Ruthenium(II) MLCT Excited States. Stabilization toward Ligand Loss in Rigid Media

Inorganic Chemistry

Volumn 37, Issue 11, 1998, Pages 2616-2617

  Adelt, Maik ^a,b   Devenney, Martin ^a,c   Meyer, Thomas J ^a   Thompson, David W ^a   Treadway, Joseph A ^a  

^a UNIVERSITY OF NORTH CAROLINA   (United States)

^b FRITZ HABER INSTITUT DER MAX PLANCK GESELLSCHAFT   (Germany)

^c SYMYX TECHNOLOGIES   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0542442097     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971121b     Document Type: Article

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19. Solution quantum yields were determined by irradiating the sample in a stirred solution contained in a jacketed cell in which at feast 98% of the incident radiation was absorbed. The yields were calculated relative to a Reineckate actinometer by following the change in absorbance with time for the first 5% of the reaction. The optical train for all the photolyses described consisted of a 75 W Xe lamp powered by a high-precision constant current source and an f4 matched monochromator with 1200 line/mm gratings using glass optics to focus the beam inside the sample.
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