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Volumn 44, Issue 6, 2005, Pages 1713-1727

Synthetic control of excited-state properties in cyclometalated Ir(III) complexes using ancillary ligands

Author keywords

[No Author keywords available]

Indexed keywords

CHELATE; IRIDIUM BIS(2' 4 TOLYLPYRIDINATO N,C 2' )(ETA 2 HYDROTRISPYRAZOLYLMETHANE)TRIFLUOROMETHYLSULFONATE; IRIDIUM BIS(2' 4 TOLYLPYRIDINATO N,C 2' )[BIS(DIPHENYLPHOSPHINO)ETHANE]TRIFLUOROMETHYLSULFONATE; IRIDIUM BIS(2' 4 TOLYLPYRIDINATO N,C 2' )[BIS(DIPHENYLPHOSPHINOMETHYLENE)DIPHENYLSILANE]TRIFLUOROMETHYLSULFONATE; IRIDIUM BIS(2' 4 TOLYLPYRIDINATO N,C 2' )BIS(DIPHENYLPHOSPHINOMETHYLENE)DIPHENYLBORATE; IRIDIUM BIS(2' 4 TOLYLPYRIDINATO N,C 2' )BIS(TERT BUTYL ISOCYANIDE)TRIFLUOROMETHYLSULFONATE; IRIDIUM BIS(2' 4 TOLYLPYRIDINATO N,C 2' )ETA HYDROTRISTRIAZOLYLBORATE; IRIDIUM BIS(4',6' DIFLUOROPHENYLPYRIDINATO N,C 2' )BIS(DIPHENYLPHOSPHINOMETHYLENE)DIPHENYLBORATEC; IRIDIUM BIS(4',6' DIFLUOROPHENYLPYRIDINATO N,C 2' )BIS(TERT BUTYL ISOCYANIDE)TRIFLUOROMETHYLSULFATE; IRIDIUM COMPLEX; LIGAND; UNCLASSIFIED DRUG;

EID: 15944408328     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic048599h     Document Type: Article
Times cited : (680)

References (119)
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    • Bruker Analytical X-ray System, Inc.: Madison, WI
    • Sheldrick, G. M. SHELXTL, version 5.1; Bruker Analytical X-ray System, Inc.: Madison, WI, 1997.
    • (1997) SHELXTL, Version 5.1
    • Sheldrick, G.M.1
  • 74
    • 15944396643 scopus 로고    scopus 로고
    • note
    • The singlet state energy is estimated from the difference between the calculated HOMO and LUMO energies.
  • 75
    • 15944377489 scopus 로고    scopus 로고
    • note
    • 2 solvent (used in ref 18).
  • 83
    • 15944414830 scopus 로고    scopus 로고
    • note
    • nr = (1 -Φ)/τ were used to calculate the rates of radiative and nonradiative decay, where Φ is the quantum efficiency and τ is the luminescence lifetime of the sample at room temperature.
  • 99
    • 15944380976 scopus 로고    scopus 로고
    • note
    • nr).
  • 100
    • 15944373620 scopus 로고    scopus 로고
    • note
    • 3CN) are comparable to the reported data in ref 18. However, the quantum efficiencies we measure for these Ir complexes are significantly lower than the reference data.
  • 102
    • 0004344770 scopus 로고
    • University Science Books: Mill Valley, CA
    • Turro, N. J. Modern Molecular Photochemistry; University Science Books: Mill Valley, CA, 1978; pp 86-88.
    • (1978) Modern Molecular Photochemistry , pp. 86-88
    • Turro, N.J.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.