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Volumn 50, Issue 4, 2011, Pages 1258-1264

Tuning the electrochemistry of Re26+ species with divergent bicyclic guanidinate ligands and by modification of axial π interactions

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EID: 79951600542     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic101890p     Document Type: Article
Times cited : (9)

References (75)
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    • For the ligands tbn and tbo, the first name follows the von Baeyer nomenclature, while the second one is the IUPAC name. For a discussion on the nomenclature, see:, and references therein
    • For the ligands tbn and tbo, the first name follows the von Baeyer nomenclature, while the second one is the IUPAC name. For a discussion on the nomenclature, see: Coles, M. P. Chem. Commun. 2009, 3659 and references therein
    • (2009) Chem. Commun. , pp. 3659
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    • 5+ systems with chloride and triflate axial ligands, which were carried out using variable temperature structural studies and EPR spectroscopy as well as DFT calculations, also support this view. See:, and Unpublished results
    • 5+ systems with chloride and triflate axial ligands, which were carried out using variable temperature structural studies and EPR spectroscopy as well as DFT calculations, also support this view. See: Chiarella, G. M., Cotton, F. A., Murillo, C. A., Villagrán, D., Young, M. D., and Wang, X. Unpublished results.
    • Chiarella, G.M.1    Cotton, F.A.2    Murillo, C.A.3    Villagrán, D.4    Young, M.D.5    Wang, X.6
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    • note
    • + cation as shown in ref 21 and references therein. In this type of compounds, the oxidation has been shown unambiguously by EPR measurements to be metal-centered.
  • 64
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    • note
    • 2 for which no oxidation processes are observed and show only two reduction waves at about 0.0 and-1 V. See Table 8.2 on page 306 in ref 1.
  • 65
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    • These studies are ongoing in the Dalal and Murillo's laboratories, and the results will be published elsewhere
    • These studies are ongoing in the Dalal and Murillo's laboratories, and the results will be published elsewhere.
  • 66
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    • For additional discussion, see pages 744-755 in ref 9a
    • For additional discussion, see pages 744-755 in ref 9a.
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    • As for some of the Ru analogues, many attempts were made to obtain elemental analyses including nitrogen. Without exception, the expected percentages for carbon and hydrogen composition were satisfactory but the percentage for nitrogen was consistently low because metal nitrides often form during combustion. See ref 22
    • As for some of the Ru analogues, many attempts were made to obtain elemental analyses including nitrogen. Without exception, the expected percentages for carbon and hydrogen composition were satisfactory but the percentage for nitrogen was consistently low because metal nitrides often form during combustion. See ref 22.
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    • Because of solubility limitations and the weakness of some bands, the band observed in others compounds at around 410 nm was not measured for 3
    • Because of solubility limitations and the weakness of some bands, the band observed in others compounds at around 410 nm was not measured for 3.
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    • As noted by a reviewer, because of disorder in the tbn compounds, it is likely that the unsymmetrical rings can bind in various ways giving raise to isomers. Indeed, evidence for isomers in Mo analogues has been provided by electron photoelectron spectra. See ref 18b. The presence of such isomers would not impact the discussion of the results presented here
    • As noted by a reviewer, because of disorder in the tbn compounds, it is likely that the unsymmetrical rings can bind in various ways giving raise to isomers. Indeed, evidence for isomers in Mo analogues has been provided by electron photoelectron spectra. See ref 18b. The presence of such isomers would not impact the discussion of the results presented here.


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