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Volumn , Issue 4, 2013, Pages 494-499

Click chemistry as a convenient tool for the incorporation of a ruthenium chromophore and a nickel-salen monomer into a visible-light-active assembly

Author keywords

Click chemistry; Electron transfer; N,O ligands; Ruthenium; Sensitizers

Indexed keywords

CHROMOPHORES; ELECTRON TRANSITIONS; LIGHT ABSORPTION; NICKEL COMPOUNDS; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

EID: 84872832251     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201201161     Document Type: Article
Times cited : (11)

References (36)
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    • 84863229501 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2012, 51, 2417-2420.
    • (2012) Angew. Chem. Int. Ed. , vol.51 , pp. 2417-2420
  • 14
    • 0000096835 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2001, 40, 2004-2021.
    • (2001) Angew. Chem. Int. Ed. , vol.40 , pp. 2004-2021
  • 16
    • 0037099395 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 2596-2599.
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 2596-2599
  • 31
    • 0038141811 scopus 로고    scopus 로고
    • F. Lafolet, J. Chauvin, M. Collomb, A. Deronzier, H. Laguitton-Pasquier, J. C. Lepretre, J. C. Vial, B. Brasme, Phys. Chem. Chem. Phys. 2003, 5, 2520-2527. Diazonium salts are often used as sacrificial electron acceptors in light-driven reactions because of their low reduction potentials (0.5 V vs. NHE) and lack of absorption in the visible region. They quench the excited state of ruthenium compounds by electron transfer. The reaction is stoichiometric with no back reaction from the reduced species to the ruthenium sensitiser. Upon reduction, diazonium salts undergo carbon-nitrogen cleavage, forming nitrogen and an aryl radical. The resulting radical abstracts a hydrogen from a solvent molecule, which results in the overall replacement of the hydrogen atom by the diazonium group.
    • (2003) Phys. Chem. Chem. Phys. , vol.5 , pp. 2520-2527
    • Lafolet, F.1    Chauvin, J.2    Collomb, M.3    Deronzier, A.4    Laguitton-Pasquier, H.5    Lepretre, J.C.6    Vial, J.C.7    Brasme, B.8


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.