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Volumn 101, Issue 1, 2001, Pages 21-35

Molecular catalysts for water oxidation

(2)  Yagi, Masayuki a   Kaneko, Masao a  

a NONE

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; MATHEMATICAL MODELS; OXIDATION; PARAMAGNETIC RESONANCE; PHOTOCATALYSIS; PHOTOSYNTHESIS; WATER;

EID: 0035124004     PISSN: 00092665     EISSN: None     Source Type: Journal    
DOI: 10.1021/cr980108l     Document Type: Article
Times cited : (615)

References (120)
  • 4
  • 18
    • 0004156451 scopus 로고    scopus 로고
    • Ort, D. R., Yocum, C. F., Eds.; Kluwer Academic Publishers: Dordrecht
    • Britt, R. D. In Oxgenic Photosynthesis: The Light Reaction; Ort, D. R., Yocum, C. F., Eds.; Kluwer Academic Publishers: Dordrecht, 1996.
    • (1996) Oxgenic Photosynthesis: The Light Reaction
    • Britt, R.D.1
  • 56
    • 0343290902 scopus 로고    scopus 로고
    • For example, references in ref 6
    • For example, references in ref 6.
  • 77
    • 0342855883 scopus 로고    scopus 로고
    • note
    • 2 vs time plots, giving an approximately liner relationship up to 30 min (ref 59).
  • 78
    • 0343290896 scopus 로고    scopus 로고
    • note
    • The value of a is calculated from the fraction of its hydrophilic column. An a value of 40 (ref 59) was used for a commercially available Nafion membrane in chemical water oxidation and 5.1 (ref 66) for a cast-membrane formed from a Nafion solution in electrochemical water oxidation.
  • 79
    • 0343726300 scopus 로고    scopus 로고
    • note
    • s is the sum of van der Waals radii of a catalyst, calculated from the distance and the angle of the atoms as well as the van der Waals radius of hydrogen, (see refs 59 and 63).
  • 80
    • 0342421251 scopus 로고    scopus 로고
    • note
    • d, obtained in the activity analysis on molecular distribution, includes contributions from the segmental motion of polymer and the bounded motion of the complex (local oscillation) (see ref 82). However, it could be assumed that despite these factors, the distribution of the dispersed molecules would maintain a random one at every moment, so that these motions would not affect the distribution of the complex as a whole. The positive charges on the complex would be compensated by the sulfonate anions of Nafion. We assume also that the distribution has a random distribution even if the interaction between the positive charges on the complexes is not negligible, since an isotropic perturbation by the charges would cause a random distribution in the membrane.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.