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A similar quintuple-bonded dichromium complex, supported by two sterically encumbered amidopyridines, was reported online by Kempe et al. seven days after we submitted this manuscript for publication. A. Noor, F. R. Wagner, R. Kempe, Angew. Chem. 2008, 120, 7356;
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A similar quintuple-bonded dichromium complex, supported by two sterically encumbered amidopyridines, was reported online by Kempe et al. seven days after we submitted this manuscript for publication. A. Noor, F. R. Wagner, R. Kempe, Angew. Chem. 2008, 120, 7356;
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Crystallographic data for 1c: C33H51Cl 2N2O2Cr, Mr, 630.66; T, 200(2) K; monoclinic; space group C2/c, a, 17.6101(4, b, 8.9222(2, c=22.4384(6) Å; β, 108.3720(10)°; V, 3345.84(14) Å3, Z, 4; ρcalcd, 1.252 Mgm-3; m, 0.532 mm-1; reflections measured: 13450, independent reflections: 3037 (Rint, 0.0992, final R indices [I > 2σ(I, R1, 0.0672, wR2, 0.1806; R indices (all data, R1, 0.0858, wR2, 0.1987. 2a·0.5 n-hexane: C41H53N 4Cr2, Mr, 705.87; T, 150(2) K; trigonal; space group R3c, a, 33.8181(5, b, 33.8181(5, c, 19.1232(2) Å
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2 = 0.1461. CCDC 694478 (1c), 694479 (2a), 695882 (2b), 694480 (2c), and 694481 (2d) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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