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Volumn 47, Issue 51, 2008, Pages 9933-9936

Quintuply-bonded dichromium(I) complexes featuring metal-metal bond lengths of 1.74 Å

Author keywords

Chromium; Density functional calculations; Metal metal interactions; Multiple bonds; N ligands

Indexed keywords

CHEMICAL BONDS; CHEMICAL REACTIONS; CHROMIUM; CHROMIUM COMPOUNDS; DENSITY FUNCTIONAL THEORY; ELECTRONIC STRUCTURE; FLOW INTERACTIONS; LIGANDS; SULFUR COMPOUNDS;

EID: 57649140716     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200803859     Document Type: Article
Times cited : (134)

References (31)
  • 19
    • 57649116566 scopus 로고    scopus 로고
    • A similar quintuple-bonded dichromium complex, supported by two sterically encumbered amidopyridines, was reported online by Kempe et al. seven days after we submitted this manuscript for publication. A. Noor, F. R. Wagner, R. Kempe, Angew. Chem. 2008, 120, 7356;
    • A similar quintuple-bonded dichromium complex, supported by two sterically encumbered amidopyridines, was reported online by Kempe et al. seven days after we submitted this manuscript for publication. A. Noor, F. R. Wagner, R. Kempe, Angew. Chem. 2008, 120, 7356;
  • 21
    • 57649119040 scopus 로고    scopus 로고
    • Crystallographic data for 1c: C33H51Cl 2N2O2Cr, Mr, 630.66; T, 200(2) K; monoclinic; space group C2/c, a, 17.6101(4, b, 8.9222(2, c=22.4384(6) Å; β, 108.3720(10)°; V, 3345.84(14) Å3, Z, 4; ρcalcd, 1.252 Mgm-3; m, 0.532 mm-1; reflections measured: 13450, independent reflections: 3037 (Rint, 0.0992, final R indices [I > 2σ(I, R1, 0.0672, wR2, 0.1806; R indices (all data, R1, 0.0858, wR2, 0.1987. 2a·0.5 n-hexane: C41H53N 4Cr2, Mr, 705.87; T, 150(2) K; trigonal; space group R3c, a, 33.8181(5, b, 33.8181(5, c, 19.1232(2) Å
    • 2 = 0.1461. CCDC 694478 (1c), 694479 (2a), 695882 (2b), 694480 (2c), and 694481 (2d) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 22
    • 57649122146 scopus 로고    scopus 로고
    • 2].
    • 2].
  • 29
    • 57649125375 scopus 로고    scopus 로고
    • See the Supporting Information
    • See the Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.