Highly efficient and robust molecular ruthenium catalysts for water oxidation

Proceedings of the National Academy of Sciences of the United States of America

Volumn 109, Issue 39, 2012, Pages 15584-15588

  Duan, Lele ^a   Araujo, Carlos Moyses ^a,c   Ahlquist, Mårten S G ^a   Sun, Licheng ^a,b  

^a ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

^b DALIAN UNIVERSITY OF TECHNOLOGY   (China)

^c YALE UNIVERSITY   (United States)

Author keywords

Catalysis; Density function theory; Photosystem II; Seven coordination; Solar fuels

Indexed keywords

2,2' BIPYRIDINE 6,6' DICARBOXYLIC ACID; CARBOXYLIC ACID; HYDROGEN; OXYGEN; PHTHALAZINE DERIVATIVE; PYRIDAZINE; PYRIMIDINE; RUTHENIUM; UNCLASSIFIED DRUG; WATER;

ARTICLE; CATALYSIS; CATALYST; CONTROLLED STUDY; DENSITY FUNCTIONAL THEORY; LIGAND BINDING; OXIDATION KINETICS; PRIORITY JOURNAL; SOLAR RADIATION; WATER OXIDATION; WATER SPLITTING SYSTEM;

ELECTRONS; HYDROGEN; OXIDATION-REDUCTION; OXYGEN; PROTONS; RUTHENIUM; WATER;

EID: 84866844020     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.1118347109     Document Type: Article

References (34)

1. Youngblood WJ, Lee S-HA, Maeda K, Mallouk TE (2009) Visible light water splitting using dye-sensitized oxide semiconductors. Acc Chem Res 42:1966-1973.
2. Balzani V, Credi A, Venturi M (2008) Photochemical conversion of solar energy. ChemSusChem 1:26-58.
3. Duan L, Tong L, Xu Y, Sun L (2011) Visible light-driven water oxidation from molecular catalysts to photoelectrochemical cells. Energy Environ Sci 4:3296-3313.
4. Concepcion JJ, et al. (2009) Making oxygen with ruthenium complexes. Acc Chem Res 42:1954-1965.
5. Sala X, Romero I, Rodríguez M, Escriche L, Llobet A (2009) Molecular catalysts that oxidize water to dioxygen. Angew Chem Int Ed Engl 48:2842-2852.
6. McDaniel ND, Coughlin FJ, Tinker LL, Bernhard S (2008) Cyclometalated iridium(III) aquo complexes: Efficient and tunable catalysts for the homogeneous oxidation of water. J Am Chem Soc 130:210-217.
7. Hull JF, et al. (2009) Highly active and robust Cp*iridium complexes for catalytic water oxidation. J Am Chem Soc 131:8730-8731.
8. Lalrempuia R, McDaniel ND, Müller-Bunz H, Bernhard S, Albrecht M (2010) Water oxidation catalyzed by strong carbene-type donor-ligand complexes of iridium. Angew Chem Int Ed Engl 49:9765-9768.
9. Yin Q, et al. (2010) A fast soluble carbon-free molecular water oxidation catalyst based on abundant metals. Science 328:342-345.
10. Dogutan DK, McGuire R, Nocera DG (2011) Electocatalytic water oxidation by cobalt (III) hangman b-octafluoro corroles. J Am Chem Soc 133:9178-9180.
11. Wasylenko DJ, Ganesamoorthy C, Borau-Garcia J, Berlinguette CP (2011) Electrochemical evidence for catalytic water oxidation mediated by a high-valent cobalt complex. Chem Commun 47:4249-4251.
12. Shevchenko D, Anderlund MF, Thapper A, Styring S (2011) Photochemical water oxidation with visible light using a cobalt containing catalyst. Energy Environ Sci 4:1284-1287.
13. Jiao F, Frei H (2009) Nanostructured cobalt oxide clusters in mesoporous silica as efficient oxygen-evolving catalysts. Angew Chem Int Ed Engl 48:1841-1844.
14. Ellis WC, McDaniel ND, Bernhard S, Collins TJ (2010) Fast water oxidation using iron. J Am Chem Soc 132:10990-10991.
15. Fillol JL, et al. (2011) Efficient water oxidation catalysts based on readily available iron coordination complexes. Nat Chem 3:807-813.
16. 2O) as biomimetic oxygen-evolving catalysts. Angew Chem Int Ed Engl 49:2233-2237.
17. Hocking RK, et al. (2011) Water-oxidation catalysis by manganese in a geochemical-like cycle. Nat Chem 3:461-466.
18. 3+ complex onto clay compounds. J Am Chem Soc 126:8084-8085.
19. Duan L, et al. (2012) A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II. Nat Chem 4:418-423.
20. - bridging ligand as an intermediate for catalytic water oxidation. J Am Chem Soc 131:10397-10399.
21. -1 bridge: A computational study. Angew Chem Int Ed Engl 49:1773-1777.
22. Mola J, et al. (2008) Ru-Hbpp-based water-oxidation catalysts anchored on conducting solid supports. Angew Chem Int Ed Engl 47:5830-5832.
23. Chen Z, Concepcion JJ, Jurss JW, Meyer TJ (2009) Single-site, catalytic water oxidation on oxide surfaces. J Am Chem Soc 131:15580-15581.
24. Concepcion JJ, Jurss JW, Hoertz PG, Meyer TJ (2009) Catalytic and surface-electrocatalytic water oxidation by redox mediator-catalyst assemblies. Angew Chem Int Ed Engl 48:9473-9476.
25. Li F, et al. (2011) Highly efficient oxidation of water by a molecular catalyst immobilized on carbon nanotubes. Angew Chem Int Ed Engl 50:12276-12279.
26. 2+ scaffold: Effects on catalytic water oxidation. J Am Chem Soc 132:16094-16106.
27. Yoshida M, Masaoka S, Abe J, Sakai K (2010) Catalysis of mononuclear aquaruthenium complexes in oxygen evolution from water: A new radical coupling path using hydroxocerium(IV) species. Chem Asian J 5:2369-2378.
28. 2 evolution from water based on mononuclear ruthenium(II) monoaquo complexes. Dalton Trans 40:3802-3804.
29. Bozoglian F, et al. (2009) The Ru-Hbpp water oxidation catalyst. J Am Chem Soc 131:15176-15187.
30. Duan L, et al. (2010) Chemical and photochemical water oxidation catalyzed by mononuclear ruthenium complexes with a negatively charged tridentate ligand. Chem Eur J 16:4659-4668.
31. Xu Y, et al. (2010) Chemical and light-driven oxidation of water catalyzed by an efficient dinuclear ruthenium complex. Angew Chem Int Ed Engl 49:8934-8937.
32. Lee C, Yang W, Parr RG (1988) Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density. Phys Rev B 37:785-789.
33. Zhao Y, Truhlar DG (2006) The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: Two new functionals and systematic testing of four M06-class functionals and 12 other functionals. Theor Chem Acc 120:215-241.
34. Martin JML, Sundermann A (2001) Correlation consistent valence basis sets for use with the Stuttgart-Dresden-Bonn relativistic effective core potentials: The atoms Ga-Kr and In-Xe. J Chem Phys 114:3408-3420. (Pubitemid 32253352)