Supercritical Fluid Processing for the Recovery of Bioactive Compounds from Food Industry By-Products

Food Engineering Series

Volumn , Issue , 2015, Pages 305-355

  Yener, M Esra ^a  

^a MIDDLE EAST TECHNICAL UNIVERSITY   (Turkey)

Author keywords

Bioactive; Carotenoid; Phytosterol; Polyphenol; PUFA; SAE; SAF; SCCO2; SCFE; SFE; Squalene; Tocopherol

Indexed keywords

EID: 84966351063     PISSN: 15710297     EISSN: None     Source Type: Book Series    
DOI: 10.1007/978-3-319-10611-3_9     Document Type: Chapter

References (142)

1. Adil İH, Çetin Hİ, Yener ME et al (2007) Subcritical (carbon dioxide + ethanol) extraction of polyphenols from apple and peach pomaces, and determination of the antioxidant activities of the extracts. J Supercrit Fluids 43:55–63
2. Adil İH, Yener ME, Bayındırlı A (2008) Extraction of total phenolics of sour cherry pomace by high pressure solvent and subcritical fluid, and determination of the antioxidant activities of the extracts. Sep Sci Technol 45:1091–1110
3. Agostini E, Bertussi RA, Agostini G et al (2012) Supercritical extraction of vinification residues: fatty acids, α-tocopherol, and phenolic compounds in the oil seeds from different varieties of grape. Scientific World J 2012:1–9
4. Akgün N (2011) Separation of squelene from olive oil deodorizer distillate using supercritical fluids. Eur J Lipid Sci Technol 113:1558–1565
5. Al-Darmaki N, Lu T, Al-Duri B et al (2012) Isothermal and temperature gradient supercritical fluid extraction and fractionation of squelene from palm fatty acid distillate using compressed carbon dioxide. J Supercrit Fluids 61:108–114
6. Amiguet VT, Kramp KL, Mao JQ et al (2012) Supercritical carbon dioxide extraction of polyunsaturated fatty acids from Northern shrimp (Pandalus borealis Kreyer) processing by-products. Food Chem 130:853–858
7. 2-based fluids. J Agric Food Chem 52:2440–2444
8. Becker EM, Nissen LR, Skibsted LH (2004) Antioxidant evaluation protocols: food quality and health effects. Eur Food Res Technol 219:561–571
9. 2 (1). J Supercrit Fluids 19:133–139
10. 2 (3). J Supercrit Fluids 20:157–162
11. Bernado-Gil G, Oneto C, Antunes P (2001) Extraction of lipids from cherry seed oil using supercritical carbon dioxide. Eur Food Res Technol 212:170–174
12. Bernardo-Gil MG, Cardoso Lopes LM (2004) Supercritical fluid extraction of Cucurbita ficifolia seed oil. Eur Food Res Technol 219:593–597
13. 2: optimization of extraction conditions. J Food Eng 78:488–493
14. Bueno JM, Ramos-Escudero F, Saez-Plaza P et al (2012) Analysis and antioxidant capacity of anthocyanin pigments. Part I. General considerations concerning polyphenols and flavonoids. Crit Rev Anal Chem 55:102–123
15. Cao X, Ito Y (2003) Supercritical fluid extraction of grape seed oil and subsequent separation of free fatty acids by high-speed counter-current chromatography. J Chromatog A 1021:117–124
16. 2: a study of mass transfer and rheological property by bayesian interference. Grassa Y Aceites 64:400–406
17. Cathpole OJ, Grey JB, Mitchell KA et al (2004) Supercritical antisolvent fractionation of propolis tincture. J Supercrit Fluids 29:97–106
18. Catchpole OJ, Durling NE, Grey JB et al (2009a) Supercritical antisolvent fractionation of plant extracts. In: Duarte ARC, Duarte CMM (eds) Current trends of supercritical fluid technology in pharmaceutical, nutraceutical and food processing industries. Bentham, Bussum, pp 71–79
19. Catchpole OJ, Tallon SJ, Eltringham WE et al (2009b) The extraction and fractionation of speciality lipids using near critical fluids. J Supercrit Fluids 47:591–597
20. 2 (3). J Supercrit Fluids 24:103–109
21. 2 + ethanol as a modifier: measurements and thermodynamic modeling. J Supercrit Fluids 32:89–96
22. Cháfer A, Pascual-Martí MC, Salvador A et al (2005) Supercritical fluid extraction and HPLC determination of relevant polyphenolic compounds in grape skins. J Sep Sci 28:2050–2056
23. 2 + ethanol as a cosolvent. J Chem Eng Data 52:116–121
24. Chandrasekaran M, Shine K (2013) Oil seeds. In: Chandrasekaran M (ed) Valorization of food processing by-products. CRC, Boca Raton, pp 331–376
25. Chang CJ, Chang YF, Lee HZ et al (2000) Supercritical carbon dioxide extraction of high-value substances from soybean oil deodorizer distillate. Ind Eng Chem Res 39:4521–4525
26. Choi ES, Noh MJ, Yoo KP (1998) Solubilities of o-, m-and p-coumeric acid isomers in carbon dioxide at 308.15–323.15 K and 8.5–25 MPa. J Chem Eng Data 43:6–8
27. 2 extraction and purification of compounds with antioxidant activity. J Agric Food Chem 54:2441–2469
28. Dunford NT, King JW (2000) Phytosterol enrichment of rice bran oil by a supercritical carbon dioxide fractionation technique. J Food Sci 65:1395–1399
29. Dunford NT, Teel JA, King JW (2003) A continuous countercurrent supercritical fluid deacidification process for phtosterol ester fortification in rice bran oil. Food Res Int 36:175–181
30. Eisenmenger M, Dunford NT (2008) Bioactive components of commertial and supercritical carbon dioxide processed wheat germ oil. JAOCS 85:55–61
31. Eisenmenger M, Dunford NT, Eller F et al (2006) Pilot-scale supercritical carbon dioxide extraction and fractionation of wheat germ oil. JAOCS 83:863–868
32. Eltringham W, Catchpole O (2008) Processing of fish oils by supercritical fluids. In: Martínez JL (ed) Supercritical fluid extraction of neutraceuticals and bioactive compounds. CRC, Boca Raton, pp 141–213
33. 2. In: Martínez JL (ed) Supercritical fluid extraction of neutraceuticals and bioactive compounds. CRC, Boca Raton, pp 103–140
34. 2/ethanol extraction of astaxanthin from crab (Callinectes sapidus) shell waste. J Food Process Eng 24:101–112
35. Ferdosh S, Sarker MZI, Rahman NNNA et al (2013) Supercritical carbon dioxide extraction of oil from Thunnus tonggol head by optimization of process parameters using response surface methodology. Korean J Chem Eng 30:1466–1472
36. Ferraro V, Cruz IB, Jorge RF et al (2010) Valorization of natural extracts from marine sources focused on marine by-products: a review. Food Res Int 43:2221–2233
37. Fiori L, Salona M, Tosi P et al (2012) Lipid profiles of oil from trout (Oncorhynchus mykiss) heads, spines and viscera: trout by-products as a possible source of omega-3 lipids. Food Chem 134:1088–1095
38. Floris T, Filippino G, Scrugli S et al (2010) Antioxidant compounds recovery from grape residues by supercritical antisolvent assisted process. J Supercrit Fluids 54:165–170
39. Fornari T, Torres CF, Señoráns FJ et al (2009) Simulation and optimization of supercritical fluid purification of phtosterol esters. AIChE J 55:1023–1029
40. Ge Y, Ni Y, Yan H et al (2002a) Optimization of the supercritical fluid extraction of natural vitamin E from wheat germ using response surface methodology. J Food Sci 67:239–243
41. Ge Y, Yan H, Hui B et al (2002b) Extraction of natural vitamin E from wheat germ by supercritical carbon dioxide. J Agric Food Chem 50:685–689
42. Gelmez N, Kıncal NS, Yener ME (2009) Optimization of supercritical carbon dioxide extraction of antioxidants from roasted wheat germ based on yield, total phenolic and tocopherol contents and antioxidant activities of the extracts. J Supercrit Fluids 48:217–224
43. Gómez AM, de la Ossa EM (2000) Quality of wheat germ oil extracted by liquid and supercritical carbon dioxide. JAOCS 77:969–974
44. Gómez AM, López CP, de la Ossa EM (1996) Recovery of grape seed oil by liquid and supercritical carbon dioxide extraction: a comparison with conventional solvent extraction. Chem Eng J 61:227–231
45. 2 process for the concentration of tocopherol, carotenoids and chlorophylls from residual olive husk. J Supercrit Fluids 59:72–77
46. Gurdial GS, Foster NR, Jimmy Yun SL et al (1993) Phase behaviour of supercritical fluid-entrainer systems. In: Kiran E, Brennecke JF (eds) Supercritical fluid engineering science: fundamentals and applications, ACS Symposium Series. ACS, Washington, pp 34–39
47. Guyot S, Marnet N, Laraba D et al (1998) Reversed-phase HPLC following thiolysis for quantitative estimation and characterization of the four main classes of phenolic compounds in different tissue zones of a french cider apple variety (Malus domestica Var. Kermerrien). J Agric Food Chem 46:1698–1705
48. Güçlü-Üstündağ Ö, Temelli F (2000) Correlating the solubility behavior of fatty acids, mono-, di-, and triglycerides and fatty acid esters in supercritical carbon dioxide. Ind Eng Chem Res 39:4756–4766
49. Güçlü-Üstündağ Ö, Temelli F (2004) Correlating the solubility behavior of minor lipid components in supercritical carbon dioxide. J Supercrit Fluids 31:235–253
50. Halvorsen BL, Holte K, Myhrstad MCW et al (2002) A systematic screening of total antioxidants in dietary plants. J Nutr 132:461–471
51. Herrero M, Cifuentes A, Ibáñez E (2006) Sub-and supercritical extraction of functional ingredients from natural sources: plants, food-by-products, algea and microalgae: a review. Food Chem 98:136–148
52. Herrero M, Mendiola JA, Cifuentes A et al (2010) Supercritical fluid extraction: recent advances and applications. J Chromatog A 1217:2495–2511
53. Herrero M, Castro-Puayana M, Mendiola JA et al (2013) Compressed fluids for the extraction of bioactive compounds. Trends Anal Chem 43:67–83
54. Higuera-Ciapara I, Félix-Valenzuela L, Goycoolea FM (2006) Astaxanthin: a review of its chemistry and applications. Crit Rev Food Sci Nut 46:185–196
55. 2. Eur J Lipid Sci Technol 114:1204–1211
56. Huang W, Li Z, Niu H et al (2008) Optimization of operating parameters for supercritical carbon dioxide extraction of lycopene by response surface methodology. J Food Eng 89:298–302
57. Ibáñez E, Palacios J, Señorans FJ et al (2000) Isolation and separation of tocopherols from olive by-products with supercritical fluids. JAOCS 77:187–190
58. Junior MRM, Leite AV, Dragano NRV (2010) Supercritical fluid extraction and stabilization of phenolic compounds from natural sources-Review (Supercritical extraction and stabilization of phenolic compounds). Open Chem Eng J 4:51–60
59. Kao TH, Chen BH (2013) Fruits and vegatables. In: Chandrasekaran M (ed) Valorization of food processing by-products. CRC, Boca Raton, pp 517–557
60. Kassama LS, Shi J, Mittal GS et al (2008) Optimization of supercritical fluid extraction of lycopene from tomato skin with central composite rotatable design model. Sep Pur Tech 60:278–284
61. Kim HJ, Lee SB, Park KA et al (1999) Characterization of extraction and separation of rice bran oil rich in EFA using SFE process. Sep Pur Technol 15:1–8
62. King JW, Dunford NT (2002) Phetosterol-enriched triglyceride fractions from vegetable oil deodorizer distillates utilizing supercritical fluid fractionation technology. Sep Sci Technol 37:451–462
63. Ko SN, Ha TY, Hong SI et al (2012) Enrichment of tocols from rice germ oil using supercritical carbon dioxide. Int J Food Sci Technol 47:761–767
64. Krings U, Berger RG (2001) Antioxidant activity of some roasted foods. Food Chem 72:223–229
65. Krings U, El-Saharty YS, El-Zeany BA et al (2000) Antioxidant activity of extracts from roasted wheat germ. Food Chem 71:91–95
66. Krings U, Johansson L, Zorn H et al (2006) In vitro DNA-protective activity of roasted wheat germ and fractions thereof. Food Chem 97:712–718
67. Krishna JG, Chandrasekaran M (2013) Biochemical and nutritional aspects of food processing by-products. In: Chandrasekaran M (ed) Valorization of food processing by-products. CRC, Boca Raton, pp 167–185
68. 2 extraction of rice bran. JAOCS 75:623–628
69. Kumar RS, Chandrasekaran M (2013) Beverages. In: Chandrasekaran M (ed) Valorization of food processing by-products. CRC, Boca Raton, pp 589–614
70. Leantowicz H, Gorinstein S, Lojek A et al (2002) Comparative content of some bioactive compounds in apples, peaches and pears and their influence on lipids and antioxidant capacity in rats. J Nutr Biochem 13:603–610
71. Létisse M, Comeau L (2008) Enrichment of eicosapentaenoic and docosahexaenoic acid from sardine by-products by supercritical fluid fractionation. J Sep Sci 31:1374–1380
72. 2 extraction optimization of pomegranate (Punica granatum L.) seed oil using response surface methodology. LWT-Food Sci Technol 42:1491–1495
73. Louli V, Ragoussis N, Magoulas K (2004) Recovery of phenolic antioxidants form wine industry by-products. Biores Technol 92:201–208
74. 2: main applications and future perspectives. Sep Sci Technol 48:2741–2760
75. Manach C, Scalbert A, Morand C et al (2004) Polyphenols: food sources and bioavailability. Am J Clin Nutr 79:727–747
76. Mitra P, Ramaswamy HS, Chang KS (2009) Pumpkin (Cucurbita maxima) seed oil extraction using supercritical carbon dioxide and physicochemical properties of the oil. J Food Eng 95:208–213
77. Moure A, Cruz JM, Franco D et al (2001) Natural antioxidants from residual sources. Food Chem 72:145–171
78. Muragan K, Chandrasekaran VS, Karthikeyan P et al (2013) Current state-of-the-art of food processing by-products. In: Chandrasekaran M (ed) Valorization of food processing by-products. CRC, Boca Raton, pp 35–61
79. Murga R, Ruiz R, Beltrán S et al (2000) Extraction of natural complex phenols and tannins from grape seeds by using supercritical mixtures of carbon dioxide and alcohol. J Agric Food Chem 48:3408–3412
80. Murga R, Sanz MT, Beltrán S et al (2002) Solubility of some phenolic compounds contained in grape seeds, in supercritical carbon dioxide. J Supercrit Fluids 23:113–121
81. Murga R, Sanz MT, Beltrán S et al (2003) Solubility of three hydroxycinnamic acids in supercritical carbon dioxide. J Supercrit Fluids 27:239–245
82. Murga R, Sanz MT, Beltrán S et al (2004) Solubility of syringic and vanillic acids in supercritical carbon dioxide. J Chem Eng Data 49:779–782
83. 2 extraction of trans-lycopene from Portugese tomato industrial waste. Food Chem 116:680–685
84. Ollanketo M, Hartonen K, Riekkola ML et al (2001) Supercritical carbon dioxide extraction of lycopene in tomato skins. Eur Food Res Technol 21:561–565
85. Oreopoulou V, Tzia C (2007) Utilization of plant by-products for the recovery of proteins, dietary fiber, antioxidants and colorants. In: Oreopoulou V, Russ W (eds) Utilization of by-products and treatment of waste in the food industry. Springer, New York, pp 209–232
86. Özkal SG, Yener ME, Bayındırlı L (2005a) Mass transfer modeling of apricot kernel oil extraction with supercritical carbon dioxide. J Supercrit Fluids 35:119–127
87. Özkal SG, Yener ME, Bayındırlı L (2005b) Response surfaces of apricot kernel oil yield in supercritical carbon dioxide. Food Sci Technol 38:611–616
88. Özkal SG, Yener ME, Bayındırlı L (2006) The solubility of apricot kernel oil in supercritical carbon dioxide. Int J Food Sci Technol 41:399–404
89. Palma M, Taylor LT (1999a) Extraction of polyphenolic compounds from grape seeds with near critical carbon dioxide. J Chromotogr A 849:117–124
90. Palma M, Taylor LT (1999b) Fractional extraction of compounds from grape seeds by supercritical fluid extraction and analysis for antimicrobial and agrochemical activities. J Agric Food Chem 47:5044–5048
91. 2: oil and defatted cake characterization. JAOCS 80:157–161
92. Pascual-Martí MC, Salvador A, Cháfer A et al (2001) Supercritical fluid extraction of resveratrol from grape skin of Vitis vinifera and determination by HPLC. Talanta 54:735–740
93. Passos CP, Silva RM, Da Silva FA et al (2009) Enhancement of the supercritical fluid extraction of grape seed oil by using enzymatically pre-treated seed. J Supercrit Fluids 48:225–229
94. Passos CP, Silva RM, Da Silva FA et al (2010) Supercritical fluid extraction of grape seed (Vitis vinifera L.) oil. Effect of operating conditions upon oil composition and antioxidant capacity. Chem Eng J 160:634–640
95. Pereira CG, Angela M, Meireles A (2010) Supercritical fluid extraction of bioactive compounds: fundamentals, applications and economic perspectives. Food Bioprocess Technol 2:340–372
96. Perretti G, Miniati E, Montanari L et al (2003) Improving the value of rice by-products. J Supercrit Fluids 26:63–71
97. Pinelo A, Ruiz-Rodríguez A, Sineiro J et al (2007) Supercritical fluid and solid-liquid extraction of phenolic antioxidants from grape pomace: a comparative study. European Food Res Technol 22:199–205
98. Prado JM, Dalmolin I, Carareto NDD et al (2012) Supercritical fluid extraction of grape seed: process scale-up, extract chemical composition and economic evaluation. J Food Eng 109:249–257
99. Reverchon E, de Marco I (2006) Supercritical fluid extraction and fractionation of natural matter. J Supercrit Fluids 38:146–166
100. Rozzi NL, Singh RK, Vierling RA et al (2002) Supercritical fluid extraction of lycopene from tomato processing by-products. J Agric Food Chem 50:2638–2643
101. Rubio-Rodríguez N, de Diego S, Beltrán S et al (2008) Supercritical fluid extraction of the omega-3 rich oil contained in hake (Merluccius capensis-Merluccius paradoxus) by-products: study of the influence of process parameters on the extraction yield and oil quality. J Supercrit Fluids 47:215–226
102. Rubio-Rodríguez N, Beltrán S, Jaime I et al (2010) Production of omega-3 polyunsaturated fatty acid concentrates: a review. Innovative Food Sci Eng Tech 11:1–12
103. Rubio-Rodríguez N, de Diego S, Beltrán S et al (2012) Supercritical fluid extraction of fish oil from fish by-products: a comparison with other extraction methods. J Food Eng 109:238–248
104. Russ W, Schnappinger M (2007) Waste related to the food industry. A challenge in material loops. In: Oreopoulou V, Russ W (eds) Utilization of by-products and treatment of waste in the food industry. Springer, New York, pp 209–232
105. 2. Ind Eng Chem Res 42:6641–6646
106. Salgın U, Korkmaz H (2011) A green separation process for recovery of healthy oil from pumpkin seed. J Supercrit Fluids 58:239–248
107. 2 extraction of lipids and astaxathin from redspotted shrimp waste (Farfantepenaeus paulensis). J Supercrit Fluids 56:164–173
108. Sánchez-Camargo AP, Meireles MAA, Lopes BLF et al (2011b) Proximate composition and extraction of carotenoids and lipids from Brazilian redspotted shrimp waste (Farfantepenaeus paulensis). J Food Eng 102:87–93
109. 2 + ethanol mixtures. J Supercrit Fluids 61:71–77
110. Sánchez-Vicente Y, Cabañaz A, Renuncio JAR et al (2009) Supercritical fluid extraction of peach (Prunus persica) seed oil using carbon dioxide and ethanol. J Supercrit Fluids 49:167–173
111. Sarmento CMP, Ferreira SRS, Hense H (2006) Supercritical fluid extraction (SFE) of rice bran oil to obtain fractions enriched with tocopherols and tocotrienols. Brazilian J Chem Eng 23:243– 249
112. Schieber A, Stintzing FC, Carle R (2001) By-products of plant processing as a source of functional compounds-recent developments. Trends Food Sci Technol 12:401–413
113. Schwartz H, Ollilainen V, Piironen V et al (2008) Tocopherol, tocotrienol and plant sterol contents of vegetable oils and industrial fats. J Food Comp Anal 21:152–161
114. Serra AT, Seabra IJ, Braga MEM et al (2010) Processing cherries (Prumus avium) using supercritical fluid technology. Part 1: recovery of extracts fractions rich in bioactive compounds. J Supercrit Fluids 55:185–191
115. Shen Z, Palmer MV, Ting SST et al (1996) Pilot scale extraction of rice bran oil with dense carbon dioxide. J Agric Food Chem 44:3033–3039
116. Shi J, Nawaz H, Pohorly J et al (2005) Extraction of polyphenolics from plant materials for functional foods-engineering and technology. Food Reviews Int 21:139–166
117. 2. Food Reviews Int 23:341–371
118. 2. J Food Eng 93:431–436
119. Snyder JM, King JW, Taylor SL et al (1999) Concentration of phytosterols for analysis by supercritical fluid extraction. JAOCS 76:717–721
120. 2 and effect of entrainers. J Supercrit Fluids 21:195–203
121. Sparks D, Hernandez R, Zappi M et al (2006) Extraction of rice bran oil using supercritical carbon dioxide and propane. JAOCS 83:885–891
122. Sun M, Temelli F (2006) Supercritical carbon dioxide extraction of carotenoids from carrots using canola oil as a continuous co-solvent. J Supercrit Fluids 37:397–408
123. Suresh PV, Prabhu GN (2013) Seafood. In: Chandrasekaran M (ed) Valorization of food processing by-products. CRC, Boca Raton, pp 685–736
124. 2 extraction. J Supercrit Fluids 32:221–230
125. 2 + ethanol) extraction of β-carotene from apricot pomace using response surface methodology. J Supercrit Fluids 34:331–338
126. Temelli F (2009) Perspectives on supercritical fluid processing of fats and oils. J Supercrit Fluids 47:583–590
127. Temelli F, Saldana MDA, Moquin PHL et al (2008) Supercritical fluid extraction of specialty oils. In: Martínez JL (ed) Supercritical fluid extraction of neutraceuticals and bioactive compounds. CRC, Boca Raton, pp 51–101
128. Tomás-Barberán FA, Gil MI, Cremin P et al (2001) HPLC-DAD-ESIMS analysis of phenolic compounds in nectarines, peaches, and plums. J Agric Food Chem 49:4748–4760
129. Topal U, Sasaki M, Goto M et al (2006) Extraction of lycopene from tomato skin with supercritical carbon dioxide: effect of operating conditions and solubility analysis. J Agric Food Chem 54:5604–5610
130. Torres CF, Fornari T, Torrelo G et al (2009) Production of pytosterol esters from soybean oil deodorizer distillates. Eur J Lipid Sci Technol 111:459–463
131. Tsagaraki E, Lazarides HN, Petrotos KB (2007) Olive mill wastewater treatment. In: Oreopoulou V, Russ W (eds) Utilization of by-products and treatment of waste in the food industry. Springer, New York, pp 133–157
132. 2 extraction of lycopene from tomato in the presence of vegetable oil as co-solvent. J Supercrit Fluids 29:87–96
133. Vázquez L, Torres CF, Fornari T et al (2006) Supercritical fluid extraction of minor lipids from pretreated sunflower oil deodorizer distillates. Eur J Lipid Sci Technol 108:659–665
134. Vázquez L, Torres CF, Fornari T et al (2007) Recovery of squelene from vegetable oil sources using countercurrent supercritical carbon dioxide extraction. J Supercrit Fluids 40:59–66
135. Wang CH, Chen CR, Wu JJ et al (2008) Designing supercritical carbon dioxide extraction of rice bran oil that contain oryzanols using response surface methodology. J Sep Sci 31:1399–1407
136. 2 extraction. Eur J Lipid Sci Technol 106:355–358
137. Wijngaard H, Hossain MB, Rai DK et al (2012) Techniques to extract bioactive compounds from food products of plant origin. Food Res Int 46:505–513
138. Yılmaz C, Gökmen V (2013) Compositional characteristics of sour cherry kernel and its oil as influenced by different extraction and roasting conditions. Ind Crops Prod 49:130–135
139. Yılmaz EE, Özvural EB, Vural H (2011) Extraction and identification of proantocyanidins from grape seed (Vitis vinifera) using supercritical carbon dioxide. J Supercrit Fluids 55:924–928
140. Yi C, Shi J, Xue SJ et al (2009) Effects of supercritical fluid extraction parameters on lycopene yield and antioxidant activity. Food Chem 113:1088–1094
141. Yu L, Haley S, Perret J et al (2002) Free radical scavenging properties of wheat extracts. J Agric Food Chem 50:1619–1624
142. Zacchi P, Daghero J, Jaeger P et al (2006) Extraction/fractionation and deacidification of wheat germ oil using supercritical carbon dioxide. Brazilian J Chem Eng 23:105–110