Experimental modeling of selective alkene oligomerization: Evidence for facile metallacyclopentane dehydrogenation mediated by a transannular β-hydrogen agostic interaction

Organometallics

Volumn 28, Issue 8, 2009, Pages 2520-2526

  Epshteyn, Albert ^a   Trunkely, Emily F ^a   Kissounko, Denis A ^a   Fettinger, James C ^a   Sita, Lawrence R ^a  

^a University of Maryland   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AGOSTIC INTERACTIONS; CARBON BOND; CHAIR CONFORMATIONS; EXPERIMENTAL MODELING; HYDROGEN ABSTRACTION; METAL CENTERS; METAL HYDRIDE INTERMEDIATES; SINGLE CRYSTAL X-RAY ANALYSIS; SOLID-STATE MOLECULAR STRUCTURE; TRIMETHYLSILYL;

CONFORMATIONS; DEHYDROGENATION; DERIVATIVES; ETHYLENE; METALS; OLIGOMERIZATION; PROPYLENE; STYRENE; ZIRCONIUM;

HYDROGEN;

EID: 65649098013     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900132u     Document Type: Article

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