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Volumn , Issue 15, 2009, Pages 2247-2253

Heteroleptic amidinate complexes of heavy group 15 elements - Synthesis, X-ray crystal structures and theoretical calculations

Author keywords

Antimony; Bismuth; Main group elements; N ligands

Indexed keywords

BISMUTH; CHELATION; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION;

EID: 66249113536     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200900233     Document Type: Article
Times cited : (24)

References (42)
  • 5
    • 49149100075 scopus 로고    scopus 로고
    • The coordination chemistry of neutral amidines and guanidines was recently described For a very recent review on amidinate and guanidinate complexes see c
    • For a very recent review on amidinate and guanidinate complexes see c) F. Edelmann, Adv. Organomet. Chem. 2008, 57, 183. The coordination chemistry of neutral amidines and guanidines was recently described
    • (2008) Adv. Organomet. Chem , vol.57 , pp. 183
    • Edelmann, F.1
  • 7
    • 85163237640 scopus 로고    scopus 로고
    • See for further bindings modes
    • See for further bindings modes: P. C. Junk, M. L. Cole, Chem.Commun. 2007, 1579.
    • (2007) Chem.Commun , pp. 1579
    • Junk, P.C.1    Cole, M.L.2
  • 13
    • 0035828925 scopus 로고    scopus 로고
    • See the following and references cited therein: a
    • See the following and references cited therein: a) M. Stender,A. D. Phillips, P. P. Power, Inorg. Chem. 2001, 40, 5314
    • (2001) Inorg. Chem , vol.40 , pp. 5314
    • Stender, M.1    Phillips, A.D.2    Power, P.P.3
  • 17
    • 85163239020 scopus 로고    scopus 로고
    • S. Schulz, M. Nieger, Angew. Chem. 1999, 111, 1020; Angew. Chem. Int. Ed. 1999, 38, 967
    • a) S. Schulz, M. Nieger, Angew. Chem. 1999, 111, 1020; Angew. Chem. Int. Ed. 1999, 38, 967
  • 19
    • 85163237925 scopus 로고    scopus 로고
    • A. Kuczkowski, S. Schulz, M. Nieger, Angew. Chem. 2001, 113, 4351; Angew. Chem. Int. Ed. 2001, 40, 4222.
    • c) A. Kuczkowski, S. Schulz, M. Nieger, Angew. Chem. 2001, 113, 4351; Angew. Chem. Int. Ed. 2001, 40, 4222.
  • 24
    • 85163238320 scopus 로고    scopus 로고
    • C. L. Raston,B. W. Skelton, V. A. Tolhurst, A. H. White, J. Chem. Soc., Dal-ton Trans. 2000, 1279. Moreover, several boramidinate complexes and complexes with the group 15 element in the formal oxidation state +5 have been structurally characterized;
    • e) C. L. Raston,B. W. Skelton, V. A. Tolhurst, A. H. White, J. Chem. Soc., Dal-ton Trans. 2000, 1279. Moreover, several boramidinate complexes and complexes with the group 15 element in the formal oxidation state +5 have been structurally characterized;
  • 31
    • 35648981120 scopus 로고    scopus 로고
    • In addition,complexes containing dianionic diamidonapthole substituents have been prepared
    • b) L. W. Pineda, V. Jancik, S. Nembenna, H. W. Roesky, Z. Anorg. Allg. Chem. 2007, 633, 2205. In addition,complexes containing dianionic diamidonapthole substituents have been prepared:
    • (2007) Z. Anorg. Allg. Chem , vol.633 , pp. 2205
    • Pineda, L.W.1    Jancik, V.2    Nembenna, S.3    Roesky, H.W.4
  • 37
    • 85163237412 scopus 로고    scopus 로고
    • According to a structure search in the Cambridge Structural Database, as described anions typically show bridging Sb-Cl bond lengths ranging from 3.00-3.30 Å.
    • According to a structure search in the Cambridge Structural Database, as described anions typically show bridging Sb-Cl bond lengths ranging from 3.00-3.30 Å.
  • 40
    • 85163241224 scopus 로고    scopus 로고
    • DFT calculations were carried out with the Gaussian03 suite of programs (M. J. Frisch, et al. Gaussian 03, Revision D.02; Gaussian Inc, Pittsburgh, PA, 2003, complete reference is given in the supplement, The molecular structures and energies of compounds 1a, 1b, 1c, 5a, and 5b were obtained by performing a complete energy optimization of all geometric parameters at the b3lyp/sdd level (input keywords, b3lyp/ sdd opt pop, nbo′, using the atomic coordinate of the crystal structure determination of 1and 5(without solvent molecule) as starting point. Population analysis was carried out with the NBO module as implemented in Gaussian03. The final molecular structures and list of the final atomic coordinates and energies, selected bond lengths, and NBO atomic populations are given in the electronic supplement
    • DFT calculations were carried out with the Gaussian03 suite of programs (M. J. Frisch, et al. Gaussian 03, Revision D.02; Gaussian Inc., Pittsburgh, PA, 2003, complete reference is given in the supplement). The molecular structures and energies of compounds 1a, 1b, 1c, 5a, and 5b were obtained by performing a complete energy optimization of all geometric parameters at the b3lyp/sdd level (input keywords "# b3lyp/ sdd opt pop = nbo′), using the atomic coordinate of the crystal structure determination of 1and 5(without solvent molecule) as starting point. Population analysis was carried out with the NBO module as implemented in Gaussian03. The final molecular structures and list of the final atomic coordinates and energies, selected bond lengths, and NBO atomic populations are given in the electronic supplement.
  • 41
    • 85163238873 scopus 로고    scopus 로고
    • SHELXS-97, Program for Structure Solution: G. M. Sheldrick,Acta Crystallogr., Sect. A 1990, 46, 467.
    • SHELXS-97, Program for Structure Solution: G. M. Sheldrick,Acta Crystallogr., Sect. A 1990, 46, 467.
  • 42
    • 0004150157 scopus 로고    scopus 로고
    • Program for Crystal Structure Refinement, University of Gottingen, Germany
    • G. M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, University of Gottingen, Germany, 1997.
    • (1997) SHELXL-97
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.