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Volumn 255, Issue 1-2, 2011, Pages 118-138

Polymerization catalysis with transition metal amidinate and related complexes

Author keywords

Amidinate; Diene; Lactone; Metal; Olefin; Polymerization

Indexed keywords


EID: 78649463987     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ccr.2010.07.005     Document Type: Review
Times cited : (150)

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    • Patent applications claim such complexes though no examples were provided: (a) J. X. Liu, U.S. Patent 6,239,239 (2001) 4 pp; (b) J. X. Liu, U.S. Patent 6,020,493
    • Patent applications claim such complexes though no examples were provided: (a) J. X. Liu, U.S. Patent 6,239,239 (2001) 4 pp; (b) J. X. Liu, U.S. Patent 6,020,493 (2000) 4 pp.
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    • See also Refs. [7] and [20,21] for earlier studies of propene polymerization using [RC(NR')2] complexes.
    • See also Refs. [7] and [20,21] for earlier studies of propene polymerization using [RC(NR')2] complexes.
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    • 2] ligands were linked at C and no structures were reported. All of the complexes furnished high density PE upon activation with MAO. Ethylene-hexene copolymers were prepared and had, 012568
    • 2] ligands were linked at C and no structures were reported. All of the complexes furnished high density PE upon activation with MAO. Ethylene-hexene copolymers were prepared and had multi-modal MWD. Propene was homopolymerized but there is no indication in the patent as to its tacticity. See.
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    • See also Ref. [40a] for styrene polymerization using mono-pyridine-thiolate complexes of Ti.
    • See also Ref. [40a] for styrene polymerization using mono-pyridine-thiolate complexes of Ti.
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    • The earliest patent application (K. Shibayama, M. Ogasa, PCT Int. Appl. 35996 pp.cf. Can Pat. 2,281,540) indicates that substituted styrenes with a polarity value e≤-1.5 are also susceptible to polymerization and provides two examples of styrene polymerization featuring 40% conversion in one case. Evidently, the negative results for styrene reported in
    • The earliest patent application (K. Shibayama, M. Ogasa, PCT Int. Appl. 35996 (1998) 28 pp. cf. Can Pat. 2,281,540) indicates that substituted styrenes with a polarity value e≤-1.5 are also susceptible to polymerization and provides two examples of styrene polymerization featuring 40% conversion in one case. Evidently, the negative results for styrene reported in more recent published work [119] suggests failure to reproduce these earlier results.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.