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Volumn 31, Issue 9, 2012, Pages 3730-3735

Unusual Si-H bond activation and formation of cationic scandium amide complexes from a mono(amidinate)-ligated scandium bis(silylamide) complex and their performance in isoprene polymerization

Author keywords

[No Author keywords available]

Indexed keywords

AMIDE COMPLEXES; AMIDINATES; CATALYST SYSTEM; HETEROMETALLICS; ISOLATED YIELD; METHYL COMPLEXES; SI-H BONDS;

EID: 84861109393     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om3002119     Document Type: Article
Times cited : (49)

References (26)
  • 17
    • 34250661343 scopus 로고    scopus 로고
    • For examples of diene polymerization catalyzed by rare-earth-metal amide complexes as catalyst precursors, see: and refs 2d, 3, 4, and 11
    • For examples of diene polymerization catalyzed by rare-earth-metal amide complexes as catalyst precursors, see: Fischbach, A.; Anwander, R. Adv. Polym. Sci. 2006, 204, 155 and refs 2d, 3, 4, and 11
    • (2006) Adv. Polym. Sci. , vol.204 , pp. 155
    • Fischbach, A.1    Anwander, R.2
  • 18
    • 49649101632 scopus 로고    scopus 로고
    • While organolanthanide-catalyzed silanolytic chain transfer involving a Si-H σ-bond activation step has been well documented, in contrast, the mechanism of Si-H σ-bond activation in this case has not been reported previously to our knowledge; see
    • While organolanthanide-catalyzed silanolytic chain transfer involving a Si-H σ-bond activation step has been well documented, in contrast, the mechanism of Si-H σ-bond activation in this case has not been reported previously to our knowledge; see: Amin, S. B.; Marks, T. J. Angew. Chem., Int. Ed. 2008, 47, 2006
    • (2008) Angew. Chem., Int. Ed. , vol.47 , pp. 2006
    • Amin, S.B.1    Marks, T.J.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.