Syntheses and X-ray structures of zinc amidinate complexes

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 634, Issue 3, 2008, Pages 507-513

  Eisenmann, Tamara ^a   Khanderi, Jayaprakash ^a   Schulz, Stephan ^a,b,c   Flörke, Ulrich ^a  

^a Universitat   (Germany)

^b Anorganische Chemie   (Germany)

^c UNIVERSITY OF DUISBURG ESSEN   (Germany)

Author keywords

Amides; Bridging ligands; Coordination modes; X ray structures; Zinc

Indexed keywords

EID: 53849134133     PISSN: 00442313     EISSN: 15213749     Source Type: Journal    
DOI: 10.1002/zaac.200700457     Document Type: Article

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39. Based on more than 1000 entries in the CSD database, terminal Zn-Cl bond lengths of four-coordinated Zn atoms range from 2.068 - 2.416 Å (mean bond length of 2.248 A ̊), whereas terminal Zn-Br bond lengths range from 2.278 - 2.548 Å (mean bond length of 2.38 Å based on more than 200 entries). Cambridge Structural Database (CSD) Version 5.28, November 2006 including update Mai 2007).
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42. 1: X1 = Cl1, X2 = N1A; 2: X1 = Cl1, X2 = N1A; 3: X1 = Br1, X2 = N1A; 6: X1 = N3, X2 = N4; 7: X1 = Br1, X2 = Br2.