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2 vs time plots, giving an approximately liner relationship up to 30 min (ref 59).
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78
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0343290896
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The value of a is calculated from the fraction of its hydrophilic column. An a value of 40 (ref 59) was used for a commercially available Nafion membrane in chemical water oxidation and 5.1 (ref 66) for a cast-membrane formed from a Nafion solution in electrochemical water oxidation.
-
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79
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s is the sum of van der Waals radii of a catalyst, calculated from the distance and the angle of the atoms as well as the van der Waals radius of hydrogen, (see refs 59 and 63).
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80
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d, obtained in the activity analysis on molecular distribution, includes contributions from the segmental motion of polymer and the bounded motion of the complex (local oscillation) (see ref 82). However, it could be assumed that despite these factors, the distribution of the dispersed molecules would maintain a random one at every moment, so that these motions would not affect the distribution of the complex as a whole. The positive charges on the complex would be compensated by the sulfonate anions of Nafion. We assume also that the distribution has a random distribution even if the interaction between the positive charges on the complexes is not negligible, since an isotropic perturbation by the charges would cause a random distribution in the membrane.
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