Detection and mechanistic relevance of transient ligand radicals formed during [Ru(bpy)2(OH2)]2O4+-catalyzed water oxidation

Journal of the American Chemical Society

Volumn 130, Issue 3, 2008, Pages 827-829

  Cape, Jonathan L ^a   Hurst, James K ^a  

^a WASHINGTON STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

2,2' BIPYRIDINE; IMINE; LIGAND; METAL COMPLEX; OXYGEN; RADICAL; RUTHENIUM DERIVATIVE; SOLVENT; WATER;

ABSORPTION SPECTROSCOPY; ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; ILLUMINATION; OXIDATION; OXIDATION REDUCTION REACTION; RAMAN SPECTROMETRY; REACTION ANALYSIS;

EID: 38349130255     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja077276s     Document Type: Article

References (22)

1. (a) Liu, F.; Concepcion, J. J.; Cardolaccia, T.; Jurss, J. W.; Meyer, T. J. Inorg. Chem. 2007, 46, in press.
2. (b) Hurst, J. K.; Cape, J. L.; Clark, A. E.; Das, S.; Qin, C. Inorg. Chem. 2007, 46, in press.
3. (c) Hurst, J. K. Coord. Chem. Rev. 2005, 249, 313-328.
4. 1a,b
5. Yamada, H.; Siems, W. F.; Koike, T.; Hurst, J. K. J. Am. Chem. Soc. 2004, 126, 9786-9795.
6. Geselowitz, D. A.; Meyer, T. J. Inorg. Chem. 1990, 29, 3894-3896.
7. Yang, X.; Baik, M.-H. J. Am. Chem. Soc. 2006, 128, 7476-7485.
8. (a) Albert, A.; Armarego, W. L. F. Adv. Heterocycl. Chem. 1965, 4, 1-42.
9. (b) Albert, A. Adv. Heterocycl. Chem. 1976, 20, 117-143.
10. Maliyackel, A. C.; Waltz, W. L.; Lilie, J.; Woods, R. J. Inorg. Chem. 1990, 29, 340-348.
11. Bunting, J. W. Adv. Heterocycl. Chem. 1979, 25, 1-82.
12. Wasserman, H. H.; Scheffer, J. R. J. Am. Chem. Soc. 1967, 89, 3073-3075.
13. Creutz, C.; Sutin, N. Proc Natl. Acad. Sci. U.S.A. 1975, 72, 2858-2862.
14. Ledney, M.; Dutta, P. K. J. Am. Chem. Soc. 1995, 117, 7687-7695.
15. (a) Dimitrijević, N. M.; Mićić, O. I. J. Chem. Soc., Dalton Trans. 1982, 1953-1957.
16. (b) Mulazzani, Q. G.; Venturi, M.; Bolletta, F.; Balzani, V. lnorg. Chim. Acta 1986, 113, L1-L2.
17. Ghosh, P. K.; Brunschwig, B. S.; Chou, M.; Creutz, C.; Sutin, N. J. Am. Chem. Soc. 1984, 106, 4772-4783.
18. (a) Rotzinger, F. P.; Munavalli, S.; Comte, P.; Hurst, J. K.; Grätzel, M.; Frank, A. J. J. Am. Chem. Soc. 1987, 109, 6619-6626.
19. (b) Comte, P.; Nazeerudin, M. K.; Rotzinger, F. P.; Frank, A. J.; Grätzel, M. J. Mol. Catal. 1989, 52, 63-84.
20. (a) Gilbert, J. A.; Eggleston, D. S.; Murphy, W. R., Jr.; Geselowitz, D. A.; Gersten, S. W.; Hodgson, D. J.; Meyer, T. J. J. Am. Chem. Soc. 1985, 107, 3855-3864.
21. (b) Gilbert, J. A.; Geselowitz, D.; Meyer, T. J. J. Am. Chem. Soc. 1986, 108, 1493-1501.
22. Yamada, H.; Hurst, J. K. J. Am. Chem. Soc. 2000, 122, 5303-5311.