorg Chem 2013, 52:286.
426. Kwon J., Dai M., Halls M.D., Langereis E., Chabal Y.J., Gordon R.G. In situ infrared characterization during atomic layer deposition of lanthanum oxide. J Phys Chem 2009, 113:654.
427. Milanov A.P., Toader T., Parala H., et al. Lanthanide oxide thin films by metalorganic chemical vapor deposition employing volatile guanidinate precursors. Chem Mater 2009, 21:5443.
428. 3 thin films by MOCVD from volatile guanidinate class of rare-earth precursors. Dalton Trans 2012, 41:13936.
429. 3: a study of the ALD characteristics and structural and electrical properties. Chem Mater 2012, 24:651.
430. 2O-assisted atomic layer deposition. J Am Chem Soc 2010, 132:36.
431. 2O assisted atomic layer deposition. Semicond Sci Technol 2010, 25:105001.
432. 2 thin films grown by metalorganic chemical vapor deposition. Thin Solid Films 2012, 520:4512.