Stereoselective production of poly(rac-lactide) by ROP with highly efficient bulky heteroscorpionate alkylmagnesium initiators

Organometallics

Volumn 30, Issue 10, 2011, Pages 2775-2789

  Sánchez Barba, Luis F ^a   Garcés, Andrés ^a   Fernández Baeza, Juan ^b   Otero, Antonio ^b   Alonso Moreno, Carlos ^b   Lara Sánchez, Agustín ^b   Rodríguez, Ana M ^b  

^a UNIVERSIDAD REY JUAN CARLOS   (Spain)

^b UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUPS; AMIDINATES; CAPROLACTONE; CATALYST CONCENTRATION; COORDINATION MODES; FIRST-ORDER DEPENDENCE; GOOD YIELD; H NMR SPECTROSCOPY; HIGH YIELD; HIGH-MOLECULAR WEIGHT POLYMERS; LACTIDES; LOW TEMPERATURES; MAGNESIUM COMPLEXES; METAL CENTERS; MICROSTRUCTURAL ANALYSIS; NUMBER AVERAGE MOLECULAR WEIGHT; POLY(RAC-LACTIDE); POLYMERIZATION RATES; PROTONOLYSIS; RAC-LACTIDE; RATE OF POLYMERIZATION; SINGLE CRYSTAL X-RAY STRUCTURES; STEREO-SELECTIVE; STRUCTURAL ISOMERS;

ISOMERS; LITHIUM; MAGNESIUM; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYDISPERSITY; RING OPENING POLYMERIZATION; STEREOSELECTIVITY;

POLYMERS;

EID: 79956070981     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om200163t     Document Type: Article

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