Chemical and spectroscopic evidence for an FeV-oxo complex

Science

Volumn 315, Issue 5813, 2007, Pages 835-838

  De Oliveira, Filipe Tiago ^a   Chanda, Arani ^a   Banerjee, Deboshri ^a   Shan, Xiaopeng ^b   Mondal, Sujit ^a   Que Jr , Lawrence ^b   Bominaar, Emile L ^a   Münck, Eckard ^a   Collins, Terrence J ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

^b University of Minnesota   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDE; HYDROGEN PEROXIDE; IRON COMPLEX; MACROCYCLIC COMPOUND;

CATALYSIS; DECOMPOSITION; ENZYME ACTIVITY; FREE RADICAL; HYDROGEN PEROXIDE; IRON; LIGAND; MASS SPECTROMETRY; ORGANIC COMPOUND; X-RAY SPECTROSCOPY;

ARTICLE; CATALYST; CHEMICAL ANALYSIS; DECOMPOSITION; DENSITY FUNCTIONAL THEORY; ELECTRON SPIN RESONANCE; MASS SPECTROMETRY; MOSSBAUER SPECTROSCOPY; POLLUTANT; PRIORITY JOURNAL; ROENTGEN SPECTROSCOPY; SPECTROSCOPY; SYNTHESIS;

CATALYSIS; CHEMISTRY, PHYSICAL; ELECTRON SPIN RESONANCE SPECTROSCOPY; IRON COMPOUNDS; LIGANDS; MACROCYCLIC COMPOUNDS; MOLECULAR CONFORMATION; OXIDATION-REDUCTION; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION; SPECTROSCOPY, MOSSBAUER; SPECTRUM ANALYSIS; X-RAYS;

EID: 33846956737     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1133417     Document Type: Article

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22. The work was supported by NIH grants EB001475 (E.M.) and GM-38767 (L.Q.), the Heinz Endowments (T.J.C.), Environmental Protection Agency (grant RD 83 to T.J.C.), and the Heinz Foundation for the Teresa Heinz Scholars for Environmental Research award (to D.B.). XAS data were collected on beamline X3B at the National Synchrotron Light Source, which is supported by the U.S. Department of Energy and the National Institutes of Health. We also thank M. Costas and A. Ghosh for valuable suggestions.