Molecular Chromophore-Catalyst Assemblies for Solar Fuel Applications

Chemical Reviews

Volumn 115, Issue 23, 2015, Pages 13006-13049

  Ashford, Dennis L ^a   Gish, Melissa K ^a   Vannucci, Aaron K ^b   Brennaman, M Kyle ^a   Templeton, Joseph L ^a   Papanikolas, John M ^a   Meyer, Thomas J ^a  

^a The University of North Carolina at Chapel Hill   (United States)

^b UNIVERSITY OF SOUTH CAROLINA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMIC LAYER DEPOSITION; CATALYSTS; CHEMICAL ACTIVATION; ELECTRON TRANSITIONS; ENERGY CONVERSION; EXCITED STATES; LIGHT ABSORPTION; OXIDE MINERALS; SOLAR ENERGY; SYNTHESIS (CHEMICAL); TITANIUM DIOXIDE;

CATALYTIC PROPERTIES; ELECTRON TRANSFER; ENHANCED EFFICIENCY; INTRINSIC PROPERTY; MOLECULAR LEVELS; SEMICONDUCTOR OXIDES; TRANSIENT ABSORPTION MEASUREMENTS; WATER OXIDATION CATALYSTS;

CHROMOPHORES;

EID: 84982068856     PISSN: 00092665     EISSN: 15206890     Source Type: Journal    
DOI: 10.1021/acs.chemrev.5b00229     Document Type: Article

References (423)

1. Annual Energy Outlook; U.S. Department of Energy, Washington, DC, 2013.
2. Lewis, N. S.; Nocera, D. G. Powering the planet: chemical challenges in solar energy utilization Proc. Natl. Acad. Sci. U. S. A. 2006, 103, 15729-15735 10.1073/pnas.0603395103
3. Shafiee, S.; Topal, E. When will fossil fuel reserves be diminished? Energy Policy 2009, 37, 181-189 10.1016/j.enpol.2008.08.016
4. Dresselhaus, M. S.; Thomas, I. L. Alternative energy technologies Nature 2001, 414, 332-337 10.1038/35104599
5. Murray, J.; King, D. Climate policy: Oils tipping point has passed Nature 2012, 481, 433-435 10.1038/481433a
6. Sigman, D. M.; Hain, M. P.; Haug, G. H. The polar ocean and glacial cycles in atmospheric CO2 concentration Nature 2010, 466, 47-55 10.1038/nature09149
7. Breecker, D. O.; Sharp, Z. D.; McFadden, L. D. Atmospheric CO2 concentrations during ancient greenhouse climates were similar to those predicted for A.D. 2100 Proc. Natl. Acad. Sci. U. S. A. 2010, 107, 576-580 10.1073/pnas.0902323106
8. Petit, J. R.; Jouzel, J.; Raynaud, D.; Barkov, N. I.; Barnola, J. M.; Basile, I.; Bender, M.; Chappellaz, J.; Davis, M.; Delaygue, G. et al. Climate and atmospheric history of the past 420,000 years from the Vostok ice core, Antarctica Nature 1999, 399, 429-436 10.1038/20859
9. Siegenthaler, U.; Stocker, T. F.; Monnin, E.; Luethi, D.; Schwander, J.; Stauffer, B.; Raynaud, D.; Barnola, J.-M.; Fischer, H.; Masson-Delmotte, V. et al. Stable carbon cycle-climate relationship during the Late Pleistocene Science 2005, 310, 1313-1317 10.1126/science.1120130
10. Wigley, T. M. L.; Richels, R.; Edmonds, J. A. Economic and environmental choices in the stabilization of atmospheric CO2 concentrations Nature 1996, 379, 240-243 10.1038/379240a0
11. Bak, T.; Nowotny, J.; Rekas, M.; Sorrell, C. C. Photo-electrochemical hydrogen generation from water using solar energy. Materials-related aspects Int. J. Hydrogen Energy 2002, 27, 991-1022 10.1016/S0360-3199(02)00022-8
12. Valentine, K. ThinkProgress 2013.
13. Christensen, J.; Albertus, P.; Sanchez-Carrera, R. S.; Lohmann, T.; Kozinsky, B.; Liedtke, R.; Ahmed, J.; Kojic, A. A Critical Review of Li/Air Batteries J. Electrochem. Soc. 2012, 159, R1-R30 10.1149/2.086202jes
14. Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J.-M. Li-O2 and Li-S batteries with high energy storage Nat. Mater. 2012, 11, 19-29 10.1038/nmat3191
15. Gao, M.-R.; Xu, Y.-F.; Jiang, J.; Yu, S.-H. Nanostructured metal chalcogenides: synthesis, modification, and applications in energy conversion and storage devices Chem. Soc. Rev. 2013, 42, 2986-3017 10.1039/c2cs35310e
16. Lu, Y.-C.; Gallant, B. M.; Kwabi, D. G.; Harding, J. R.; Mitchell, R. R.; Whittingham, M. S.; Shao-Horn, Y. Lithium-oxygen batteries: bridging mechanistic understanding and battery performance Energy Environ. Sci. 2013, 6, 750-768 10.1039/c3ee23966g
17. Shao, Y.; Park, S.; Xiao, J.; Zhang, J.-G.; Wang, Y.; Liu, J. Electrocatalysts for Nonaqueous Lithium-Air Batteries: Status, Challenges, and Perspective ACS Catal. 2012, 2, 844-857 10.1021/cs300036v
18. Wang, W.; Luo, Q.; Li, B.; Wei, X.; Li, L.; Yang, Z. Recent Progress in Redox Flow Battery Research and Development Adv. Funct. Mater. 2013, 23, 970-986 10.1002/adfm.201200694
19. Seh, Z. W.; Li, W.; Cha, J. J.; Zheng, G.; Yang, Y.; McDowell, M. T.; Hsu, P.-C.; Cui, Y. Sulphur-TiO2 yolk-shell nanoarchitecture with internal void space for long-cycle lithium-sulphur batteries Nat. Commun. 2013, 4, 1331 10.1038/ncomms2327
20. Renger, G. Oxidative photosynthetic water splitting: Energetics, kinetics and mechanism Photosynth. Res. 2007, 92, 407-425 10.1007/s11120-007-9185-x
21. Ferreira, K. N.; Iverson, T. M.; Maghlaoui, K.; Barber, J.; Iwata, S. Architecture of the Photosynthetic Oxygen-Evolving Center Science 2004, 303, 1831-1838 10.1126/science.1093087
22. Barber, J. Engine of life and big bang of evolution: a personal perspective Photosynth. Res. 2004, 80, 137-155 10.1023/B:PRES.0000030662.04618.27
23. Umena, Y.; Kawakami, K.; Shen, J.-R.; Kamiya, N. Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å Nature 2011, 473, 55-60 10.1038/nature09913
24. Song, W.; Chen, Z.; Glasson, C. R.; Hanson, K.; Luo, H.; Norris, M. R.; Ashford, D. L.; Concepcion, J. J.; Brennaman, M. K.; Meyer, T. J. Interfacial Dynamics and Solar Fuel Formation in Dye-Sensitized Photoelectrosynthesis Cells ChemPhysChem 2012, 13, 2882-2890 10.1002/cphc.201200100
25. Zhu, X.-G.; Long, S. P.; Ort, D. R. Improving photosynthetic efficiency for greater yield Annu. Rev. Plant Biol. 2010, 61, 235-261 10.1146/annurev-arplant-042809-112206
26. Wijffels, R. H.; Barbosa, M. J. An Outlook on Microalgal Biofuels Science 2010, 329, 796-799 10.1126/science.1189003
27. Blankenship, R. E.; Tiede, D. M.; Barber, J.; Brudvig, G. W.; Fleming, G.; Ghirardi, M.; Gunner, M. R.; Junge, W.; Kramer, D. M.; Melis, A. et al. Comparing Photosynthetic and Photovoltaic Efficiencies and Recognizing the Potential for Improvement Science 2011, 332, 805-809 10.1126/science.1200165
28. Reece, S. Y.; Hamel, J. A.; Sung, K.; Jarvi, T. D.; Esswein, A. J.; Pijpers, J. J. H.; Nocera, D. G. Wireless Solar Water Splitting Using Silicon-Based Semiconductors and Earth-Abundant Catalysts Science 2011, 334, 645-648 10.1126/science.1209816
29. Gust, D.; Moore, T. A.; Moore, A. L. Solar Fuels via Artificial Photosynthesis Acc. Chem. Res. 2009, 42, 1890-1898 10.1021/ar900209b
30. Gilbert, J. A.; Eggleston, D. S.; Murphy, W. R., Jr.; Geselowitz, D. A.; Gersten, S. W.; Hodgson, D. J.; Meyer, T. J. Structure and redox properties of the water-oxidation catalyst [(bpy)2(OH2)RuORu(OH2)(bpy)2]4+ J. Am. Chem. Soc. 1985, 107, 3855-3864 10.1021/ja00299a017
31. Yagi, M.; Kaneko, M. Molecular Catalysts for Water Oxidation Chem. Rev. 2001, 101, 21-35 10.1021/cr980108l
32. Meyer, T. J.; Huynh, M. H. V.; Thorp, H. H. The possible role of proton-coupled electron transfer (PCET) in water oxidation by photosystem II Angew. Chem., Int. Ed. 2007, 46, 5284-5304 10.1002/anie.200600917
33. Concepcion, J. J.; Jurss, J. W.; Norris, M. R.; Chen, Z. F.; Templeton, J. L.; Meyer, T. J. Catalytic Water Oxidation by Single-Site Ruthenium Catalysts Inorg. Chem. 2010, 49, 1277-1279 10.1021/ic901437e
34. Concepcion, J. J.; Jurss, J. W.; Templeton, J. L.; Meyer, T. J. One Site is Enough. Catalytic Water Oxidation by [Ru(tpy) (bpm) (OH2)]2+ and [Ru(tpy) (bpz) (OH2)]2+ J. Am. Chem. Soc. 2008, 130, 16462-16463 10.1021/ja8059649
35. Concepcion, J. J.; Tsai, M. K.; Muckerman, J. T.; Meyer, T. J. Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts J. Am. Chem. Soc. 2010, 132, 1545-1557 10.1021/ja904906v
36. Hurst, J. K.; Cape, J. L.; Clark, A. E.; Das, S.; Qin, C. Mechanisms of Water Oxidation Catalyzed by Ruthenium Diimine Complexes Inorg. Chem. 2008, 47, 1753-1764 10.1021/ic700724h
37. Brimblecombe, R.; Dismukes, G. C.; Swiegers, G. F.; Spiccia, L. Molecular water-oxidation catalysts for photoelectrochemical cells Dalton Trans. 2009, 9374-9384 10.1039/b912669d
38. Weinberg, D. R.; Gagliardi, C. J.; Hull, J. F.; Murphy, C. F.; Kent, C. A.; Westlake, B. C.; Paul, A.; Ess, D. H.; McCafferty, D. G.; Meyer, T. J. Proton-Coupled Electron Transfer Chem. Rev. 2012, 112, 4016-4093 10.1021/cr200177j
39. Huynh, M. H. V.; Meyer, T. J. Proton-Coupled Electron Transfer Chem. Rev. 2007, 107, 5004-5064 10.1021/cr0500030
40. Cukier, R. I.; Nocera, D. G. Proton-coupled electron transfer Annu. Rev. Phys. Chem. 1998, 49, 337-369 10.1146/annurev.physchem.49.1.337
41. Mayer, J. M. Proton-coupled electron transfer: A reaction chemists view Annu. Rev. Phys. Chem. 2004, 55, 363-390 10.1146/annurev.physchem.55.091602.094446
42. Concepcion, J. J.; Jurss, J. W.; Brennaman, M. K.; Hoertz, P. G.; Patrocinio, A. O. T.; Murakami Iha, N. Y.; Templeton, J. L.; Meyer, T. J. Making Oxygen with Ruthenium Complexes Acc. Chem. Res. 2009, 42, 1954-1965 10.1021/ar9001526
43. Nocera, D. G. The Artificial Leaf Acc. Chem. Res. 2012, 45, 767-776 10.1021/ar2003013
44. Kanan, M. W.; Nocera, D. G. In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+ Science 2008, 321, 1072-1075 10.1126/science.1162018
45. Fujishima, A.; Honda, K. Electrochemical photolysis of water at a semiconductor electrode Nature 1972, 238, 37-38 10.1038/238037a0
46. Chen, X.; Shen, S.; Guo, L.; Mao, S. S. Semiconductor-based Photocatalytic Hydrogen Generation Chem. Rev. 2010, 110, 6503-6570 10.1021/cr1001645
47. Kudo, A.; Kato, H.; Tsuji, I. Strategies for the development of visible-light-driven photocatalysts for water splitting Chem. Lett. 2004, 33, 1534-1539 10.1246/cl.2004.1534
48. Young, K. M. H.; Klahr, B. M.; Zandi, O.; Hamann, T. W. Photocatalytic water oxidation with hematite electrodes Catal. Sci. Technol. 2013, 3, 1660-1671 10.1039/c3cy00310h
49. Butler, M. A. Photoelectrolysis and physical properties of the semiconducting electrode tungsten trioxide J. Appl. Phys. 1977, 48, 1914-1920 10.1063/1.323948
50. Hong, S. J.; Lee, S.; Jang, J. S.; Lee, J. S. Heterojunction BiVO4/WO3 electrodes for enhanced photoactivity of water oxidation Energy Environ. Sci. 2011, 4, 1781-1787 10.1039/c0ee00743a
51. Katz, M. J.; Riha, S. C.; Jeong, N. C.; Martinson, A. B. F.; Farha, O. K.; Hupp, J. T. Toward solar fuels: Water splitting with sunlight and "rust"? Coord. Chem. Rev. 2012, 256, 2521-2529 10.1016/j.ccr.2012.06.017
52. Kay, A.; Cesar, I.; Graetzel, M. New Benchmark for Water Photooxidation by Nanostructured α-Fe2O3 Films J. Am. Chem. Soc. 2006, 128, 15714-15721 10.1021/ja064380l
53. Ling, Y.; Wang, G.; Wheeler, D. A.; Zhang, J. Z.; Li, Y. Sn-Doped Hematite Nanostructures for Photoelectrochemical Water Splitting Nano Lett. 2011, 11, 2119-2125 10.1021/nl200708y
54. Albero, J.; Clifford, J. N.; Palomares, E. Quantum dot based molecular solar cells Coord. Chem. Rev. 2014, 53, 263-264 10.1016/j.ccr.2013.07.005
55. Kochuveedu, S. T.; Jang, Y. H.; Kim, D. H. A study on the mechanism for the interaction of light with noble metal-metal oxide semiconductor nanostructures for various photophysical applications Chem. Soc. Rev. 2013, 42, 8467-8493 10.1039/c3cs60043b
56. Alexander, B. D.; Kulesza, P. J.; Rutkowska, I.; Solarska, R.; Augustynski, J. Metal oxide photoanodes for solar hydrogen production J. Mater. Chem. 2008, 18, 2298-2303 10.1039/b718644d
57. Guo, L.; Hung, D.; Wang, W.; Shen, W.; Zhu, L.; Chien, C.-L.; Searson, P. C. Tunnel barrier photoelectrodes for solar water splitting Appl. Phys. Lett. 2010, 97, 063111-063113 10.1063/1.3479055
58. Zhang, Z.; Dua, R.; Zhang, L.; Zhu, H.; Zhang, H.; Wang, P. Carbon-Layer-Protected Cuprous Oxide Nanowire Arrays for Efficient Water Reduction ACS Nano 2013, 7, 1709-1717 10.1021/nn3057092
59. Duonghong, D.; Borgarello, E.; Graetzel, M. Dynamics of light-induced water cleavage in colloidal systems J. Am. Chem. Soc. 1981, 103, 4685-4690 10.1021/ja00406a004
60. Osterloh, F. E. Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting Chem. Soc. Rev. 2013, 42, 2294-2320 10.1039/C2CS35266D
61. Kudo, A.; Miseki, Y. Heterogeneous photocatalyst materials for water splitting Chem. Soc. Rev. 2009, 38, 253-278 10.1039/B800489G
62. Osterloh, F. E. Inorganic Materials as Catalysts for Photochemical Splitting of Water Chem. Mater. 2008, 20, 35-54 10.1021/cm7024203
63. Osterloh, F. E.; Parkinson, B. A. Recent developments in solar water-splitting photocatalysis MRS Bull. 2011, 36, 17-22 10.1557/mrs.2010.5
64. Maeda, K. Z-Scheme Water Splitting Using Two Different Semiconductor Photocatalysts ACS Catal. 2013, 3, 1486-1503 10.1021/cs4002089
65. Yang, J.; Wang, D.; Han, H.; Li, C. Roles of cocatalysts in photocatalysis and photoelectrocatalysis Acc. Chem. Res. 2013, 46, 1900-1909 10.1021/ar300227e
66. Maeda, K.; Lu, D.; Domen, K. Direct Water Splitting into Hydrogen and Oxygen under Visible Light by using Modified TaON Photocatalysts with d0 Electronic Configuration Chem.-Eur. J. 2013, 19, 4986-4991 10.1002/chem.201300158
67. Kelzenberg, M. D.; Boettcher, S. W.; Petykiewicz, J. A.; Turner-Evans, D. B.; Putnam, M. C.; Warren, E. L.; Spurgeon, J. M.; Briggs, R. M.; Lewis, N. S.; Atwater, H. A. Enhanced absorption and carrier collection in Si wire arrays for photovoltaic applications Nat. Mater. 2010, 9, 239-244 10.1038/nmat2635
68. Walter, M. G.; Warren, E. L.; McKone, J. R.; Boettcher, S. W.; Mi, Q.; Santori, E. A.; Lewis, N. S. Solar Water Splitting Cells Chem. Rev. 2010, 110, 6446-6473 10.1021/cr1002326
69. Spurgeon, J. M.; Boettcher, S. W.; Kelzenberg, M. D.; Brunschwig, B. S.; Atwater, H. A.; Lewis, N. S. Flexible, polymer-supported, Si wire array photoelectrodes Adv. Mater. 2010, 22, 3277-3281 10.1002/adma.201000602
70. Spurgeon, J. M.; Walter, M. G.; Zhou, J.; Kohl, P. A.; Lewis, N. S. Electrical conductivity, ionic conductivity, optical absorption, and gas separation properties of ionically conductive polymer membranes embedded with Si microwire arrays Energy Environ. Sci. 2011, 4, 1772-1780 10.1039/c1ee01028j
71. Lewis, N. S. Toward Cost-Effective Solar Energy Use Science 2007, 315, 798-801 10.1126/science.1137014
72. Hou, Y.; Abrams, B. L.; Vesborg, P. C. K.; Bjoerketun, M. E.; Herbst, K.; Bech, L.; Setti, A. M.; Damsgaard, C. D.; Pedersen, T.; Hansen, O. et al. Bioinspired molecular co-catalysts bonded to a silicon photocathode for solar hydrogen evolution Nat. Mater. 2011, 10, 434-438 10.1038/nmat3008
73. Chen, Z.; Dinh, H. N.; Miller, E. Photoelectrochemical Water Splitting: Standards, Experimental Methods, and Protocols; Springer: New York, NY, 2013.
74. Rocheleau, R. E.; Miller, E. L.; Misra, A. High-efficiency photoelectrochemical hydrogen production using multijunction amorphous silicon photoelectrodes Energy Fuels 1998, 12, 3-10 10.1021/ef9701347
75. Surendranath, Y.; Dinca, M.; Nocera, D. G. Electrolyte-Dependent Electrosynthesis and Activity of Cobalt-Based Water Oxidation Catalysts J. Am. Chem. Soc. 2009, 131, 2615-2620 10.1021/ja807769r
76. Lutterman, D. A.; Surendranath, Y.; Nocera, D. G. A Self-Healing Oxygen-Evolving Catalyst J. Am. Chem. Soc. 2009, 131, 3838-3839 10.1021/ja900023k
77. Khaselev, O.; Turner, J. A. A monolithic photovoltaic-photoelectrochemical device for hydrogen production via water splitting Science 1998, 280, 425-427 10.1126/science.280.5362.425
78. Joya, K. S.; Joya, Y. F.; Ocakoglu, K.; van de Krol, R. Water-splitting catalysis and solar fuel devices: artificial leaves on the move Angew. Chem., Int. Ed. 2013, 52, 10426-10437 10.1002/anie.201300136
79. Bard, A. J. Photoelectrochemistry and heterogeneous photocatalysis at semiconductors J. Photochem. 1979, 10, 59-75 10.1016/0047-2670(79)80037-4
80. Maeda, K.; Higashi, M.; Lu, D.; Abe, R.; Domen, K. Efficient Nonsacrificial Water Splitting through Two-Step Photoexcitation by Visible Light using a Modified Oxynitride as a Hydrogen Evolution Photocatalyst J. Am. Chem. Soc. 2010, 132, 5858-5868 10.1021/ja1009025
81. Tada, H.; Mitsui, T.; Kiyonaga, T.; Akita, T.; Tanaka, K. All-solid-state Z-scheme in CdS-Au-TiO2 three-component nanojunction system Nat. Mater. 2006, 5, 782-786 10.1038/nmat1734
82. Iwase, A.; Ng, Y. H.; Ishiguro, Y.; Kudo, A.; Amal, R. Reduced Graphene Oxide as a Solid-State Electron Mediator in Z-Scheme Photocatalytic Water Splitting under Visible Light J. Am. Chem. Soc. 2011, 133, 11054-11057 10.1021/ja203296z
83. Kudo, A. Z-scheme photocatalyst systems for water splitting under visible light irradiation MRS Bull. 2011, 36, 32-38 10.1557/mrs.2010.3
84. Ingram, D. B.; Linic, S. Water splitting on composite plasmonic-metal/semiconductor photoelectrodes: evidence for selective plasmon-induced formation of charge carriers near the semiconductor surface J. Am. Chem. Soc. 2011, 133, 5202-5205 10.1021/ja200086g
85. Mor, G. K.; Shankar, K.; Paulose, M.; Varghese, O. K.; Grimes, C. A. Enhanced Photocleavage of Water Using Titania Nanotube Arrays Nano Lett. 2005, 5, 191-195 10.1021/nl048301k
86. Zhu, K.; Neale, N. R.; Miedaner, A.; Frank, A. J. Enhanced Charge-Collection Efficiencies and Light Scattering in Dye-Sensitized Solar Cells Using Oriented TiO2 Nanotubes Arrays Nano Lett. 2007, 7, 69-74 10.1021/nl062000o
87. Klimov, V. I. Mechanisms for Photogeneration and Recombination of Multiexcitons in Semiconductor Nanocrystals: Implications for Lasing and Solar Energy Conversion J. Phys. Chem. B 2006, 110, 16827-16845 10.1021/jp0615959
88. Meyer, B. K.; Alves, H.; Hofmann, D. M.; Kriegseis, W.; Forster, D.; Bertram, F.; Christen, J.; Hoffmann, A.; Strassburg, M.; Dworzak, M. et al. Bound exciton and donor-acceptor pair recombinations in ZnO Phys. Status Solidi B 2004, 241, 231-260 10.1002/pssb.200301962
89. Barnhart, C. J.; Dale, M.; Brandt, A. R.; Benson, S. M. The energetic implications of curtailing versus storing solar- and wind-generated electricity Energy Environ. Sci. 2013, 6, 2804-2810 10.1039/c3ee41973h
90. Youngblood, W. J.; Lee, S.-H. A.; Maeda, K.; Mallouk, T. E. Visible Light Water Splitting using Dye-Sensitized Oxide Semiconductors Acc. Chem. Res. 2009, 42, 1966-1973 10.1021/ar9002398
91. Young, K. J.; Martini, L. A.; Milot, R. L.; Snoeberger, R. C.; Batista, V. S.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W. Light-driven water oxidation for solar fuels Coord. Chem. Rev. 2012, 256, 2503-2520 10.1016/j.ccr.2012.03.031
92. Concepcion, J. J.; House, R. L.; Papanikolas, J. M.; Meyer, T. J. Chemical approaches to artificial photosynthesis Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 15560-15564 10.1073/pnas.1212254109
93. Gratzel, M. Photoelectrochemical cells Nature 2001, 414, 338-344 10.1038/35104607
94. Hamann, T. W. Water splitting An adaptive junction Nat. Mater. 2014, 13, 3-4 10.1038/nmat3843
95. Sun, J.; Zhong, D. K.; Gamelin, D. R. Composite photoanodes for photoelectrochemical solar water splitting Energy Environ. Sci. 2010, 3, 1252-1261 10.1039/c0ee00030b
96. Jiang, C.; Wang, R.; Parkinson, B. A. Combinatorial Approach to Improve Photoelectrodes Based on BiVO4 ACS Comb. Sci. 2013, 15, 639-645 10.1021/co300119q
97. Rowley, J. G.; Do, T. D.; Cleary, D. A.; Parkinson, B. A. Combinatorial Discovery Through a Distributed Outreach Program: Investigation of the Photoelectrolysis Activity of p-Type Fe, Cr, Al Oxides ACS Appl. Mater. Interfaces 2014, 6, 9046-9052 10.1021/am406045j
98. Seley, D.; Ayers, K.; Parkinson, B. A. Combinatorial search for improved metal oxide oxygen evolution electrocatalysts in acidic electrolytes ACS Comb. Sci. 2013, 15, 82-89 10.1021/co300086h
99. Xiang, C.; Suram, S. K.; Haber, J. A.; Guevarra, D. W.; Soedarmadji, E.; Jin, J.; Gregoire, J. M. High-Throughput Bubble Screening Method for Combinatorial Discovery of Electrocatalysts for Water Splitting ACS Comb. Sci. 2014, 16, 47-52 10.1021/co400151h
100. Marcus, R. A.; Sutin, N. Electron transfers in chemistry and biology Biochim. Biophys. Acta, Rev. Bioenerg. 1985, 811, 265-322 10.1016/0304-4173(85)90014-X
101. Meyer, T. J. Chemical approaches to artificial photosynthesis Acc. Chem. Res. 1989, 22, 163-170 10.1021/ar00161a001
102. Wasielewski, M. R. Photoinduced electron transfer in supramolecular systems for artificial photosynthesis Chem. Rev. 1992, 92, 435-461 10.1021/cr00011a005
103. Gust, D.; Moore, T. A.; Moore, A. L. Molecular mimicry of photosynthetic energy and electron transfer Acc. Chem. Res. 1993, 26, 198-205 10.1021/ar00028a010
104. Kay, A.; Graetzel, M. Artificial photosynthesis. 1. Photosensitization of titania solar cells with chlorophyll derivatives and related natural porphyrins J. Phys. Chem. 1993, 97, 6272-6277 10.1021/j100125a029
105. Bard, A. J.; Fox, M. A. Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen Acc. Chem. Res. 1995, 28, 141-145 10.1021/ar00051a007
106. Balzani, V.; Credi, A.; Venturi, M. Photochemical conversion of solar energy ChemSusChem 2008, 1, 26-58 10.1002/cssc.200700087
107. Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; Von Zelewsky, A. Ruthenium(II) polypyridine complexes: photophysics, photochemistry, electrochemistry, and chemiluminescence Coord. Chem. Rev. 1988, 84, 85-277 10.1016/0010-8545(88)80032-8
108. Ghosh, P. K.; Brunschwig, B. S.; Chou, M.; Creutz, C.; Sutin, N. Thermal and light-induced reduction of the ruthenium complex cation Ru(bpy)33+ in aqueous solution J. Am. Chem. Soc. 1984, 106, 4772-4783 10.1021/ja00329a022
109. Hagfeldt, A.; Boschloo, G.; Sun, L.; Kloo, L.; Pettersson, H. Dye-Sensitized Solar Cells Chem. Rev. 2010, 110, 6595-6663 10.1021/cr900356p
110. Gratzel, M. Dye-sensitized solar cells J. Photochem. Photobiol., C 2003, 4, 145-153 10.1016/S1389-5567(03)00026-1
111. Gratzel, M. Recent advances in sensitized mesoscopic solar cells Acc. Chem. Res. 2009, 42, 1788-1798 10.1021/ar900141y
112. Graetzel, M. Solar Energy Conversion by Dye-Sensitized Photovoltaic Cells Inorg. Chem. 2005, 44, 6841-6851 10.1021/ic0508371
113. ORegan, B.; Graetzel, M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal titanium dioxide films Nature 1991, 353, 737-740 10.1038/353737a0
114. Swierk, J. R.; Mallouk, T. E. Design and development of photoanodes for water-splitting dye-sensitized photoelectrochemical cells Chem. Soc. Rev. 2013, 42, 2357-2387 10.1039/C2CS35246J
115. Frischmann, P. D.; Mahata, K.; Wuerthner, F. Powering the future of molecular artificial photosynthesis with light-harvesting metallosupramolecular dye assemblies Chem. Soc. Rev. 2013, 42, 1847-1870 10.1039/C2CS35223K
116. Ashford, D. L.; Glasson, C. R. K.; Norris, M. R.; Hanson, K.; Concepcion, J. J.; Keinan, S.; Brennaman, M. K.; Templeton, J. L.; Meyer, T. J. Controlling Ground and Excited State Properties through Ligand Changes in Ruthenium Polypyridyl Complexes Inorg. Chem. 2014, 53, 5637-5646 10.1021/ic500408j
117. Thompson, D. W.; Ito, A.; Meyer, T. J. [Ru(bpy)3]2+∗ and other remarkable metal-to-ligand charge transfer (MLCT) excited states Pure Appl. Chem. 2013, 85, 1257-1305 10.1351/PAC-CON-13-03-04
118. Lever, A. B. P. Electrochemical parametrization of metal complex redox potentials, using the ruthenium(III)/ruthenium(II) couple to generate a ligand electrochemical series Inorg. Chem. 1990, 29, 1271-1285 10.1021/ic00331a030
119. Yam, V. W.-W.; Lee, V. W.-M.; Ke, F.; Siu, K.-W. M. Synthesis, Photophysics, and Electrochemistry of Ruthenium(II) Polypyridine Complexes with Crown Ether Pendants Inorg. Chem. 1997, 36, 2124-2129 10.1021/ic961400j
120. Mikkelsen, M.; Jorgensen, M.; Krebs, F. C. The teraton challenge. A review of fixation and transformation of carbon dioxide Energy Environ. Sci. 2010, 3, 43-81 10.1039/B912904A
121. Rakowski Dubois, M.; Dubois, D. L. Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation Acc. Chem. Res. 2009, 42, 1974-1982 10.1021/ar900110c
122. Schneider, J.; Jia, H.; Muckerman, J. T.; Fujita, E. Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal center of CO2 reduction catalysts Chem. Soc. Rev. 2012, 41, 2036-2051 10.1039/C1CS15278E
123. Takeda, H.; Ishitani, O. Development of efficient photocatalytic systems for CO2 reduction using mononuclear and multinuclear metal complexes based on mechanistic studies Coord. Chem. Rev. 2010, 254, 346-354 10.1016/j.ccr.2009.09.030
124. Odobel, F.; Le Pleux, L.; Pellegrin, Y.; Blart, E. New Photovoltaic Devices Based on the Sensitization of p-type Semiconductors: Challenges and Opportunities Acc. Chem. Res. 2010, 43, 1063-1071 10.1021/ar900275b
125. Odobel, F.; Pellegrin, Y. Recent advances in the sensitization of wide-band-gap nanostructured p-type semiconductors. Photovoltaic and photocatalytic applications J. Phys. Chem. Lett. 2013, 4, 2551-2564 10.1021/jz400861v
126. Alibabaei, L.; Brennaman, K. M.; Norris, M. R.; Kalanyan, B.; Song, W.; Losego, M. D.; Concepcion, J. J.; Binstead, R. A.; Parsons, G. N.; Meyer, T. J. Solar Water Splitting in a Molecular Photoelectrochemical Cell Proc. Natl. Acad. Sci. U. S. A. 2013, 110, 20008-20013 10.1073/pnas.1319628110
127. Morandeira, A.; Fortage, J.; Edvinsson, T.; Le Pleux, L.; Blart, E.; Boschloo, G.; Hagfeldt, A.; Hammarstroem, L.; Odobel, F. Improved Photon-to-Current Conversion Efficiency with a Nanoporous p-Type NiO Electrode by the Use of a Sensitizer-Acceptor Dyad J. Phys. Chem. C 2008, 112, 1721-1728 10.1021/jp077446n
128. He, J.; Lindstroem, H.; Hagfeldt, A.; Lindquist, S.-E. Dye-Sensitized Nanostructured p-Type Nickel Oxide Film as a Photocathode for a Solar Cell J. Phys. Chem. B 1999, 103, 8940-8943 10.1021/jp991681r
129. Gibson, E. A.; Smeigh, A. L.; Le Pleux, L.; Fortage, J.; Boschloo, G.; Blart, E.; Pellegrin, Y.; Odobel, F.; Hagfeldt, A.; Hammarstrom, L. A p-type NiO-based dye-sensitized solar cell with an open-circuit voltage of 0.35 V Angew. Chem., Int. Ed. 2009, 48, 4402-4405 10.1002/anie.200900423
130. Gibson, E. A.; Smeigh, A. L.; Le Pleux, L.; Hammarstroem, L.; Odobel, F.; Boschloo, G.; Hagfeldt, A. Cobalt Polypyridyl-Based Electrolytes for p-Type Dye-Sensitized Solar Cells J. Phys. Chem. C 2011, 115, 9772-9779 10.1021/jp110473n
131. Le Pleux, L.; Smeigh, A. L.; Gibson, E.; Pellegrin, Y.; Blart, E.; Boschloo, G.; Hagfeldt, A.; Hammarstrom, L.; Odobel, F. Synthesis, photophysical and photovoltaic investigations of acceptor-functionalized perylene monoimide dyes for nickel oxide p-type dye-sensitized solar cells Energy Environ. Sci. 2011, 4, 2075-2084 10.1039/c1ee01148k
132. Morandeira, A.; Boschloo, G.; Hagfeldt, A.; Hammarstroem, L. Photoinduced Ultrafast Dynamics of Coumarin 343 Sensitized p-Type-Nanostructured NiO Films J. Phys. Chem. B 2005, 109, 19403-19410 10.1021/jp053230e
133. Li, L.; Duan, L.; Wen, F.; Li, C.; Wang, M.; Hagfeldt, A.; Sun, L. Visible light driven hydrogen production from a photo-active cathode based on a molecular catalyst and organic dye-sensitized p-type nanostructured NiO Chem. Commun. 2012, 48, 988-990 10.1039/C2CC16101J
134. Green, A. N. M.; Palomares, E.; Haque, S. A.; Kroon, J. M.; Durrant, J. R. Charge Transport versus Recombination in Dye-Sensitized Solar Cells Employing Nanocrystalline TiO2 and SnO2 Films J. Phys. Chem. B 2005, 109, 12525-12533 10.1021/jp050145y
135. Brennaman, M. K.; Patrocinio, A. O. T.; Song, W.-J.; Jurss, J. W.; Concepcion, J. J.; Hoertz, P. G.; Traub, M. C.; Murakami Iha, N. Y.; Meyer, T. J. Interfacial Electron Transfer Dynamics Following Laser Flash Photolysis of [Ru(bpy)2((4,4′-PO3H2)2bpy)]2+ in TiO2 Nanoparticle Films in Aqueous Environments ChemSusChem 2011, 4, 216-227 10.1002/cssc.201000356
136. Hanson, K.; Brennaman, M. K.; Ito, A.; Luo, H.; Song, W.; Parker, K. A.; Ghosh, R.; Norris, M. R.; Glasson, C. R. K.; Concepcion, J. J. et al. Structure-Property Relationships in Phosphonate-Derivatized, RuII Polypyridyl Dyes on Metal Oxide Surfaces in an Aqueous Environment J. Phys. Chem. C 2012, 116, 14837-14847 10.1021/jp304088d
137. Knauf, R. R.; Brennaman, M. K.; Alibabaei, L.; Norris, M. R.; Dempsey, J. L. Revealing the Relationship between Semiconductor Electronic Structure and Electron Transfer Dynamics at Metal Oxide-Chromophore Interfaces J. Phys. Chem. C 2013, 117, 25259-25268 10.1021/jp407587r
138. Nayak, A.; Knauf, R. R.; Hanson, K.; Alibabaei, L.; Concepcion, J. J.; Ashford, D. L.; Dempsey, J. L.; Meyer, T. J. Synthesis and photophysical characterization of porphyrin and porphyrin-Ru(ii) polypyridyl chromophore-catalyst assemblies on mesoporous metal oxides Chemical Science 2014, 5, 3115-3119 10.1039/c4sc00875h
139. Arai, T.; Sato, S.; Kajino, T.; Morikawa, T. Solar CO2 reduction using H2O by a semiconductor/metal-complex hybrid photocatalyst: enhanced efficiency and demonstration of a wireless system using SrTiO3 photoanodes Energy Environ. Sci. 2013, 6, 1274-1282 10.1039/c3ee24317f
140. Sato, S.; Arai, T.; Morikawa, T.; Uemura, K.; Suzuki, T. M.; Tanaka, H.; Kajino, T. Selective CO2 Conversion to Formate Conjugated with H2O Oxidation Utilizing Semiconductor/Complex Hybrid Photocatalysts J. Am. Chem. Soc. 2011, 133, 15240-15243 10.1021/ja204881d
141. Luo, H.; Song, W.; Hoertz, P. G.; Hanson, K.; Ghosh, R.; Rangan, S.; Brennaman, M. K.; Concepcion, J. J.; Binstead, R. A.; Bartynski, R. A. et al. A Sensitized Nb2O5 Photoanode for Hydrogen Production in a Dye-Sensitized Photoelectrosynthesis Cell Chem. Mater. 2013, 25, 122-131 10.1021/cm3027972
142. Zheng, H.; Tachibana, Y.; Kalantar-zadeh, K. Dye-sensitized solar cells based on WO3 Langmuir 2010, 26, 19148-19152 10.1021/la103692y
143. Sadek, A. Z.; Zheng, H.; Breedon, M.; Bansal, V.; Bhargava, S. K.; Latham, K.; Zhu, J.; Yu, L.; Hu, Z.; Spizzirri, P. G. et al. High-Temperature Anodized WO3 Nanoplatelet Films for Photosensitive Devices Langmuir 2009, 25, 9545-9551 10.1021/la901944x
144. Anta, J. A.; Guillen, E.; Tena-Zaera, R. ZnO-Based Dye-Sensitized Solar Cells J. Phys. Chem. C 2012, 116, 11413-11425 10.1021/jp3010025
145. Xu, F.; Sun, L. Solution-derived ZnO nanostructures for photoanodes of dye-sensitized solar cells Energy Environ. Sci. 2011, 4, 818-841 10.1039/C0EE00448K
146. Lenzmann, F.; Krueger, J.; Burnside, S.; Brooks, K.; Graetzel, M.; Gal, D.; Ruehle, S.; Cahen, D. Surface Photovoltage Spectroscopy of Dye-Sensitized Solar Cells with TiO2, Nb2O5, and SrTiO3 Nanocrystalline Photoanodes: Indication for Electron Injection from Higher Excited Dye States J. Phys. Chem. B 2001, 105, 6347-6352 10.1021/jp010380q
147. Coutts, T. J.; Young, D. L.; Li, X.; Mulligan, W. P.; Wu, X. Search for improved transparent conducting oxides: A fundamental investigation of CdO, Cd2SnO4, and Zn2SnO4 J. Vac. Sci. Technol., A 2000, 18, 2646-2660 10.1116/1.1290371
148. Yang, S.-M.; Kou, H.-Z.; Wang, H.-J.; Cheng, K.; Wang, J.-C. Preparation and Band Energetics of Transparent Nanostructured SrTiO3 Film Electrodes J. Phys. Chem. C 2010, 114, 815-819 10.1021/jp910204q
149. Burnside, S.; Moser, J.-E.; Brooks, K.; Graetzel, M.; Cahen, D. Nanocrystalline Mesoporous Strontium Titanate as Photoelectrode Material for Photosensitized Solar Devices: Increasing Photovoltage through Flatband Potential Engineering J. Phys. Chem. B 1999, 103, 9328-9332 10.1021/jp9913867
150. Zou, C.; Wrighton, M. S. Synthesis of octamethylferrocene derivatives via reaction of (octamethylferrocenyl)methyl carbocation with nucleophiles and application to functionalization of surfaces J. Am. Chem. Soc. 1990, 112, 7578-7584 10.1021/ja00177a020
151. McNamara, W. R.; Milot, R. L.; Song, H.-e.; Snoeberger, R. C., III; Batista, V. S.; Schmuttenmaer, C. A.; Brudvig, G. W.; Crabtree, R. H. Water-stable, hydroxamate anchors for functionalization of TiO2 surfaces with ultrafast interfacial electron transfer Energy Environ. Sci. 2010, 3, 917-923 10.1039/c001065k
152. Haller, I. Covalently attached organic monolayers on semiconductor surfaces J. Am. Chem. Soc. 1978, 100, 8050-8055 10.1021/ja00494a003
153. McNamara, W. R.; Snoeberger, R. C.; Li, G.; Schleicher, J. M.; Cady, C. W.; Poyatos, M.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W.; Batista, V. S. Acetylacetonate Anchors for Robust Functionalization of TiO2 Nanoparticles with Mn(II)-Terpyridine Complexes J. Am. Chem. Soc. 2008, 130, 14329-14338 10.1021/ja805498w
154. Hanson, K.; Brennaman, M. K.; Luo, H.; Glasson, C. R. K.; Concepcion, J. J.; Song, W.; Meyer, T. J. Photostability of Phosphonate-Derivatized, RuII Polypyridyl Complexes on Metal Oxide Surfaces ACS Appl. Mater. Interfaces 2012, 4, 1462-1469 10.1021/am201717x
155. Brown, D. G.; Schauer, P. A.; Borau-Garcia, J.; Fancy, B. R.; Berlinguette, C. P. Stabilization of Ruthenium Sensitizers to TiO2 Surfaces through Cooperative Anchoring Groups J. Am. Chem. Soc. 2013, 135, 1692-1695 10.1021/ja310965h
156. Hanson, K.; Losego, M. D.; Kalanyan, B.; Ashford, D. L.; Parsons, G. N.; Meyer, T. J. Stabilization of [Ru(bpy)2(4,4′-(PO3H2)bpy)]2+ on Mesoporous TiO2 with Atomic Layer Deposition of Al2O3 Chem. Mater. 2013, 25, 3-5 10.1021/cm303172w
157. Hanson, K.; Losego, M. D.; Kalanyan, B.; Parsons, G. N.; Meyer, T. J. Stabilizing Small Molecules on Metal Oxide Surfaces Using Atomic Layer Deposition Nano Lett. 2013, 13, 4802-4809 10.1021/nl402416s
158. Losego, M. D.; Hanson, K. Stabilizing molecular sensitizers in aqueous environs Nano Energy 2013, 2, 1067-1069 10.1016/j.nanoen.2013.07.007
159. Vannucci, A. K.; Alibabaei, L.; Losego, M. D.; Concepcion, J. J.; Kalanyan, B.; Parsons, G. N.; Meyer, T. J. Crossign the Divide Between Homogenous and Heterogeneous Catalysis Proc. Natl. Acad. Sci. U. S. A. 2013, 110, 20918-20922 10.1073/pnas.1319832110
160. Son, H.-J.; Wang, X.; Prasittichai, C.; Jeong, N. C.; Aaltonen, T.; Gordon, R. G.; Hupp, J. T. Glass-Encapsulated Light Harvesters: More Efficient Dye-Sensitized Solar Cells by Deposition of Self-Aligned, Conformal, and Self-Limited Silica Layers J. Am. Chem. Soc. 2012, 134, 9537-9540 10.1021/ja300015n
161. Son, H.-J.; Prasittichai, C.; Mondloch, J. E.; Luo, L.; Wu, J.; Kim, D. W.; Farha, O. K.; Hupp, J. T. Dye Stabilization and Enhanced Photoelectrode Wettability in Water-Based Dye-Sensitized Solar Cells through Post-assembly Atomic Layer Deposition of TiO2 J. Am. Chem. Soc. 2013, 135, 11529-11532 10.1021/ja406538a
162. Antila, L. J.; Heikkila, M. J.; Makinen, V.; Humalamaki, N.; Laitinen, M.; Linko, V.; Jalkanen, P.; Toppari, J.; Aumanen, V.; Kemell, M. et al. ALD Grown Aluminum Oxide Submonolayers in Dye-Sensitized Solar Cells: The Effect on Interfacial Electron Transfer and Performance J. Phys. Chem. C 2011, 115, 16720-16729 10.1021/jp204886n
163. Prasittichai, C.; Hupp, J. T. Surface Modification of SnO2 Photoelectrodes in Dye-Sensitized Solar Cells: Significant Improvements in Photovoltage via Al2O3 Atomic Layer Deposition J. Phys. Chem. Lett. 2010, 1, 1611-1615 10.1021/jz100361f
164. Wee, K.-R.; Brennaman, M. K.; Alibabaei, L.; Farnum, B. H.; Sherman, B.; Lapides, A. M.; Meyer, T. J. Stabilization of Ruthenium(II) Polypyridyl Chromophores on Nanoparticle Metal-Oxide Electrodes in Water by Hydrophobic PMMA Overlayers J. Am. Chem. Soc. 2014, 136, 13514-13517 10.1021/ja506987a
165. Ashford, D. L.; Lapides, A. M.; Vannucci, A. K.; Hanson, K.; Torelli, D. A.; Harrison, D. P.; Templeton, J. L.; Meyer, T. J. Water Oxidation by an Electropolymerized Catalyst on Derivatized Mesoporous Metal Oxide Electrodes J. Am. Chem. Soc. 2014, 136, 6578-6581 10.1021/ja502464s
166. Lapides, A. M.; Ashford, D. L.; Hanson, K.; Torelli, D. A.; Templeton, J. L.; Meyer, T. J. Stabilization of a Ruthenium(II) Polypyridyl Dye on Nanocrystalline TiO2 by an Electropolymerized Overlayer J. Am. Chem. Soc. 2013, 135, 15450-15458 10.1021/ja4055977
167. Ashford, D. L.; Sherman, B. D.; Binstead, R. A.; Templeton, J. L.; Meyer, T. J. Electro-Assembly of a Chromophore-Catalyst Bilayer for Water Oxidation and Photocatalytic Water Splitting Angew. Chem., Int. Ed. 2015, 54, 4778-4781 10.1002/anie.201410944
168. Liu, F.; Concepcion, J. J.; Jurss, J. W.; Cardolaccia, T.; Templeton, J. L.; Meyer, T. J. Mechanisms of Water Oxidation from the Blue Dimer to Photosystem II Inorg. Chem. 2008, 47, 1727-1752 10.1021/ic701249s
169. Akimov, A. V.; Neukirch, A. J.; Prezhdo, O. V. Theoretical Insights into Photoinduced Charge Transfer and Catalysis at Oxide Interfaces Chem. Rev. 2013, 113, 4496-4565 10.1021/cr3004899
170. Kaerkaes, M. D.; Verho, O.; Johnston, E. V.; Aakermark, B. Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation Chem. Rev. 2014, 114, 11863-12001 10.1021/cr400572f
171. Ardo, S.; Meyer, G. J. Photodriven heterogeneous charge transfer with transition-metal compounds anchored to TiO2 semiconductor surfaces Chem. Soc. Rev. 2009, 38, 115-164 10.1039/B804321N
172. Li, J.; Djurovich, P. I.; Alleyne, B. D.; Yousufuddin, M.; Ho, N. N.; Thomas, J. C.; Peters, J. C.; Bau, R.; Thompson, M. E. Synthetic Control of Excited-State Properties in Cyclometalated Ir(III) Complexes Using Ancillary Ligands Inorg. Chem. 2005, 44, 1713-1727 10.1021/ic048599h
173. Chen, P.; Meyer, T. J. Medium Effects on Charge Transfer in Metal Complexes Chem. Rev. 1998, 98, 1439-1477 10.1021/cr941180w
174. Juban, E. A.; Smeigh, A. L.; Monat, J. E.; McCusker, J. K. Ultrafast dynamics of ligand-field excited states Coord. Chem. Rev. 2006, 250, 1783-1791 10.1016/j.ccr.2006.02.010
175. Kalyanasundaram, K. Photophysics, photochemistry and solar energy conversion with tris(bipyridyl)ruthenium(II) and its analogs Coord. Chem. Rev. 1982, 46, 159-244 10.1016/0010-8545(82)85003-0
176. Huynh, M. H. V.; Dattelbaum, D. M.; Meyer, T. J. Exited state electron and energy transfer in molecular assemblies Coord. Chem. Rev. 2005, 249, 457-483 10.1016/j.ccr.2004.07.005
177. Anderson, P. A.; Strouse, G. F.; Treadway, J. A.; Keene, F. R.; Meyer, T. J. Black MLCT Absorbers Inorg. Chem. 1994, 33, 3863-3864 10.1021/ic00096a007
178. Kakiage, K.; Aoyama, Y.; Yano, T.; Oya, K.; Kyomen, T.; Hanaya, M. Fabrication of a high-performance dye-sensitized solar cell with 12.8% conversion efficiency using organic silyl-anchor dyes Chem. Commun. 2015, 51, 6315-6317 10.1039/C5CC00464K
179. Martinez-Diaz, M. V.; de la Torre, G.; Torres, T. Lighting porphyrins and phthalocyanines for molecular photovoltaics Chem. Commun. 2010, 46, 7090-7108 10.1039/c0cc02213f
180. Wang, Z.-S.; Koumura, N.; Cui, Y.; Takahashi, M.; Sekiguchi, H.; Mori, A.; Kubo, T.; Furube, A.; Hara, K. Hexylthiophene-Functionalized Carbazole Dyes for Efficient Molecular Photovoltaics: Tuning of Solar-Cell Performance by Structural Modification Chem. Mater. 2008, 20, 3993-4003 10.1021/cm8003276
181. Jeon, N. J.; Noh, J. H.; Yang, W. S.; Kim, Y. C.; Ryu, S.; Seo, J.; Seok, S. I. Compositional engineering of perovskite materials for high-performance solar cells Nature 2015, 517, 476-480 10.1038/nature14133
182. Gagliardi, C. J.; Westlake, B. C.; Kent, C. A.; Paul, J. J.; Papanikolas, J. M.; Meyer, T. J. Integrating proton coupled electron transfer (PCET) and excited states Coord. Chem. Rev. 2010, 254, 2459-2471 10.1016/j.ccr.2010.03.001
183. McEvoy, J. P.; Brudvig, G. W. Water-splitting chemistry of photosystem II Chem. Rev. 2006, 106, 4455-4483 10.1021/cr0204294
184. Barber, J.; Ferreira, K.; Maghlaoui, K.; Iwata, S. Structural model of the oxygen-evolving centre of photosystem II with mechanistic implications Phys. Chem. Chem. Phys. 2004, 6, 4737-4742 10.1039/b407981g
185. Ishikita, H.; Saenger, W.; Loll, B.; Biesiadka, J.; Knapp, E.-W. Energetics of a Possible Proton Exit Pathway for Water Oxidation in Photosystem II Biochemistry 2006, 45, 2063-2071 10.1021/bi051615h
186. Farnum, B. H.; Morseth, Z. A.; Brennaman, M. K.; Papanikolas, J. M.; Meyer, T. J. Driving Force Dependent, Photoinduced Electron Transfer at Degenerately Doped, Optically Transparent Semiconductor Nanoparticle Interfaces J. Am. Chem. Soc. 2014, 136, 15869-15872 10.1021/ja508862h
187. Farnum, B. H.; Morseth, Z. A.; Brennaman, M. K.; Papanikolas, J. M.; Meyer, T. J. Application of Degenerately Doped Metal Oxides in the Study of Photoinduced Interfacial Electron Transfer J. Phys. Chem. B 2015, 119, 7698-7711 10.1021/jp512624u
188. Alstrum-Acevedo, J. H.; Brennaman, M. K.; Meyer, T. J. Chemical Approaches to Artificial Photosynthesis. 2 Inorg. Chem. 2005, 44, 6802-6827 10.1021/ic050904r
189. Ulstrup, J.; Jortner, J. Effect of intramolecular quantum modes on free energy relations for electron transfer reactions J. Chem. Phys. 1975, 63, 4358-4368 10.1063/1.431152
190. Kestner, N. R.; Logan, J.; Jortner, J. Thermal electron transfer reactions in polar solvents J. Phys. Chem. 1974, 78, 2148-2166 10.1021/j100614a017
191. Jortner, J. Temperature dependent activation energy for electron transfer between biological molecules J. Chem. Phys. 1976, 64, 4860-4867 10.1063/1.432142
192. Sutin, N. Theory of electron transfer reactions: insights and hindsights Prog. Inorg. Chem. 1983, 30, 441-498 10.1002/9780470166314.ch9
193. Meyer, T. J.; Taube, H. In Comprehensive Coordination Chemistry, The Synthesis, Reactions, Properties and Applications of Coordination Compounds; Pergammon Press: Oxford, U.K., 1987; Vol. 1.
194. Kim, H. B.; Kitamura, N.; Tazuke, S. Time-dependent nonradiative decay in the metal-to-ligand charge-transfer excited state of tris(2,2′-bipyridine)ruthenium(2+) J. Phys. Chem. 1990, 94, 7401-7405 10.1021/j100382a017
195. Ito, A.; Meyer, T. J. The Golden Rule. Application for fun and profit in electron transfer, energy transfer, and excited-state decay Phys. Chem. Chem. Phys. 2012, 14, 13731-13745 10.1039/c2cp41658a
196. 2J. Phys. Chem. C 2013, 117, 812-824 10.1021/jp310155q
197. Caspar, J. V.; Meyer, T. J. Photochemistry of tris(2,2′-bipyridine)ruthenium(2+) ion (Ru(bpy)32+). Solvent effects J. Am. Chem. Soc. 1983, 105, 5583-5590 10.1021/ja00355a009
198. Kestell, J. D.; Williams, Z. L.; Stultz, L. K.; Claude, J. P. Medium Dependence of Intramolecular Vibrational Modes Coupled to MLCT Transitions in Metal Polypyridyl Complexes J. Phys. Chem. A 2002, 106, 5768-5778 10.1021/jp0204758
199. Nozaki, K.; Takamori, K.; Nakatsugawa, Y.; Ohno, T. Theoretical Studies of Phosphorescence Spectra of Tris(2,2′-bipyridine) Transition Metal Compounds Inorg. Chem. 2006, 45, 6161-6178 10.1021/ic052068r
200. Ardo, S.; Sun, Y.; Castellano, F. N.; Meyer, G. J. Excited-State Electron Transfer from Ruthenium-Polypyridyl Compounds to Anatase TiO2 Nanocrystallites: Evidence for a Stark Effect J. Phys. Chem. B 2010, 114, 14596-14604 10.1021/jp102349m
201. Miller, S. A.; West, B. A.; Curtis, A. C.; Papanikolas, J. M.; Moran, A. M. Communication: Uncovering molecule-TiO2 interactions with nonlinear spectroscopy J. Chem. Phys. 2011, 135, 081101-081104 10.1063/1.3631339
202. Hannappel, T.; Burfeindt, B.; Storck, W.; Willig, F. Measurement of ultrafast photoinduced electron transfer from chemically anchored Ru-dye molecules into empty electronic states in a colloidal anatase TiO2 film J. Phys. Chem. B 1997, 101, 6799-6802 10.1021/jp971581q
203. Tachibana, Y.; Haque, S. A.; Mercer, I. P.; Durrant, J. R.; Klug, D. R. Electron Injection and Recombination in Dye Sensitized Nanocrystalline Titanium Dioxide Films: A Comparison of Ruthenium Bipyridyl and Porphyrin Sensitizer Dyes J. Phys. Chem. B 2000, 104, 1198-1205 10.1021/jp992774b
204. Tachibana, Y.; Moser, J. E.; Graetzel, M.; Klug, D. R.; Durrant, J. R. Subpicosecond interfacial charge separation in dye-sensitized nanocrystalline titanium dioxide films J. Phys. Chem. 1996, 100, 20056-20062 10.1021/jp962227f
205. Doyle, R. L.; Godwin, I. J.; Brandon, M. P.; Lyons, M. E. G. Redox and electrochemical water splitting catalytic properties of hydrated metal oxide modified electrodes Phys. Chem. Chem. Phys. 2013, 15, 13737-13783 10.1039/c3cp51213d
206. Jiao, F.; Frei, H. Nanostructured cobalt and manganese oxide clusters as efficient water oxidation catalysts Energy Environ. Sci. 2010, 3, 1018-1027 10.1039/c002074e
207. Fang, Y.-H.; Liu, Z.-P. Mechanism and Tafel lines of electro-oxidation of water to oxygen on RuO2(110) J. Am. Chem. Soc. 2010, 132, 18214-18222 10.1021/ja1069272
208. Winther-Jensen, B.; Winther-Jensen, O.; Forsyth, M.; MacFarlane, D. R. High Rates of Oxygen Reduction over a Vapor Phase-Polymerized PEDOT Electrode Science 2008, 321, 671-674 10.1126/science.1159267
209. Da Silva, L. M.; Boodts, J. F. C.; De Faria, L. A. Oxygen evolution at RuO2(x)+Co3O4(1-x) electrodes from acid solution Electrochim. Acta 2001, 46, 1369-1375 10.1016/S0013-4686(00)00716-7
210. Jirkovsky, J.; Makarova, M.; Krtil, P. Particle size dependence of oxygen evolution reaction on nanocrystalline RuO2 and Ru0.8Co0.2O2-x Electrochem. Commun. 2006, 8, 1417-1422 10.1016/j.elecom.2006.06.027
211. Bertoncello, R.; Cattarin, S.; Frateur, I.; Musiani, M. Preparation of anodes for oxygen evolution by electrodeposition of composite oxides of Pb and Ru on Ti J. Electroanal. Chem. 2000, 492, 145-149 10.1016/S0022-0728(00)00300-4
212. Hurst, J. K. Water oxidation catalyzed by dimeric μ-oxo bridged ruthenium diimine complexes Coord. Chem. Rev. 2005, 249, 313-328 10.1016/j.ccr.2004.06.017
213. Gersten, S. W.; Samuels, G. J.; Meyer, T. J. Catalytic oxidation of water by an oxo-bridged ruthenium dimer J. Am. Chem. Soc. 1982, 104, 4029-4030 10.1021/ja00378a053
214. 4+, The Blue Dimer Inorg. Chem. 2012, 51, 1345-1358 10.1021/ic201521w
215. Jurss, J. W.; Concepcion, J. C.; Norris, M. R.; Templeton, J. L.; Meyer, T. J. Surface Catalysis of Water Oxidation by the Blue Ruthenium Dimer Inorg. Chem. 2010, 49, 3980-3982 10.1021/ic100469x
216. Concepcion, J. J.; Jurss, J. W.; Templeton, J. L.; Meyer, T. J. Mediator-assisted water oxidation by the ruthenium "blue dimer" cis,cis-[(bpy)2(H2O)RuORu(OH2) (bpy)2]4+ Proc. Natl. Acad. Sci. U. S. A. 2008, 105, 17632-17635 10.1073/pnas.0807153105
217. Chen, Z.; Concepcion, J. J.; Jurss, J. W.; Meyer, T. J. Single-Site, Catalytic Water Oxidation on Oxide Surfaces J. Am. Chem. Soc. 2009, 131, 15580-15581 10.1021/ja906391w
218. Concepcion, J. J.; Jurss, J. W.; Hoertz, P. G.; Meyer, T. J. Catalytic and Surface-Electrocatalytic Water Oxidation by Redox Mediator-Catalyst Assemblies Angew. Chem., Int. Ed. 2009, 48, 9473-9476 10.1002/anie.200901279
219. Zong, R.; Thummel, R. P. A New Family of Ru Complexes for Water Oxidation J. Am. Chem. Soc. 2005, 127, 12802-12803 10.1021/ja054791m
220. Tseng, H.-W.; Zong, R.; Muckerman, J. T.; Thummel, R. Mononuclear Ruthenium(II) Complexes That Catalyze Water Oxidation Inorg. Chem. 2008, 47, 11763-11773 10.1021/ic8014817
221. Chen, Z.; Concepcion, J. J.; Hull, J. F.; Hoertz, P. G.; Meyer, T. J. Catalytic water oxidation on derivatized nanoITO Dalton Transactions 2010, 39, 6950-6952 10.1039/c0dt00362j
222. Duan, L.; Bozoglian, F.; Mandal, S.; Stewart, B.; Privalov, T.; Llobet, A.; Sun, L. A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II Nat. Chem. 2012, 4, 418-423 10.1038/nchem.1301
223. Duan, L.; Wang, L.; Inge, A. K.; Fischer, A.; Zou, X.; Sun, L. Insights into Ru-Based Molecular Water Oxidation Catalysts: Electronic and Noncovalent-Interaction Effects on Their Catalytic Activities Inorg. Chem. 2013, 52, 7844-7852 10.1021/ic302687d
224. Li, F.; Zhang, B.; Li, X.; Jiang, Y.; Chen, L.; Li, Y.; Sun, L. Highly Efficient Oxidation of Water by a Molecular Catalyst Immobilized on Carbon Nanotubes Angew. Chem., Int. Ed. 2011, 50, 12276-12279 10.1002/anie.201105044
225. Wasylenko, D. J.; Ganesamoorthy, C.; Koivisto, B. D.; Henderson, M. A.; Berlinguette, C. P. Insight into Water Oxidation by Mononuclear Polypyridyl Ru Catalysts Inorg. Chem. 2010, 49, 2202-2209 10.1021/ic902024s
226. Badiei, Y. M.; Polyansky, D. E.; Muckerman, J. T.; Szalda, D. J.; Haberdar, R.; Zong, R.; Thummel, R. P.; Fujita, E. Water Oxidation with Mononuclear Ruthenium(II) Polypyridine Complexes Involving a Direct RuIV=O Pathway in Neutral and Alkaline Media Inorg. Chem. 2013, 52, 8845-8850 10.1021/ic401023w
227. Sala, X.; Maji, S.; Bofill, R.; Garcia-Anton, J.; Escriche, L.; Llobet, A. Molecular Water Oxidation Mechanisms Followed by Transition Metals: State of the Art Acc. Chem. Res. 2014, 47, 504-516 10.1021/ar400169p
228. Hull, J. F.; Balcells, D.; Blakemore, J. D.; Incarvito, C. D.; Eisenstein, O.; Brudvig, G. W.; Crabtree, R. H. Highly Active and Robust Cp∗ Iridium Complexes for Catalytic Water Oxidation J. Am. Chem. Soc. 2009, 131, 8730-8731 10.1021/ja901270f
229. Blakemore, J. D.; Schley, N. D.; Balcells, D.; Hull, J. F.; Olack, G. W.; Incarvito, C. D.; Eisenstein, O.; Brudvig, G. W.; Crabtree, R. H. Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis J. Am. Chem. Soc. 2010, 132, 16017-16029 10.1021/ja104775j
230. Schley, N. D.; Blakemore, J. D.; Subbaiyan, N. K.; Incarvito, C. D.; DSouza, F.; Crabtree, R. H.; Brudvig, G. W. Distinguishing Homogeneous from Heterogeneous Catalysis in Electrode-Driven Water Oxidation with Molecular Iridium Complexes J. Am. Chem. Soc. 2011, 133, 10473-10481 10.1021/ja2004522
231. Joya, K. S.; Subbaiyan, N. K.; DSouza, F.; de Groot, H. J. M. Surface-Immobilized Single-Site Iridium Complexes for Electrocatalytic Water Splitting Angew. Chem., Int. Ed. 2012, 51, 9601-9605 10.1002/anie.201203560
232. McDaniel, N. D.; Coughlin, F. J.; Tinker, L. L.; Bernhard, S. Cyclometalated Iridium(III) Aquo Complexes: Efficient and Tunable Catalysts for the Homogeneous Oxidation of Water J. Am. Chem. Soc. 2008, 130, 210-217 10.1021/ja074478f
233. Savini, A.; Bellachioma, G.; Ciancaleoni, G.; Zuccaccia, C.; Zuccaccia, D.; Macchioni, A. Iridium(III) molecular catalysts for water oxidation: the simpler the faster Chem. Commun. 2010, 46, 9218-9219 10.1039/c0cc03801f
234. Wasylenko, D. J.; Ganesamoorthy, C.; Borau-Garcia, J.; Berlinguette, C. P. Electrochemical evidence for catalytic water oxidation mediated by a high-valent cobalt complex Chem. Commun. 2011, 47, 4249-4251 10.1039/c0cc05522k
235. Dogutan, D. K.; McGuire, R.; Nocera, D. G. Electrocatalytic Water Oxidation by Cobalt(III) Hangman β-Octafluoro Corroles J. Am. Chem. Soc. 2011, 133, 9178-9180 10.1021/ja202138m
236. Barnett, S. M.; Goldberg, K. I.; Mayer, J. M. A soluble copper-bipyridine water-oxidation electrocatalyst Nat. Chem. 2012, 4, 498-502 10.1038/nchem.1350
237. Codola, Z.; Garcia-Bosch, I.; Acuna-Pares, F.; Prat, I.; Luis, J. M.; Costas, M.; Lloret-Fillol, J. Electronic Effects on Single-Site Iron Catalysts for Water Oxidation Chem.-Eur. J. 2013, 19, 8042-8047 10.1002/chem.201301112
238. Ellis, W. C.; McDaniel, N. D.; Bernhard, S.; Collins, T. J. Fast Water Oxidation Using Iron J. Am. Chem. Soc. 2010, 132, 10990-10991 10.1021/ja104766z
239. Fillol, J. L.; Codola, Z.; Garcia-Bosch, I.; Gomez, L.; Pla, J. J.; Costas, M. Efficient water oxidation catalysts based on readily available iron coordination complexes Nat. Chem. 2011, 3, 807-813 10.1038/nchem.1140
240. Joya, K. S.; Valles-Pardo, J. L.; Joya, Y. F.; Eisenmayer, T.; Thomas, B.; Buda, F.; de Groot, H. J. M. Molecular Catalytic Assemblies for Electrodriven Water Splitting ChemPlusChem 2013, 78, 35-47 10.1002/cplu.201200161
241. Wasylenko, D. J.; Palmer, R. D.; Berlinguette, C. P. Homogeneous water oxidation catalysts containing a single metal site Chem. Commun. 2013, 49, 218-227 10.1039/C2CC35632E
242. Cao, R.; Lai, W.; Du, P. Catalytic water oxidation at single metal sites Energy Environ. Sci. 2012, 5, 8134-8157 10.1039/c2ee21494f
243. Singh, A.; Spiccia, L. Water oxidation catalysts based on abundant 1st row transition metals Coord. Chem. Rev. 2013, 257, 2607-2622 10.1016/j.ccr.2013.02.027
244. Hintermair, U.; Sheehan, S. W.; Parent, A. R.; Ess, D. H.; Richens, D. T.; Vaccaro, P. H.; Brudvig, G. W.; Crabtree, R. H. Precursor Transformation during Molecular Oxidation Catalysis with Organometallic Iridium Complexes J. Am. Chem. Soc. 2013, 135, 10837-10851 10.1021/ja4048762
245. Blakemore, J. D.; Mara, M. W.; Kushner-Lenhoff, M. N.; Schley, N. D.; Konezny, S. J.; Rivalta, I.; Negre, C. F. A.; Snoeberger, R. C.; Kokhan, O.; Huang, J. et al. Characterization of an Amorphous Iridium Water-Oxidation Catalyst Electrodeposited from Organometallic Precursors Inorg. Chem. 2013, 52, 1860-1871 10.1021/ic301968j
246. Wang, D.; Groves, J. T. Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base Proc. Natl. Acad. Sci. U. S. A. 2013, 110, 15579-15584 10.1073/pnas.1315383110
247. Lopez, A. M.; Natali, M.; Pizzolato, E.; Chiorboli, C.; Bonchio, M.; Sartorel, A.; Scandola, F. A Co(II)-Ru(II) dyad relevant to light-driven water oxidation catalysis Phys. Chem. Chem. Phys. 2014, 16, 12000-12007 10.1039/c3cp55369h
248. Chen, Z. F.; Meyer, T. J. Copper(II) Catalysis of Water Oxidation Angew. Chem., Int. Ed. 2013, 52, 700-703 10.1002/anie.201207215
249. Zhang, M. T.; Chen, Z. F.; Kang, P.; Meyer, T. J. Electrocatalytic Water Oxidation with a Copper(II) Polypeptide Complex J. Am. Chem. Soc. 2013, 135, 2048-2051 10.1021/ja3097515
250. de Oliveira, F. T.; Chanda, A.; Banerjee, D.; Shan, X.; Mondal, S.; Que, L., Jr.; Bominaar, E. L.; Muenck, E.; Collins, T. J. Chemical and spectroscopic evidence for an FeV-Oxo Complex Science 2007, 315, 835-838 10.1126/science.1133417
251. Gagliardi, C. J.; Vannucci, A. K.; Concepcion, J. J.; Chen, Z. F.; Meyer, T. J. The role of proton coupled electron transfer in water oxidation Energy Environ. Sci. 2012, 5, 7704-7717 10.1039/c2ee03311a
252. Lin, X.; Hu, X.; Concepcion, J. J.; Chen, Z.; Liu, S.; Meyer, T. J.; Yang, W. Theoretical study of catalytic mechanism for single-site water oxidation process Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 15669-15672 10.1073/pnas.1118344109
253. Hughes, T. F.; Friesner, R. A. Systematic Investigation of the Catalytic Cycle of a Single Site Ruthenium Oxygen Evolving Complex Using Density Functional Theory J. Phys. Chem. B 2011, 115, 9280-9289 10.1021/jp2026576
254. Duan, L.; Fischer, A.; Xu, Y.; Sun, L. Isolated Seven-Coordinate Ru(IV) Dimer Complex with [HOHOH]- Bridging Ligand as an Intermediate for Catalytic Water Oxidation J. Am. Chem. Soc. 2009, 131, 10397-10399 10.1021/ja9034686
255. Dau, H.; Limberg, C.; Reier, T.; Risch, M.; Roggan, S.; Strasser, P. The Mechanism of Water Oxidation: from Electrolysis via Homogeneous to Biological Catalysis ChemCatChem 2010, 2, 724-761 10.1002/cctc.201000126
256. Cady, C. W.; Crabtree, R. H.; Brudvig, G. W. Functional models for the oxygen-evolving complex of photosystem II Coord. Chem. Rev. 2008, 252, 444-455 10.1016/j.ccr.2007.06.002
257. Chen, Z.; Concepcion, J. J.; Hu, X.; Yang, W.; Hoertz, P. G.; Meyer, T. J. Concerted O atom-proton transfer in the O-O bond forming step in water oxidation Proc. Natl. Acad. Sci. U. S. A. 2010, 107, 7225-7229 10.1073/pnas.1001132107
258. Chen, Z. F.; Concepcion, J. J.; Hu, X. Q.; Yang, W. T.; Hoertz, P. G.; Meyer, T. J. Concerted O atom-proton transfer in the O-O bond forming step in water oxidation Proc. Natl. Acad. Sci. U. S. A. 2010, 107, 7225-7229 10.1073/pnas.1001132107
259. Chen, Z. F.; Concepcion, J. J.; Luo, H. L.; Hull, J. F.; Paul, A.; Meyer, T. J. Nonaqueous Catalytic Water Oxidation J. Am. Chem. Soc. 2010, 132, 17670-17673 10.1021/ja107347n
260. Duan, L.; Araujo, C. M.; Ahlquist, M. S. G.; Sun, L. Highly efficient and robust molecular ruthenium catalysts for water oxidation Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 15584-15588 10.1073/pnas.1118347109
261. Concepcion, J. J.; Zhong, D. K.; Szalda, D. J.; Muckerman, J. T.; Fujita, E. Mechanism of water oxidation by [Ru(bda)(L)2]: the return of the "blue dimer" Chem. Commun. 2015, 51, 4105-4108 10.1039/C4CC07968J
262. Song, N.; Concepcion, J. J.; Binstead, R. A.; Rudd, J. A.; Vannucci, A. K.; Dares, C. J.; Coggins, M. K.; Meyer, T. J. Base Enhanced Catalytic Water Oxidation by a Carboxylate- Bipyridine Ru(II) Complex Proc. Natl. Acad. Sci. U. S. A. 2015, 112, 4935-4940 10.1073/pnas.1500245112
263. Chen, Z. F.; Concepcion, J. J.; Hull, J. F.; Hoertz, P. G.; Meyer, T. J. Catalytic water oxidation on derivatized nanoITO Dalton Trans. 2010, 39, 6950-6952 10.1039/c0dt00362j
264. 2Thin Films J. Phys. Chem. B 2010, 114, 14772-14777 10.1021/jp103867j
265. Norris, M. R.; Concepcion, J. J.; Fang, Z.; Templeton, J. L.; Meyer, T. J. Low Overpotential Water Oxidation by a Surface-Bound Ruthenium-Chromophore-Ruthenium-Catalyst Assembly Angew. Chem., Int. Ed. 2013, 52, 13580-13583 10.1002/anie.201305951
266. 2J. Am. Chem. Soc. 2012, 134, 19189-19198 10.1021/ja3084362
267. Ashford, D. L.; Stewart, D. J.; Glasson, C. R.; Binstead, R. A.; Harrison, D. P.; Norris, M. R.; Concepcion, J. J.; Fang, Z.; Templeton, J. L.; Meyer, T. J. An Amide-Linked Chromophore-Catalyst Assembly for Water Oxidation Inorg. Chem. 2012, 51, 6428-6430 10.1021/ic300061u
268. Wang, L.; Ashford, D. L.; Thompson, D. W.; Meyer, T. J.; Papanikolas, J. M. Watching Photoactivation in a Ru(II) Chromophore-Catalyst Assembly on TiO2 by Ultrafast Spectroscopy J. Phys. Chem. C 2013, 117, 24250-24258 10.1021/jp410571x
269. Song, W.; Glasson, C. R. K.; Luo, H.; Hanson, K.; Brennaman, M. K.; Concepcion, J. J.; Meyer, T. J. Photoinduced Stepwise Oxidative Activation of a Chromophore-Catalyst Assembly on TiO2 J. Phys. Chem. Lett. 2011, 2, 1808-1813 10.1021/jz200773r
270. Donovan, B.; Walker, L. A., II; Yocum, C. F.; Sension, R. J. Transient Absorption Studies of the Primary Charge Separation in Photosystem II J. Phys. Chem. 1996, 100, 1945-1949 10.1021/jp951984v
271. Pullerits, T.; Sundstroem, V. Photosynthetic Light-Harvesting Pigment-Protein Complexes: Toward Understanding How and Why Acc. Chem. Res. 1996, 29, 381-389 10.1021/ar950110o
272. Song, W.; Chen, Z.; Brennaman, M. K.; Concepcion, J. J.; Patrocinio, A. O. T.; Iha, N. Y. M.; Meyer, T. J. Making solar fuels by artificial photosynthesis Pure Appl. Chem. 2011, 83, 749-768 10.1351/PAC-CON-10-11-09
273. Li, R.; Liu, J.; Cai, N.; Zhang, M.; Wang, P. Synchronously Reduced Surface States, Charge Recombination, and Light Absorption Length for High-Performance Organic Dye-Sensitized Solar Cells J. Phys. Chem. B 2010, 114, 4461-4464 10.1021/jp101222s
274. Lai, H.; Hong, J.; Liu, P.; Yuan, C.; Li, Y.; Fang, Q. Multi-carbazole derivatives: new dyes for highly efficient dye-sensitized solar cells RSC Adv. 2012, 2, 2427-2432 10.1039/c2ra01002j
275. Kim, M.-J.; Yu, Y.-J.; Kim, J.-H.; Jung, Y.-S.; Kay, K.-Y.; Ko, S.-B.; Lee, C.-R.; Jang, I.-H.; Kwon, Y.-U.; Park, N.-G. Tuning of spacer groups in organic dyes for efficient inhibition of charge recombination in dye-sensitized solar cells Dyes Pigm. 2012, 95, 134-141 10.1016/j.dyepig.2012.04.002
276. Cowan, A. J.; Durrant, J. R. Long-lived charge separated states in nanostructured semiconductor photoelectrodes for the production of solar fuels Chem. Soc. Rev. 2013, 42, 2281-2293 10.1039/C2CS35305A
277. Murakami, T. N.; Koumura, N.; Uchiyama, T.; Uemura, Y.; Obuchi, K.; Masaki, N.; Kimura, M.; Mori, S. Recombination inhibitive structure of organic dyes for cobalt complex redox electrolytes in dye-sensitized solar cells J. Mater. Chem. A 2013, 1, 792-798 10.1039/C2TA00897A
278. Lin, C.; Tsai, F.-Y.; Lee, M.-H.; Lee, C.-H.; Tien, T.-C.; Wang, L.-P.; Tsai, S.-Y. Enhanced performance of dye-sensitized solar cells by an Al2O3 charge-recombination barrier formed by low-temperature atomic layer deposition J. Mater. Chem. 2009, 19, 2999-3003 10.1039/b819337a
279. Hamann, T. W.; Farha, O. K.; Hupp, J. T. Outer-Sphere Redox Couples as Shuttles in Dye-Sensitized Solar Cells. Performance Enhancement Based on Photoelectrode Modification via Atomic Layer Deposition J. Phys. Chem. C 2008, 112, 19756-19764 10.1021/jp807395g
280. Wu, M.; Yang, Z. H.; Jiang, Y. H.; Zhang, J. J.; Liu, S. Q.; Sun, Y. M. Improvement of dye-sensitized solar cell performance through electrodepositing a close-packed TiO2 film J. Solid State Electrochem. 2010, 14, 857-863 10.1007/s10008-009-0866-6
281. Li, X.; Qiu, Y.; Wang, S.; Lu, S.; Gruar, R. I.; Zhang, X.; Darr, J. A.; He, T. Electrophoretically deposited TiO2 compact layers using aqueous suspension for dye-sensitized solar cells Phys. Chem. Chem. Phys. 2013, 15, 14729-14735 10.1039/c3cp51705e
282. Kang, S. H.; Kim, J.-Y.; Kim, Y.; Kim, H. S.; Sung, Y.-E. Surface Modification of Stretched TiO2 Nanotubes for Solid-State Dye-Sensitized Solar Cells J. Phys. Chem. C 2007, 111, 9614-9623 10.1021/jp071504n
283. Song, J.; Yang, H. B.; Wang, X.; Khoo, S. Y.; Wong, C. C.; Liu, X.-W.; Li, C. M. Improved Utilization of Photogenerated Charge Using Fluorine-Doped TiO2 Hollow Spheres Scattering Layer in Dye-Sensitized Solar Cells ACS Appl. Mater. Interfaces 2012, 4, 3712-3717 10.1021/am300801f
284. Yang, H. B.; Guo, C. X.; Guai, G. H.; Song, Q. L.; Jiang, S. P.; Li, C. M. Reduction of Charge Recombination by an Amorphous Titanium Oxide Interlayer in Layered Graphene/Quantum Dots Photochemical Cells ACS Appl. Mater. Interfaces 2011, 3, 1940-1945 10.1021/am200154h
285. Chen, Z.; Kang, P.; Zhang, M.-T.; Meyer, T. J. Making syngas electrocatalytically using a polypyridyl ruthenium catalyst Chem. Commun. 2014, 50, 335-337 10.1039/C3CC47251E
286. Alibabaei, L.; Sherman, B. D.; Norris, M. R.; Brennaman, M. K.; Meyer, T. J. Visible Photoelectrochemical Water Splitting into H2 and O2 in a Dye Sensitized Photoelectrosynthesis Cell Proc. Natl. Acad. Sci. U. S. A. 2015, 112, 5899-5902 10.1073/pnas.1506111112
287. Alibabaei, L.; Farnum, B. H.; Kalanyan, B.; Brennaman, M. K.; Losego, M. D.; Parsons, G. N.; Meyer, T. J. Atomic Layer Deposition of TiO2 on Mesoporous nanoITO: Conductive Core-Shell Photoanodes for Dye-Sensitized Solar Cells Nano Lett. 2014, 14, 3255-3261 10.1021/nl5006433
288. Gao, Y.; Ding, X.; Liu, J.; Wang, L.; Lu, Z.; Li, L.; Sun, L. Visible light driven water splitting in a molecular device with unprecedentedly high photocurrent density J. Am. Chem. Soc. 2013, 135, 4219-4222 10.1021/ja400402d
289. Gao, Y.; Zhang, L.; Ding, X.; Sun, L. Artificial photosynthesis-functional devices for light driven water splitting with photoactive anodes based on molecular catalysts Phys. Chem. Chem. Phys. 2014, 16, 12008-12013 10.1039/c3cp55204g
290. Song, W.; Ito, A.; Binstead, R. A.; Hanson, K.; Luo, H.; Brennaman, M. K.; Concepcion, J. J.; Meyer, T. J. Accumulation of Multiple Oxidative Equivalents at a Single Site by Cross-Surface Electron Transfer on TiO2 J. Am. Chem. Soc. 2013, 135, 11587-11594 10.1021/ja4032538
291. Kaerkaes, M. D.; Johnston, E. V.; Verho, O.; Aakermark, B. Artificial Photosynthesis: From Nanosecond Electron Transfer to Catalytic Water Oxidation Acc. Chem. Res. 2014, 47, 100-111 10.1021/ar400076j
292. Bottari, G.; Trukhina, O.; Ince, M.; Torres, T. Towards artificial photosynthesis: Supramolecular, donor-acceptor, porphyrin- and phthalocyanine/carbon nanostructure ensembles Coord. Chem. Rev. 2012, 256, 2453-2477 10.1016/j.ccr.2012.03.011
293. Murata, K.; Araki, M.; Inagaki, A.; Akita, M. Syntheses, photophysical properties, and reactivities of novel bichromophoric Pd complexes composed of Ru(II)-polypyridyl and naphthyl moieties Dalton Trans. 2013, 42, 6989-7001 10.1039/c3dt50266j
294. Li, F.; Jiang, Y.; Zhang, B.; Huang, F.; Gao, Y.; Sun, L. Towards A Solar Fuel Device: Light-Driven Water Oxidation Catalyzed by a Supramolecular Assembly Angew. Chem., Int. Ed. 2012, 51, 2417-2420 10.1002/anie.201108051
295. Wang, L.; Mirmohades, M.; Brown, A.; Duan, L.; Li, F.; Daniel, Q.; Lomoth, R.; Sun, L.; Hammarström, L. Sensitizer-Catalyst Assemblies for Water Oxidation Inorg. Chem. 2015, 54, 2742-2751 10.1021/ic502915r
296. Herrero, C.; Quaranta, A.; Fallahpour, R.-A.; Leibl, W.; Aukauloo, A. Identification of the Different Mechanisms of Activation of a [RuII(tpy) (bpy) (OH2)]2+ Catalyst by Modified Ruthenium Sensitizers in Supramolecular Complexes J. Phys. Chem. C 2013, 117, 9605-9612 10.1021/jp4025816
297. Dietrich, J.; Thorenz, U.; Foerster, C.; Heinze, K. Effects of Sequence, Connectivity, and Counter Ions in New Amide-Linked Ru(tpy)2-Re(bpy) Chromophores on Redox Chemistry and Photophysics Inorg. Chem. 2013, 52, 1248-1264 10.1021/ic301632y
298. Norris, M. R.; Concepcion, J. J.; Harrison, D. P.; Binstead, R. A.; Ashford, D. L.; Fang, Z.; Templeton, J. L.; Meyer, T. J. Redox Mediator Effect on Water Oxidation in a Ruthenium-Based Chromophore-Catalyst Assembly J. Am. Chem. Soc. 2013, 135, 2080-2083 10.1021/ja311645d
299. Herrero, C.; Batchelor, L.; Baron, A.; El Ghachtouli, S.; Sheth, S.; Guillot, R.; Vauzeilles, B.; Sircoglou, M.; Mallah, T.; Leibl, W. et al. Click Chemistry as a Convenient Tool for the Incorporation of a Ruthenium Chromophore and a Nickel-Salen Monomer into a Visible-Light-Active Assembly Eur. J. Inorg. Chem. 2013, 2013, 494-499 10.1002/ejic.201201161
300. Zhang, P.; Wang, M.; Li, C.; Li, X.; Dong, J.; Sun, L. Photochemical H2 production with noble-metal-free molecular devices comprising a porphyrin photosensitizer and a cobaloxime catalyst Chem. Commun. 2009, 46, 8806-8808 10.1039/c0cc03154b
301. McCormick, T. M.; Han, Z.; Weinberg, D. J.; Brennessel, W. W.; Holland, P. L.; Eisenberg, R. Impact of Ligand Exchange in Hydrogen Production from Cobaloxime-Containing Photocatalytic Systems Inorg. Chem. 2011, 50, 10660-10666 10.1021/ic2010166
302. Vagnini, M. T.; Smeigh, A. L.; Blakemore, J. D.; Eaton, S. W.; Schley, N. D.; DSouza, F.; Crabtree, R. H.; Brudvig, G. W.; Co, D. T.; Wasielewski, M. R. Ultrafast photodriven intramolecular electron transfer from an iridium-based water-oxidation catalyst to perylene diimide derivatives Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 15651-15656 10.1073/pnas.1202075109
303. Bock, C. R.; Connor, J. A.; Gutierrez, A. R.; Meyer, T. J.; Whitten, D. G.; Sullivan, B. P.; Nagle, J. K. Estimation of excited-state redox potentials by electron-transfer quenching. Application of electron-transfer theory to excited-state redox processes J. Am. Chem. Soc. 1979, 101, 4815-4824 10.1021/ja00511a007
304. Bock, C. R.; Meyer, T. J.; Whitten, D. G. Electron transfer quenching of the luminescent excited state of tris(2,2′-bipyridine)ruthenium(II). Flash photolysis relaxation technique for measuring the rates of very rapid electron transfer reactions J. Am. Chem. Soc. 1974, 96, 4710-4712 10.1021/ja00821a078
305. Demas, J. N.; Adamson, A. W. Tris (2,2′-bipyridine)ruthenium(II) sensitized reactions of some oxalato complexes J. Am. Chem. Soc. 1973, 95, 5159-5168 10.1021/ja00797a011
306. Young, R. C.; Meyer, T. J.; Whitten, D. G. Electron transfer quenching of excited states of metal complexes J. Am. Chem. Soc. 1976, 98, 286-287 10.1021/ja00417a073
307. Ellmer, K. Past achievements and future challenges in the development of optically transparent electrodes Nat. Photonics 2012, 6, 809-817 10.1038/nphoton.2012.282
308. Hosono, H.; Ohta, H.; Orita, M.; Ueda, K.; Hirano, M. Frontier of transparent conductive oxide thin films Vacuum 2002, 66, 419-425 10.1016/S0042-207X(02)00165-3
309. van Deelen, J.; Illiberi, A.; Hovestad, A.; Barbu, I.; Klerk, L.; Buskens, P. Transparent conducting materials: overview and recent results Proc. SPIE 2012, 8470 10.1117/12.929685
310. Alibabaei, L.; Luo, H. L.; House, R. L.; Hoertz, P. G.; Lopez, R.; Meyer, T. J. Applications of metal oxide materials in dye sensitized photoelectrosynthesis cells for making solar fuels: let the molecules do the work J. Mater. Chem. A 2013, 1, 4133-4145 10.1039/c2ta00935h
311. Bahr, J. L.; Tour, J. M. Covalent chemistry of single-wall carbon nanotubes J. Mater. Chem. 2002, 12, 1952-1958 10.1039/b201013p
312. Cosnier, S. Biomolecule immobilization on electrode surfaces by entrapment or attachment to electrochemically polymerized films. A review Biosens. Bioelectron. 1999, 14, 443-456 10.1016/S0956-5663(99)00024-X
313. Stein, A.; Wang, Z.; Fierke, M. A. Functionalization of porous carbon materials with designed pore architecture Adv. Mater. 2009, 21, 265-293 10.1002/adma.200801492
314. Krumpfer, J. W.; Gao, L.; Fadeev, A. Y.; McCarthy, T. J. Using surface-attached organosilanes to control and understand hydrophobicity and superhydrophobicity Adv. Silicon Sci. 2012, 4, 95-114 10.1007/978-94-007-3876-8-4
315. Mirkhalaf, F.; Graves, J. E. Nanostructured electrocatalysts immobilised on electrode surfaces and organic film templates Chem. Pap. 2012, 66, 472-483 10.2478/s11696-011-0110-6
316. Vannucci, A. K.; Hull, J. F.; Chen, Z.; Binstead, R. A.; Concepcion, J. J.; Meyer, T. J. Water Oxidation Intermediates Applied to Catalysis: Benzyl Alcohol Oxidation J. Am. Chem. Soc. 2012, 134, 3972-3975 10.1021/ja210718u
317. Trammell, S. A.; Meyer, T. J. Diffusional Mediation of Surface Electron Transfer on TiO2 J. Phys. Chem. B 1999, 103, 104-107 10.1021/jp9825258
318. Langmuir, I. The adsorption of gases on plane surfaces of glass, mica and platinum J. Am. Chem. Soc. 1918, 40, 1361-1402 10.1021/ja02242a004
319. Ashford, D. L.; Brennaman, M. K.; Brown, R. J.; Keinan, S.; Concepcion, J. J.; Papanikolas, J. M.; Templeton, J. L.; Meyer, T. J. Varying the Electronic Structure of Surface-Bound Ruthenium(II) Polypyridyl Complexes Inorg. Chem. 2014, 54, 460-469 10.1021/ic501682k
320. Treadway, J. A.; Moss, J. A.; Meyer, T. J. Visible Region Photooxidation on TiO2 with a Chromophore-Catalyst Molecular Assembly Inorg. Chem. 1999, 38, 4386-4387 10.1021/ic990466m
321. Trammell, S. A.; Moss, J. A.; Yang, J. C.; Nakhle, B. M.; Slate, C. A.; Odobel, F.; Sykora, M.; Erickson, B. W.; Meyer, T. J. Sensitization of TiO2 by Phosphonate-Derivatized Proline Assemblies Inorg. Chem. 1999, 38, 3665-3669 10.1021/ic990052t
322. II-polypyridyl complexes on nanocrystalline metal oxide films Biopolymers 2013, 100, 25-37 10.1002/bip.22152
323. Springer, J. W.; Parkes-Loach, P. S.; Reddy, K. R.; Krayer, M.; Jiao, J.; Lee, G. M.; Niedzwiedzki, D. M.; Harris, M. A.; Kirmaier, C.; Bocian, D. F. et al. Biohybrid Photosynthetic Antenna Complexes for Enhanced Light-Harvesting J. Am. Chem. Soc. 2012, 134, 4589-4599 10.1021/ja207390y
324. Wilger, D. J.; Bettis, S. E.; Materese, C. K.; Minakova, M.; Papoian, G. A.; Papanikolas, J. M.; Waters, M. L. Tunable Energy Transfer Rates via Control of Primary, Secondary, and Tertiary Structure of a Coiled Coil Peptide Scaffold Inorg. Chem. 2012, 51, 11324-11338 10.1021/ic300669t
325. Polo, F.; Antonello, S.; Formaggio, F.; Toniolo, C.; Maran, F. Evidence Against the Hopping Mechanism as an Important Electron Transfer Pathway for Conformationally Constrained Oligopeptides J. Am. Chem. Soc. 2005, 127, 492-493 10.1021/ja043607e
326. Ryan, D. M.; Coggins, M. K.; Concepcion, J. J.; Ashford, D. L.; Fang, Z.; Alibabaei, L.; Ma, D.; Meyer, T. J.; Waters, M. L. Synthesis and Electrocatalytic Water Oxidation by Electrode-Bound Helical Peptide Chromophore-Catalyst Assemblies Inorg. Chem. 2014, 53, 8120-8128 10.1021/ic5011488
327. Ma, D.; Bettis, S. E.; Hanson, K.; Minakova, M.; Alibabaei, L.; Fondrie, W.; Ryan, D. M.; Papoian, G. A.; Meyer, T. J.; Waters, M. L. et al. Interfacial Energy Conversion in RuII Polypyridyl-Derivatized Oligoproline Assemblies on TiO2 J. Am. Chem. Soc. 2013, 135, 5250-5253 10.1021/ja312143h
328. Hanson, K.; Torelli, D. A.; Vannucci, A. K.; Brennaman, M. K.; Luo, H.; Alibabaei, L.; Song, W.; Ashford, D. L.; Norris, M. R.; Glasson, C. R. K. et al. Self-assembled Bilayer Films of Ru(II) Polypyridyl Complexes by Layer-by-Layer Deposition on Nanostructured Metal Oxides Angew. Chem., Int. Ed. 2012, 51, 12782-12785 10.1002/anie.201206882
329. Ding, X.; Gao, Y.; Zhang, L.; Yu, Z.; Liu, J.; Sun, L. Visible Light-Driven Water Splitting in Photoelectrochemical Cells with Supramolecular Catalysts on Photoanodes ACS Catal. 2014, 4, 2347-2350 10.1021/cs500518k
330. Glasson, C. R. K.; Song, W.; Ashford, D. L.; Vannucci, A.; Chen, Z.; Concepcion, J. J.; Holland, P. L.; Meyer, T. J. Self-Assembled Bilayers on Indium-Tin Oxide (SAB-ITO) Electrodes: A Design for Chromophore-Catalyst Photoanodes Inorg. Chem. 2012, 51, 8637-8639 10.1021/ic300636w
331. Xiang, X.; Fielden, J.; Rodriguez-Cordoba, W.; Huang, Z.; Zhang, N.; Luo, Z.; Musaev, D. G.; Lian, T.; Hill, C. L. Electron Transfer Dynamics in Semiconductor-Chromophore-Polyoxometalate Catalyst Photoanodes J. Phys. Chem. C 2013, 117, 918-926 10.1021/jp312092u
332. Brimblecombe, R.; Koo, A.; Dismukes, G. C.; Swiegers, G. F.; Spiccia, L. Solar-driven Water Oxidation by a Bio-inspired Manganese Molecular Catalyst J. Am. Chem. Soc. 2010, 132, 2892-2894 10.1021/ja910055a
333. Li, L.; Duan, L.; Xu, Y.; Gorlov, M.; Hagfeldt, A.; Sun, L. A photoelectrochemical device for visible light driven water splitting by a molecular ruthenium catalyst assembled on dye-sensitized nanostructured TiO2 Chem. Commun. 2010, 46, 7307-7309 10.1039/c0cc01828g
334. Moore, G. F.; Blakemore, J. D.; Milot, R. L.; Hull, J. F.; Song, H.-e.; Cai, L.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W. A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst Energy Environ. Sci. 2011, 4, 2389-2392 10.1039/c1ee01037a
335. Youngblood, W. J.; Lee, S.-H. A.; Kobayashi, Y.; Hernandez-Pagan, E. A.; Hoertz, P. G.; Moore, T. A.; Moore, A. L.; Gust, D.; Mallouk, T. E. Photoassisted Overall Water Splitting in a Visible Light-Absorbing Dye-Sensitized Photoelectrochemical Cell J. Am. Chem. Soc. 2009, 131, 926-927 10.1021/ja809108y
336. Lee, S.-H. A.; Zhao, Y.; Hernandez-Pagan, E. A.; Blasdel, L.; Youngblood, W. J.; Mallouk, T. E. Electron transfer kinetics in water splitting dye-sensitized solar cells based on core-shell oxide electrodes Faraday Discuss. 2012, 155, 165-176 10.1039/C1FD00083G
337. Gambardella, A. A.; Bjorge, N. S.; Alspaugh, V. K.; Murray, R. W. Voltammetry of Diffusing 2 nm Iridium Oxide Nanoparticles J. Phys. Chem. C 2011, 115, 21659-21665 10.1021/jp206987z
338. Gambardella, A. A.; Feldberg, S. W.; Murray, R. W. Electron Transfer Dynamics of Iridium Oxide Nanoparticles Attached to Electrodes by Self-Assembled Monolayers J. Am. Chem. Soc. 2012, 134, 5774-5777 10.1021/ja301212r
339. Nakagawa, T.; Bjorge, N. S.; Murray, R. W. Electrogenerated IrOx Nanoparticles as Dissolved Redox Catalysts for Water Oxidation J. Am. Chem. Soc. 2009, 131, 15578-15579 10.1021/ja9063298
340. Crabtree, R. H. Resolving Heterogeneity Problems and Impurity Artifacts in Operationally Homogeneous Transition Metal Catalysts Chem. Rev. 2012, 112, 1536-1554 10.1021/cr2002905
341. Cape, J. L.; Hurst, J. K. Detection and Mechanistic Relevance of Transient Ligand Radicals Formed during [Ru(bpy)2(OH2)]2O4+-Catalyzed Water Oxidation J. Am. Chem. Soc. 2008, 130, 827-829 10.1021/ja077276s
342. Heimer, T. A.; Heilweil, E. J.; Bignozzi, C. A.; Meyer, G. J. Electron Injection, Recombination, and Halide Oxidation Dynamics at Dye-Sensitized Metal Oxide Interfaces J. Phys. Chem. A 2000, 104, 4256-4262 10.1021/jp993438y
343. ODonnell, R. M.; Ardo, S.; Meyer, G. J. Charge-Screening Kinetics at Sensitized TiO2 Interfaces J. Phys. Chem. Lett. 2013, 4, 2817-2821 10.1021/jz4014689
344. Hilgendorff, M.; Sundstroem, V. Dynamics of Electron Injection and Recombination of Dye-Sensitized TiO2 Particles J. Phys. Chem. B 1998, 102, 10505-10514 10.1021/jp982210s
345. Miller, S. A.; West, B. A.; Curtis, A. C.; Papanikolas, J. M.; Moran, A. M. Communication: Uncovering molecule-TiO2 interactions with nonlinear spectroscopy J. Chem. Phys. 2011, 135, 081101-081104 10.1063/1.3631339
346. Morandeira, A.; Lopez-Duarte, I.; Martinez-Diaz, M. V.; ORegan, B.; Shuttle, C.; Haji-Zainulabidin, N. A.; Torres, T.; Palomares, E.; Durrant, J. R. Slow electron injection on Ru-phthalocyanine sensitized TiO2 J. Am. Chem. Soc. 2007, 129, 9250-9251 10.1021/ja0722980
347. Asbury, J. B.; Hao, E.; Wang, Y.; Ghosh, H. N.; Lian, T. Ultrafast Electron Transfer Dynamics from Molecular Adsorbates to Semiconductor Nanocrystalline Thin Films J. Phys. Chem. B 2001, 105, 4545-4557 10.1021/jp003485m
348. Verma, S.; Kar, P.; Das, A.; Palit, D. K.; Ghosh, H. N. The Effect of Heavy Atoms on Photoinduced Electron Injection from Nonthermalized and Thermalized Donor States of MII-Polypyridyl (M = Ru/Os) Complexes to Nanoparticulate TiO2 Surfaces: An Ultrafast Time-Resolved Absorption Study Chem.-Eur. J. 2010, 16, 611-619 10.1002/chem.200901937
349. Benkoe, G.; Kallioinen, J.; Myllyperkioe, P.; Trif, F.; Korppi-Tommola, J. E. I.; Yartsev, A. P.; Sundstroem, V. Interligand Electron Transfer Determines Triplet Excited State Electron Injection in RuN3-Sensitized TiO2 Films J. Phys. Chem. B 2004, 108, 2862-2867 10.1021/jp036778z
350. Hasselmann, G. M.; Meyer, G. J. Diffusion-Limited Interfacial Electron Transfer with Large Apparent Driving Forces J. Phys. Chem. B 1999, 103, 7671-7675 10.1021/jp992086s
351. Liu, F.; Meyer, G. J. Remote and Adjacent Excited-State Electron Transfer at TiO2 Interfaces Sensitized to Visible Light with Ru(II) Compounds Inorg. Chem. 2005, 44, 9305-9313 10.1021/ic0513336
352. She, C.; Guo, J.; Irle, S.; Morokuma, K.; Mohler, D. L.; Zabri, H.; Odobel, F.; Youm, K.-T.; Liu, F.; Hupp, J. T. et al. Comparison of Interfacial Electron Transfer through Carboxylate and Phosphonate Anchoring Groups J. Phys. Chem. A 2007, 111, 6832-6842 10.1021/jp0709003
353. Gillaizeau-Gauthier, I.; Odobel, F.; Alebbi, M.; Argazzi, R.; Costa, E.; Bignozzi, C. A.; Qu, P.; Meyer, G. J. Phosphonate-based bipyridine dyes for stable photovoltaic devices Inorg. Chem. 2001, 40, 6073-6079 10.1021/ic010192e
354. Durrant, J. R.; Haque, S. A.; Palomares, E. Towards optimization of electron transfer processes in dye sensitised solar cells Coord. Chem. Rev. 2004, 248, 1247-1257 10.1016/j.ccr.2004.03.014
355. Dang, X.; Hupp, J. T. Interfacial Charge-Transfer Pathways: Evidence for Marcus-Type Inverted Electron Transfer in Metal Oxide Semiconductor/Inorganic Dye Systems J. Am. Chem. Soc. 1999, 121, 8399-8400 10.1021/ja990709+
356. Boschloo, G.; Hagfeldt, A. Activation Energy of Electron Transport in Dye-Sensitized TiO2 Solar Cells J. Phys. Chem. B 2005, 109, 12093-12098 10.1021/jp0513770
357. Frank, A. J.; Kopidakis, N.; van de Lagemaat, J. Electrons in nanostructured TiO2 solar cells: transport, recombination and photovoltaic properties Coord. Chem. Rev. 2004, 248, 1165-1179 10.1016/j.ccr.2004.03.015
358. Haque, S. A.; Palomares, E.; Cho, B. M.; Green, A. N. M.; Hirata, N.; Klug, D. R.; Durrant, J. R. Charge Separation versus Recombination in Dye-Sensitized Nanocrystalline Solar Cells: the Minimization of Kinetic Redundancy J. Am. Chem. Soc. 2005, 127, 3456-3462 10.1021/ja0460357
359. McNeil, I.; Ashford, D. L.; Glasson, C. R. K.; Luo, H.; Fecko, C. J. Power-law kinetics in the photoluminescence of dye-sensitized nanoparticle films: Implications for electron injection and charge transport J. Phys. Chem. C 2012, 116, 15888-15899 10.1021/jp3030717
360. McNeil, I. J.; Alibabaei, L.; Ashford, D. L.; Fecko, C. J. Investigation of Factors That Affect Excited State Lifetime Distribution of Dye-Sensitized Nanoparticle Films J. Phys. Chem. C 2013, 117, 17412-17420 10.1021/jp404876k
361. De Angelis, F.; Fantacci, S.; Mosconi, E.; Nazeeruddin, M. K.; Gratzel, M. Absorption Spectra and Excited State Energy Levels of the N719 Dye on TiO2 in Dye-Sensitized Solar Cell Models J. Phys. Chem. C 2011, 115, 8825-8831 10.1021/jp111949a
362. Wenger, B.; Graetzel, M.; Moser, J.-E. Rationale for Kinetic Heterogeneity of Ultrafast Light-Induced Electron Transfer from Ru(II) Complex Sensitizers to Nanocrystalline TiO2 J. Am. Chem. Soc. 2005, 127, 12150-12151 10.1021/ja042141x
363. Antila, L. J.; Myllyperkio, P.; Mustalahti, S.; Lehtivuori, H.; Korppi-Tommola, J. Injection and ultrafast regeneration in dye-sensitized solar cells J. Phys. Chem. C 2014, 118, 7772-7780 10.1021/jp4124277
364. Halme, J.; Boschloo, G.; Hagfeldt, A.; Lund, P. Spectral Characteristics of Light Harvesting, Electron Injection, and Steady-State Charge Collection in Pressed TiO2 Dye Solar Cells J. Phys. Chem. C 2008, 112, 5623-5637 10.1021/jp711245f
365. Bettis, S. E.; Hanson, K.; Wang, L.; Gish, M. K.; Concepcion, J. J.; Fang, Z.; Meyer, T. J.; Papanikolas, J. M. Photophysical Characterization of a Chromophore/Water Oxidation Catalyst Containing a Layer-by-Layer Assembly on Nanocrystalline TiO2 Using Ultrafast Spectroscopy J. Phys. Chem. A 2014, 118, 10301-10308 10.1021/jp411139j
366. Milot, R. L.; Moore, G. F.; Crabtree, R. H.; Brudvig, G. W.; Schmuttenmaer, C. A. Electron Injection Dynamics from Photoexcited Porphyrin Dyes into SnO2 and TiO2 Nanoparticles J. Phys. Chem. C 2013, 117, 21662-21670 10.1021/jp406734t
367. Koops, S. E.; Barnes, P. R. F.; ORegan, B. C.; Durrant, J. R. Kinetic Competition in a Coumarin Dye-Sensitized Solar Cell: Injection and Recombination Limitations upon Device Performance J. Phys. Chem. C 2010, 114, 8054-8061 10.1021/jp910972x
368. Wiberg, J.; Marinado, T.; Hagberg, D. P.; Sun, L.; Hagfeldt, A.; Albinsson, B. Effect of Anchoring Group on Electron Injection and Recombination Dynamics in Organic Dye-Sensitized Solar Cells J. Phys. Chem. C 2009, 113, 3881-3886 10.1021/jp8101139
369. Chang, C.-W.; Luo, L.; Chou, C.-K.; Lo, C.-F.; Lin, C.-Y.; Hung, C.-S.; Lee, Y.-P.; Diau, E. W.-G. Femtosecond Transient Absorption of Zinc Porphyrins with Oligo(phenylethylnyl) Linkers in Solution and on TiO2 Films J. Phys. Chem. C 2009, 113, 11524-11531 10.1021/jp810580u
370. Dos Santos, T.; Morandeira, A.; Koops, S.; Mozer, A. J.; Tsekouras, G.; Dong, Y.; Wagner, P.; Wallace, G.; Earles, J. C.; Gordon, K. C. et al. Injection Limitations in a Series of Porphyrin Dye-Sensitized Solar Cells J. Phys. Chem. C 2010, 114, 3276-3279 10.1021/jp908401k
371. Myahkostupov, M.; Piotrowiak, P.; Wang, D.; Galoppini, E. Ru(II)-Bpy Complexes Bound to Nanocrystalline TiO2 Films through Phenyleneethynylene (OPE) Linkers: Effect of the Linkers Length on Electron Injection Rates J. Phys. Chem. C 2007, 111, 2827-2829 10.1021/jp0679257
372. Fessenden, R. W.; Kamat, P. V. Rate Constants for Charge Injection from Excited Sensitizer into SnO2, ZnO, and TiO2 Semiconductor Nanocrystallites J. Phys. Chem. 1995, 99, 12902-12906 10.1021/j100034a032
373. Kuciauskas, D.; Monat, J. E.; Villahermosa, R.; Gray, H. B.; Lewis, N. S.; McCusker, J. K. Transient Absorption Spectroscopy of Ruthenium and Osmium Polypyridyl Complexes Adsorbed onto Nanocrystalline TiO2 Photoelectrodes J. Phys. Chem. B 2002, 106, 9347-9358 10.1021/jp014589f
374. Benkoe, G.; Kallioinen, J.; Korppi-Tommola, J. E. I.; Yartsev, A. P.; Sundstroem, V. Photoinduced ultrafast dye-to-semiconductor electron injection from nonthermalized and thermalized donor states J. Am. Chem. Soc. 2002, 124, 489-493 10.1021/ja016561n
375. Asbury, J. B.; Anderson, N. A.; Hao, E.; Ai, X.; Lian, T. Parameters affecting electron injection dynamics from ruthenium dyes to titanium dioxide nanocrystalline thin film J. Phys. Chem. B 2003, 107, 7376-7386 10.1021/jp034148r
376. Myahkostupov, M.; Piotrowiak, P.; Wang, D.; Galoppini, E. Ru(II)-Bpy Complexes Bound to Nanocrystalline TiO2 Films through Phenyleneethynylene (OPE) Linkers: Effect of the Linkers Length on Electron Injection Rates J. Phys. Chem. C 2007, 111, 2827-2829 10.1021/jp0679257
377. Damrauer, N. H.; Boussie, T. R.; Devenney, M.; McCusker, J. K. Effects of Intraligand Electron Delocalization, Steric Tuning, and Excited-State Vibronic Coupling on the Photophysics of Aryl-Substituted Bipyridyl Complexes of Ru(II) J. Am. Chem. Soc. 1997, 119, 8253-8268 10.1021/ja971321m
378. Damrauer, N. H.; McCusker, J. K. Ultrafast Dynamics in the Metal-to-Ligand Charge Transfer Excited-State Evolution of [Ru(4,4′-diphenyl-2,2′-bipyridine)3]2+ J. Phys. Chem. A 1999, 103, 8440-8446 10.1021/jp9927754
379. Bettis, S. E.; Ryan, D. M.; Gish, M. K.; Alibabaei, L.; Meyer, T. J.; Waters, M. L.; Papanikolas, J. M. Photophysical Characterization of a Helical Peptide Chromophore-Water Oxidation Catalyst Assembly on a Semiconductor Surface Using Ultrafast Spectroscopy J. Phys. Chem. C 2014, 118, 6029-6037 10.1021/jp410646u
380. Nelson, J.; Haque, S. A.; Klug, D. R.; Durrant, J. R. Trap-limited recombination in dye-sensitized nanocrystalline metal oxide electrodes Phys. Rev. B: Condens. Matter Mater. Phys. 2001, 63, 205321-205329 10.1103/PhysRevB.63.205321
381. Nelson, J.; Chandler, R. E. Random walk models of charge transfer and transport in dye sensitized systems Coord. Chem. Rev. 2004, 248, 1181-1194 10.1016/j.ccr.2004.04.001
382. Clifford, J. N.; Palomares, E.; Nazeeruddin, M. K.; Graetzel, M.; Nelson, J.; Li, X.; Long, N. J.; Durrant, J. R. Molecular Control of Recombination Dynamics in Dye-Sensitized Nanocrystalline TiO2 Films: Free Energy vs Distance Dependence J. Am. Chem. Soc. 2004, 126, 5225-5233 10.1021/ja039924n
383. Bisquert, J. Hopping Transport of Electrons in Dye-Sensitized Solar Cells J. Phys. Chem. C 2007, 111, 17163-17168 10.1021/jp077419x
384. Barzykin, A. V.; Tachiya, M. Mechanism of Charge Recombination in Dye-Sensitized Nanocrystalline Semiconductors: Random Flight Model J. Phys. Chem. B 2002, 106, 4356-4363 10.1021/jp012957+
385. Bisquert, J.; Zaban, A.; Salvador, P. Analysis of the Mechanisms of Electron Recombination in Nanoporous TiO2 Dye-Sensitized Solar Cells. Nonequilibrium Steady-State Statistics and Interfacial Electron Transfer via Surface States J. Phys. Chem. B 2002, 106, 8774-8782 10.1021/jp026058c
386. Hu, K.; Robson, K. C. D.; Beauvilliers, E. E.; Schott, E.; Zarate, X.; Arratia-Perez, R.; Berlinguette, C. P.; Meyer, G. J. Intramolecular and Lateral Intermolecular Hole Transfer at the Sensitized TiO2 Interface J. Am. Chem. Soc. 2014, 136, 1034-1046 10.1021/ja410647c
387. Williams, G.; Watts, D. C. Non-symmetrical dielectric relaxation behavior arising from a simple empirical decay function Trans. Faraday Soc. 1970, 66, 80-85 10.1039/tf9706600080
388. Adelt, M.; Devenney, M.; Meyer, T. J.; Thompson, D. W.; Treadway, J. A. Ruthenium(II) MLCT Excited States. Stabilization toward Ligand Loss in Rigid Media Inorg. Chem. 1998, 37, 2616-2617 10.1021/ic971121b
389. Thompson, D. W.; Fleming, C. N.; Myron, B. D.; Meyer, T. J. Rigid medium stabilization of metal-to-ligand charge transfer excited states J. Phys. Chem. B 2007, 111, 6930-6941 10.1021/jp068682l
390. Haque, S. A.; Tachibana, Y.; Klug, D. R.; Durrant, J. R. Charge Recombination Kinetics in Dye-Sensitized Nanocrystalline Titanium Dioxide Films under Externally Applied Bias J. Phys. Chem. B 1998, 102, 1745-1749 10.1021/jp973335k
391. Haque, S. A.; Tachibana, Y.; Willis, R. L.; Moser, J. E.; Graetzel, M.; Klug, D. R.; Durrant, J. R. Parameters Influencing Charge Recombination Kinetics in Dye-Sensitized Nanocrystalline Titanium Dioxide Films J. Phys. Chem. B 2000, 104, 538-547 10.1021/jp991085x
392. Gust, D.; Moore, T. A.; Moore, A. L. Mimicking Photosynthetic Solar Energy Transduction Acc. Chem. Res. 2001, 34, 40-48 10.1021/ar9801301
393. Arakawa, H.; Aresta, M.; Armor, J. N.; Barteau, M. A.; Beckman, E. J.; Bell, A. T.; Bercaw, J. E.; Creutz, C.; Dinjus, E.; Dixon, D. A. et al. Catalysis research of relevance to carbon management: progress, challenges, and opportunities Chem. Rev. 2001, 101, 953-996 10.1021/cr000018s
394. Balzani, V.; Credi, A.; Raymo, F. M.; Stoddart, J. F. Artificial molecular machines Angew. Chem., Int. Ed. 2000, 39, 3348-3391 10.1002/1521-3773(20001002)39:193348::AID-ANIE33483.0.CO;2-X
395. Anderson, S.; Constable, E. C.; Dare-Edwards, M. P.; Goodenough, J. B.; Hamnett, A.; Seddon, K. R.; Wright, R. D. Chemical modification of a titanium(IV) oxide electrode to give stable dye sensitization without a supersensitizer Nature 1979, 280, 571-573 10.1038/280571a0
396. Memming, R.; Schroeppel, F. Electron transfer reactions of excited ruthenium(II) complexes in monolayer assemblies at the tin dioxide-water interface Chem. Phys. Lett. 1979, 62, 207-210 10.1016/0009-2614(79)80160-8
397. Memming, R.; Schroeppel, F.; Bringmann, U. Sensitized oxidation of water by tris(2,2′-bipyridyl) ruthenium at stannic oxide electrodes J. Electroanal. Chem. Interfacial Electrochem. 1979, 100, 307-318 10.1016/S0022-0728(79)80170-9
398. Gillaizeau-Gauthier, I.; Odobel, F.; Alebbi, M.; Argazzi, R.; Costa, E.; Bignozzi, C. A.; Qu, P.; Meyer, G. J. Phosphonate-based bipyridine dyes for stable photovoltaic devices Inorg. Chem. 2001, 40, 6073-6079 10.1021/ic010192e
399. Kim, D. H.; Losego, M. D.; Hanson, K.; Alibabaei, L.; Lee, K.; Meyer, T. J.; Parsons, G. N. Stabilizing Chromophore Binding on TiO2 for Long-Term Stability of Dye-Sensitized Solar Cells Using Multicomponent Atomic Layer Deposition Phys. Chem. Chem. Phys. 2014, 16, 8615-8622 10.1039/C4CP01130A
400. ONeill, B. J.; Jackson, D. H. K.; Lee, J.; Canlas, C.; Stair, P. C.; Marshall, C. L.; Elam, J. W.; Kuech, T. F.; Dumesic, J. A.; Huber, G. W. Catalyst Design with Atomic Layer Deposition ACS Catal. 2015, 5, 1804-1825 10.1021/cs501862h
401. Moss, J. A.; Yang, J. C.; Stipkala, J. M.; Wen, X.; Bignozzi, C. A.; Meyer, G. J.; Meyer, T. J. Sensitization and Stabilization of TiO2 Photoanodes with Electropolymerized Overlayer Films of Ruthenium and Zinc Polypyridyl Complexes: A Stable Aqueous Photoelectrochemical Cell Inorg. Chem. 2004, 43, 1784-1792 10.1021/ic030081a
402. Szpakolski, K.; Latham, K.; Rix, C.; Rani, R. A.; Kalantar-zadeh, K. Silane: A new linker for chromophores in dye-sensitised solar cells Polyhedron 2013, 52, 719-732 10.1016/j.poly.2012.07.078
403. McNamara, W. R.; Snoeberger, R. C., III; Li, G.; Richter, C.; Allen, L. J.; Milot, R. L.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W.; Batista, V. S. Hydroxamate anchors for water-stable attachment to TiO2 nanoparticles Energy Environ. Sci. 2009, 2, 1173-1175 10.1039/b910241h
404. Zakeeruddin, S. M.; Nazeeruddin, M. K.; Humphry-Baker, R.; Péchy, P.; Quagliotto, P.; Barolo, C.; Viscardi, G.; Grätzel, M. Design, Synthesis, and Application of Amphiphilic Ruthenium Polypyridyl Photosensitizers in Solar Cells Based on Nanocrystalline TiO2 Films Langmuir 2002, 18, 952-954 10.1021/la0110848
405. Tamaki, Y.; Vannucci, A. K.; Dares, C. J.; Binstead, R. A.; Meyer, T. J. One-Electron Activation of Water Oxidation Catalysis J. Am. Chem. Soc. 2014, 136, 6854-6857 10.1021/ja502637s
406. Hyde, J. T.; Hanson, K.; Vannucci, A. K.; Lapides, A. M.; Alibabaei, L.; Norris, M. R.; Meyer, T. J.; Harrison, D. P. Electrochemical Instability of Phosphonate-Derivatized, RuIII Polypyridyl Complexes on Metal Oxide Surfaces ACS Appl. Mater. Interfaces 2015, 7, 9554-9562 10.1021/acsami.5b01000
407. Limburg, B.; Bouwman, E.; Bonnet, S. Molecular water oxidation catalysts based on transition metals and their decomposition pathways Coord. Chem. Rev. 2012, 256, 1451-1467 10.1016/j.ccr.2012.02.021
408. Roecker, L.; Kutner, W.; Gilbert, J. A.; Simmons, M.; Murray, R. W.; Meyer, T. J. Instability of the oxidation catalysts ([(bpy)2(py)Ru(O)]2+) and oxo(1,10-phenanthroline)(2,2′,2"-terpyridine) ruthenium(2+) ([(trpy) (phen)Ru(O)]2+) in basic solution Inorg. Chem. 1985, 24, 3784-3791 10.1021/ic00217a018
409. Zouni, A.; Witt, H.-T.; Kern, J.; Fromme, P.; Krauss, N.; Saenger, W.; Orth, P. Crystal structure of photosystem II from Synechococcus elongatus at 3.8 [angst] resolution Nature 2001, 409, 739-743 10.1038/35055589
410. Peek, B. M.; Ross, G. T.; Edwards, S. W.; Meyer, G. J.; Meyer, T. J.; Erickson, B. W. Synthesis of redox derivatives of lysine and related peptides containing phenothiazine of tris(2,2′-bipyridine)ruthenium(II) Int. J. Pept. Protein Res. 1991, 38, 114-123 10.1111/j.1399-3011.1991.tb01418.x
411. Serron, S. A.; Aldridge, W. S., III; Fleming, C. N.; Danell, R. M.; Baik, M.-H.; Sykora, M.; Dattelbaum, D. M.; Meyer, T. J. Evidence for Through-Space Electron Transfer in the Distance Dependence of Normal and Inverted Electron Transfer in Oligoproline Arrays J. Am. Chem. Soc. 2004, 126, 14506-14514 10.1021/ja030659f
412. 2+Loadings for Efficient Heterogeneous Photocatalysis ACS Catal. 2012, 2, 417-424 10.1021/cs300027n
413. Sun, Y. L.; Chen, Z.; Puodziukynaite, E.; Jenkins, D. M.; Reynolds, J. R.; Schanze, K. S. Light Harvesting Arrays of Polypyridine Ruthenium(II) Chromophores Prepared by Reversible Addition-Fragmentation Chain Transfer Polymerization Macromolecules 2012, 45, 2632-2642 10.1021/ma202804u
414. Qiu, D.; Zhao, Q.; Bao, X.; Liu, K.; Wang, H.; Guo, Y.; Zhang, L.; Zeng, J.; Wang, H. Electropolymerization and characterization of an alternatively conjugated donor-acceptor metallopolymer: Poly-[Ru(4′-(4-(Diphenylamino)phenyl)-2,2′:6′,2"-Terpyridine)2]2+ Inorg. Chem. Commun. 2011, 14, 296-299 10.1016/j.inoche.2010.11.019
415. Fang, Z.; Keinan, S.; Alibabaei, L.; Luo, H.; Ito, A.; Meyer, T. J. Controlled Electropolymerization of Ruthenium(II) Vinylbipyridyl Complexes in Mesoporous Nanoparticle Films of TiO2 Angew. Chem., Int. Ed. 2014, 53, 4872-4876 10.1002/anie.201402309
416. Nakagawa, T.; Beasley, C. A.; Murray, R. W. Efficient Electro-Oxidation of Water near Its Reversible Potential by a Mesoporous IrOx Nanoparticle Film J. Phys. Chem. C 2009, 113, 12958-12961 10.1021/jp9060076
417. Concepcion, J. J.; Binstead, R. A.; Alibabaei, L.; Meyer, T. J. Application of the Rotating Ring-Disc-Electrode Technique to Water Oxidation by Surface-Bound Molecular Catalysts Inorg. Chem. 2013, 52, 10744-10746 10.1021/ic402240t
418. 2in a Dye-Sensitized Photoelectrosynthesis Cell: Factors Influencing Efficiency and Dynamics J. Phys. Chem. C 2011, 115, 7081-7091 10.1021/jp200124k
419. Song, W.; Vannucci, A. K.; Farnum, B. H.; Lapides, A. M.; Brennaman, M. K.; Kalanyan, B.; Alibabaei, L.; Concepcion, J. J.; Losego, M. D.; Parsons, G. N. et al. Visible Light Driven Benzyl Alcohol Dehydrogenation in a Dye-Sensitized Photoelectrosynthesis Cell J. Am. Chem. Soc. 2014, 136, 9773-9779 10.1021/ja505022f
420. Hocking, R. K.; Brimblecombe, R.; Chang, L.-Y.; Singh, A.; Cheah, M. H.; Glover, C.; Casey, W. H.; Spiccia, L. Water-oxidation catalysis by manganese in a geochemical-like cycle Nat. Chem. 2011, 3, 461-466 10.1038/nchem.1049
421. Chen, Z. F.; Vannucci, A. K.; Concepcion, J. J.; Jurss, J. W.; Meyer, T. J. Proton-coupled electron transfer at modified electrodes by multiple pathways Proc. Natl. Acad. Sci. U. S. A. 2011, 108, E1461-E1469 10.1073/pnas.1115769108
422. Lang, Z.-L.; Yang, G.-C.; Ma, N.-N.; Wen, S.-Z.; Yan, L.-K.; Guan, W.; Su, Z.-M. DFT characterization on the mechanism of water splitting catalyzed by single-Ru-substituted polyoxometalates Dalton Trans. 2013, 42, 10617-10625 10.1039/c3dt50666e
423. Michaux, K. E.; Gambardella, A. A.; Alibabaei, L.; Ashford, D. L.; Sherman, B. D.; Binstead, R. A.; Meyer, T. J.; Murray, R. W. Visible Photoelectrochemical Water Splitting Based on a Ru(II) Polypyridyl Chromophore and Iridium Oxide Nanoparticle Catalyst J. Phys. Chem. C 2015, 119, 17023-17027 10.1021/acs.jpcc.5b05711