Synthesis of molecular gallium hydrides by means of low-temperature catalytic dehydrogenation

European Journal of Inorganic Chemistry

Volumn , Issue 14, 2012, Pages 2368-2372

  Rudolf, Daniel ^a   Storch, Golo ^a   Kaifer, Elisabeth ^a   Himmel, Hans Jörg ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

Dehydrogenation; Gallium; Guanidine; Hydrides; Structure elucidation

Indexed keywords

DEHYDROGENATION; GALLIUM COMPOUNDS; QUANTUM CHEMISTRY; SYNTHESIS (CHEMICAL); TEMPERATURE;

CATALYTIC DEHYDROGENATION; GUANIDINE; LOWS-TEMPERATURES; QUANTUM CHEMICAL CALCULATIONS; QUANTUM-CHEMICAL CALCULATION; STRUCTURE ELUCIDATION; TEMPERATURE SENSITIVE; ]+ CATALYST;

HYDRIDES;

EID: 84860723199     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201200102     Document Type: Article

References (42)

1. F. H. Stephens, V. Pons, R. T. Baker, Dalton Trans. 2007, 2613-2626.
2. T. B. Marder, Angew. Chem. 2007, 119, 8262-8264;
3. Angew. Chem. Int. Ed. 2007, 46, 8116-8118.
4. C. W. Hamilton, R. T. Baker, A. Staubitz, I. Manners, Chem. Soc. Rev. 2009, 38, 279-293.
5. U. B. Demirci, P. Miele, Energy Environ. Sci. 2009, 2, 627-637.
6. A. Staubitz, A. P. M. Robertson, I. Manners, Chem. Rev. 2010, 110, 4079-4124.
7. G. Alcaraz, S. Sabo-Etienne, Angew. Chem. 2010, 122, 7326-7335;
8. Angew. Chem. Int. Ed. 2010, 49, 7170-7179.
9. N. C. Smythe, J. C. Gordon, Eur. J. Inorg. Chem. 2010, 509-521.
10. n. In this case, amines were postulated as catalysts on the basis of a mechanistic analysis. See:, J. A. Jegier, S. McKernan, W. L. Gladfelter, Inorg. Chem. 1999, 38, 2726-2733.
11. See: The Group 13 Metals Aluminium, Gallium, Indium and Thallium: Chemical Patterns and Peculiarities (Eds.:, A. J. Downs S Aldrige,), Wiley, 2011, chapter 2. and references given therein.
12. F. A. Cotton, C. A. Murillo, X. Wang, C. C. Wilkinson, Inorg. Chem. 2006, 45, 5493-5500.
13. R. Dinda, O. Ciobanu, H. Wadepohl, O. Hübner, R. Acharraya, H.-J. Himmel, Angew. Chem. 2007, 119, 9270-9273;
14. Angew. Chem. Int. Ed. 2007, 46, 9110-9113.
15. O. Ciobanu, E. Kaifer, H.-J. Himmel, Angew. Chem. 2009, 121, 5646-5649;
16. Angew. Chem. 2009, 48, 5538-5541.
17. N. Schulenberg, H. Wadepohl, H.-J. Himmel, Angew. Chem. 2011, 123, 19628-19631;
18. Angew. Chem. Int. Ed. 2011, 50, 10444-10447.
19. G. Robinson, C. Y. Tang, R. Köppe, A. R. Cowley, H.-J. Himmel, Chem. Eur. J. 2007, 13, 2648-2654.
20. D. Rudolf, E. Kaifer, H.-J. Himmel, Eur. J. Inorg. Chem. 2010, 4952-4961.
21. C. A. Jaska, K. Temple, A. J. Lough, I. Manners, Chem. Commun. 2001, 962-963.
22. C. A. Jaska, K. Temple, A. J. Lough, I. Manners, J. Am. Chem. Soc. 2003, 125, 9424-1934.
23. C. A. Jaska, I. Manners, J. Am. Chem. Soc. 2004, 126, 9776-9785.
24. Y. D. Blum, R. M. Laine, US Pat. 4801439, 1989.
25. N. Schulenberg, O. Ciobanu, E. Kaifer, H. Wadepohl, H.-J. Himmel, Eur. J. Inorg. Chem. 2010, 5201-5210.
26. Y.-J. Lee, J.-D. Lee, S.-J. Kim, S. Keum, J. Ko, I.-H. Suh, M. Cheong, S. O. Kang, Organometallics 2004, 23, 203-214.
27. Y.-J. Lee, J.-Y. Bae, S.-J. Kim, J. Ko, M.-G. Choi, S. O. Kang, Organometallics 2000, 19, 5546-5548.
28. R. J. Keaton, J. M. Blacquiere, R. T. Baker, J. Am. Chem. Soc. 2007, 129, 1844-185.
29. S.-K. Kim, W.-S. Han, T.-J. Kim, T.-Y. Kim, S. W. Nam, M. Mitoraj, Ś. Pieko, A. Michalak, S.-J. Hwang, S. O. Kang, J. Am. Chem. Soc. 2010, 132, 9954-9955.
30. I. Göttker-Schnetmann, P. White, M. Brookhart, J. Am. Chem. Soc. 2004, 126, 1804-1811.
31. I. Göttker-Schnetmann, P. White, M. Brookhart, Organometallics 2004, 23, 1766-1776.
32. M. C. Denney, V. Pons, T. J. Hebden, D. M. Heinekey, K. I. Goldberg, J. Am. Chem. Soc. 2006, 128, 12048-12049.
33. D. F. Shriver, A. E. Shirk, Inorg. Synth. 1977, 17, 42-45.
34. B. Luo, V. G. Young Jr., W. L. Gladfelter, Inorg. Chem. 2000, 39, 1705-1709.
35. S. D. Nogai, H. Schmidbaur, Organometallics 2004, 23, 5877-5880.
36. 3 and Lewis bases).
37. H.-J. Himmel, A. J. Downs, T. M. Greene, Chem. Commun. 2000, 871-872.
38. H.-J. Himmel, A. J. Downs, T. M. Greene, J. Am. Chem. Soc. 2000, 122, 9793-9807.
39. P. L. Baxter, A. J. Downs, D. W. H. Rankin, H. E. Robertson, J. Chem. Soc., Dalton Trans. 1985, 807-814.
40. J. P. Campell, J.-W. Hwang, V. G. Young Jr., R. B. Dreele, C. J. Cramer, W. L. Gladfelter, J. Am. Chem. Soc. 1998, 120, 521-531.
41. G. R. Fulmer, A. J. M. Miller, N. H. Sherden, H. E. Gottlieb, A. Nudelman, B. M. Stoltz, J. E. Bercaw, K. I. Goldberg, Organometallics 2010, 29, 2176-2179.
42. For more information on these species, see:, O. Ciobanu, H.-J. Himmel, Eur. J. Inorg. Chem. 2007, 3565-3572.