Synthesis and structures of heteroleptic silylenes

Journal of the American Chemical Society

Volumn 129, Issue 39, 2007, Pages 12049-12054

  So, Cheuk Wai ^a   Roesky, Herbert W ^a   Gurubasavaraj, Prabhuodeyara M ^a   Oswald, Rainer B ^a   Gamer, Michael T ^b   Jones, Peter G ^c   Blaurock, Steffen ^d  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

^b FREIE UNIVERSITÄT BERLIN   (Germany)

^c TECHNICAL UNIVERSITY OF BRAUNSCHWEIG   (Germany)

^d OTTO VON GUERICKE UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

HETEROLEPTIC SILYLENE; MONONUCLEAR CHLOROSILYLENE;

AROMATIC COMPOUNDS; POTASSIUM; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

OLEFINS;

CHLORINE DERIVATIVE; CHLOROSILYLENE; POTASSIUM; SILANE DERIVATIVE; SILYLENE DERIVATIVE; TETRAHYDROFOLIC ACID; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; MOLECULAR STABILITY; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 34848848440     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja074019e     Document Type: Article

References (44)

1. (a) Haaf, M.; Schmedake, T. A.; West, R. Acc. Chem. Res. 2000, 33, 704.
2. (b) Hill, N. J.; West, R. J. Organomet. Chem. 2004, 689, 4165.
3. Denk, M.; Lennon, R.; Hayashi, R.; West, R.; Belyakov, A. V.; Verne, H. P.; Haaland, A.; Wagner, M.; Metzler, N. J. Am. Chem. Soc. 1994, 116, 2691.
4. (a) Gehrhus, B.; Lappert, M. F.; Heinicke, J.; Boese, R.; Bläser, D. J. Chem. Soc., Chem. Commun. 1995, 1931.
5. (b) West, R.; Denk, M. Pure Appl. Chem. 1996, 68, 785.
6. (c) Haaf, M.; Schmedake, T. A.; Paradise, B. J.; West, R. Can. J. Chem. 2000, 78, 1526.
7. (d) Heinicke, J.; Oprea, A.; Kindermann, M. K.; Karpati, T.; Nyulászi, L.; Veszprémi, T. Chem.-Eur. J. 1998, 4, 541.
8. (e) Kira, M.; Ishida, S.; Iwamoto, T.; Kabuto, C. J. Am. Chem. Soc. 1999, 121, 9722.
9. (f) Gehrhus, B.; Hitchcock, P. B.; Lappert, M. F. Z. Anorg. Allg. Chem. 2005, 631, 1383.
10. (g) Driess, M.; Yao, S.; Brym, M.; van Wüllen, C.; Lentz, D. J. Am. Chem. Soc. 2006, 128, 9628.
11. Schmeisser, M.; Voss, P. Z. Anorg. Allg. Chem. 1964, 334, 50.
12. (a) Moiseev, A. G.; Leigh, W. J. J. Am. Chem. Soc. 2006, 128, 14442.
13. (b) Levin, G.; Das, P. K.; Lee, C. L. Organometallics 1988, 7, 1231.
14. (c) Levin, G.; Das, P. K.; Bilgrien, C.; Lee, C. L. Organometallics 1989, 8, 1206.
15. (d) Tsutsui, S.; Sakamoto, K.; Kira, M. J. Am. Chem. Soc. 1998, 120, 9955.
16. (a) So, C.-W.; Roesky, H. W.; Magull, J.; Oswald, R. B. Angew. Chem., Int. Ed. 2006, 45, 3948.
17. (b) Auner, N., Weis, J., Eds. Organosilicon Chemistry V1; Wiley-VCH: Weinheim, Germany, 2005; pp 194-201.
18. Roesky, H. W.; Meller, B.; Noltemeyer, M.; Schmidt, H.-G.; Scholz, U.; Sheldrick, G. M. Chem. Ber. 1988, 121, 1403.
19. Karsch, H. H.; Schlüter, P. A.; Reisky, M. Eur. J. Inorg. Chem. 1998, 433.
20. (a) Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37, 785.
21. (b) Miehlich, B.; Savin, A.; Stoll, H.; Preuss, H. Chem. Phys. Lett. 1989, 157, 200.
22. (c) Vosko, S. H.; Wilk, L.; Nusair, M. Can. J. Phys. 1980, 58, 1200.
23. (d) Becke, A. D. J. Chem. Phys. 1993, 98, 5648.
24. Frisch, M. J.; et al. Gaussian 03, revision C.02; Gaussian, Inc.: Wallingford, CT, 2004. For the complete ref, see the Supporting Information.
25. Cella, J. A.; Cargioli, J. D.; Williams, E. A. J. Organomet. Chem. 1980, 186, 13.
26. (a) Ding, Y.; Ma, Q.; Roesky, H. W.; Herbst-Irmer, R.; Usón, I.; Noltemeyer, M.; Schmidt, H.-G. Organometallics 2002, 21, 5216.
27. (b) Ding, Y.; Hao, H.; Roesky, H. W.; Noltemeyer, M.; Schmidt, H.-G. Organometallics 2001, 20, 4806.
28. (c) Pineda, L. W.; Jancik, V.; Roesky, H. W.; Neculai, D.; Neculai, A. M. Angew. Chem., Int. Ed. 2004, 43, 1419.
29. (d) Pineda, L. W.; Jancik, V.; Starke, K.; Oswald, R. B.; Roesky, H. W. Angew. Chem., Int. Ed. 2006, 45, 2602.
30. Jutzi, P.; Keitemeyer, S.; Neumann, B.; Stammler, H.-G. Organometallics 1999, 18, 4778.
31. (a) Dias, H. V. R.; Wang, Z. J. Am. Chem. Soc. 1997, 119, 4650.
32. (b) Ayers, A. E.; Marynick, D. S.; Dias, H. V. R. Inorg. Chem. 2000, 39, 4147.
33. Lee, G.-H.; West, R.; Müller, T. J. Am. Chem. Soc. 2003, 125, 8114.
34. (a) Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270.
35. (b) Petersson, G. A.; Al-Laham, M. A. J. Chem. Phys. 1991, 94, 6081.
36. (c) Petersson, G. A.; Bennett, A.; Tensfeldt, T. G.; Al-Laham, M. A.; Shirley, W. A.; Mantzaris, J. J. Chem. Phys. 1998, 89, 2193.
37. (a) Foster, J. P.; Weinhold, F. J. Am. Chem. Soc. 1980, 102, 7211.
38. (b) Reed, A. E.; Weinhold, F. J. Chem. Phys. 1985, 83, 1736.
39. (c) Reed, A. E.; Curtiss, L. A.; Weinhold, F. Chem. Rev. 1988, 88, 899.
40. Maier, G.; Reisenauer, H. P.; Schöttler, K.; Wessolek-Kraus, U. J. Organomet. Chem. 1989, 366, 25.
41. Yao, S.; Brym, M.; van Wüllen, C.; Driess, M. Angew. Chem., Int. Ed. 2007, 46, 4159.
42. Karsch, H. H.; Keller, U.; Gamper, S.; Müller, G. Angew. Chem., Int. Ed. Engl. 1990, 29, 295.
43. Atwood, D. A.; Atwood, V. O.; Cowley, A. H.; Gobran, H. R.; Jones, R. A.; Smeal, T. M.; Carrano, C. J. Organometallics 1993, 12, 3517.
44. Sheldrick, G. M. SHELXS-97, Program for Crystal Structure Refinement; University of Göttingen: Göttingen, Germany, 1997.