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4
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32944475750
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The coordination chemistry of neutral amidines and guanidines was recently described: Coles, M. P
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The coordination chemistry of neutral amidines and guanidines was recently described: Coles, M. P. J. Chem. Soc., Dalton Trans. 2006, 985.
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(a) Coles, M. P.; Swenson, D. C; Jordan, R. F.; Young, V. G., Jr. Organometallics 1997, 16, 5183.
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Coles, M.P.1
Swenson, D.C.2
Jordan, R.F.3
Young Jr., V.G.4
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(d) Dagome, S.; Guzei, I. A.; Coles, M. P.; Jordan, R. F. J. Am. Chem. Soc. 2000, 122, 274.
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See the following and references cited therein
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See the following and references cited therein: Baunemann, A.; Bekermann, D.; Thiede, T. B.; Parala, H.; Winter, M.; Gemel, C.; Fischer, R. A. J. Chem. Soc., Dalton Trans. 2008, 3715.
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Baunemann, A.1
Bekermann, D.2
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Parala, H.4
Winter, M.5
Gemel, C.6
Fischer, R.A.7
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10
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0000864456
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See the following and references cited therein: a
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See the following and references cited therein: (a) Sita, L. R.; Babcock, J. R. Organometallics 1998, 17, 5228.
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Sita, L.R.1
Babcock, J.R.2
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0035128037
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(b) Tunge, J. A.; Czerwinski, C J.; Gately, D. A.; Norton, J. R. Organometallics 2001, 20, 254.
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Tunge, J.A.1
Czerwinski, C.J.2
Gately, D.A.3
Norton, J.R.4
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Xia, A.; E1-Kaderi, H. M.; Heeg, M. J.; Winter, C. H. J. Organomet. Chem. 2003, 682, 224.
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(c)Xia, A.; E1-Kaderi, H. M.; Heeg, M. J.; Winter, C. H. J. Organomet. Chem. 2003, 682, 224.
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14
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85178832354
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Only a handful of benzamidinate, formamidinate, and boraamidinate complexes have been structurally characterized: (a) Buijink, J.-K.; Noltemeyer, M.; Edelmann, F. T. Z. Naturforsch. B 1991, 46, 1328.
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Only a handful of benzamidinate, formamidinate, and boraamidinate complexes have been structurally characterized: (a) Buijink, J.-K.; Noltemeyer, M.; Edelmann, F. T. Z. Naturforsch. B 1991, 46, 1328.
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15
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0002610405
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(b) Cotton, F. A.; Daniels, L. M.; Falvello, L. R.; Matonic, J. H.; Murillo, C. A.; Wang, X.; Zhou, H. Inorg. Chim. Acta 1997, 266, 91.
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Cotton, F.A.1
Daniels, L.M.2
Falvello, L.R.3
Matonic, J.H.4
Murillo, C.A.5
Wang, X.6
Zhou, H.7
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16
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(c)Cole, M. L.; Evans, D. J.; Junk, P. C; Louis, L. M. New J. Chem. 2002, 26,1015.
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Cole, M.L.1
Evans, D.J.2
Junk, P.C.3
Louis, L.M.4
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17
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33645075463
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(d)Chivers, T.; Eisler, D. J.; Fedorchuk, C.; Schatte, G.; Tuononen, H. M. Inorg. Chem. 2006, 45, 2119.
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Inorg. Chem
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Chivers, T.1
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Tuononen, H.M.5
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(e) Fedorchuk, C.; Copsey, M.; Chivers, T. Coord. Chem. Rev. 2007, 251, 897.
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Coord. Chem. Rev
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Fedorchuk, C.1
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20
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68149091851
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(b) Birch, S. J.; Boss, S. R.; Cole, S. C; Coles, M. P.; Haigh, R.; Hitchcock, P. B.; Wheatley, A. E. H. J. Chem. Soc., Dalton Trans. 2004, 356.
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(2004)
J. Chem. Soc., Dalton Trans
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Birch, S.J.1
Boss, S.R.2
Cole, S.C.3
Coles, M.P.4
Haigh, R.5
Hitchcock, P.B.6
Wheatley, A.E.H.7
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21
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53849134133
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Eisenmann, T.; Khanderi, J.; Schulz, S.; Flörke, U. Z. Anorg. Allg. Chem. 2008, 634, 507.
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Eisenmann, T.1
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(a) Schulz, S.; Münch, M.; Flörke, U. Z. Anorg. Allg. Chem. 2008, 634, 2221.
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Anorg. Allg. Chem
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Schulz, S.1
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23
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(b) Münch, M.; Flörke, U.; Bolte, M.; Schulz, S.; Gudat, D. Angew. Chem. 2008, 120, 1535.;
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Angew. Chem
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Münch, M.1
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Gudat, D.5
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25
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68149092024
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2 with subsequent formation of elemental zinc.
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2 with subsequent formation of elemental zinc.
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68149129755
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2 was repeated several times, in all cases yielding mixtures of 1-5 with up to 5% 5. Single crystals of 5 (mixture together with 2) were isolated from different reaction batches after fractional crystallization from solutions in npentane at -30 °C and identified by single-crystal X-ray diffraction.
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2 was repeated several times, in all cases yielding mixtures of 1-5 with up to 5% 5. Single crystals of 5 (mixture together with 2) were isolated from different reaction batches after fractional crystallization from solutions in npentane at -30 °C and identified by single-crystal X-ray diffraction.
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68149089872
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The methine H atom (C1H) is the only resonance of the Cy group that clearly indicates the formation of multiple species since the resonances of other H atoms of this group (C2H-C6H) are rather broad and overlap.
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The methine H atom (C1H) is the only resonance of the Cy group that clearly indicates the formation of multiple species since the resonances of other H atoms of this group (C2H-C6H) are rather broad and overlap.
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28
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68149119357
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1H NMR spectroscopic studies, 5 was only formed in three different reactions when the carbodiimide was used as received. In contrast, no indication for the formation of 5 was found in reactions with purified carbodiimide.
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1H NMR spectroscopic studies, 5 was only formed in three different reactions when the carbodiimide was used as received. In contrast, no indication for the formation of 5 was found in reactions with purified carbodiimide.
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29
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68149136793
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2]ZnMe with strong bases such as organolithium compounds.
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2]ZnMe with strong bases such as organolithium compounds.
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30
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68149091662
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Schmidt, S.; Schulz, S.; Bolte, M.; Z. Anorg. Allg. Chem. 2009, in press.
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Schmidt, S.; Schulz, S.; Bolte, M.; Z. Anorg. Allg. Chem. 2009, in press.
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0000421979
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(a) Chang, C-C.; Hsiung, C-S.; Su, H.-L.; Srinivas, B.; Chiang, M. Y.; Lee, G.-H.; Wang, Y. Organometallics 1998, 17, 1595.
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Chang, C.-C.1
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Rowley, C. N.; DiLabio, G. A; Barry, S. T. Inorg. Chem. 2005, 44, 1983.
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(b)Rowley, C. N.; DiLabio, G. A; Barry, S. T. Inorg. Chem. 2005, 44, 1983.
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