In situ formation of an oxygen-evolving catalyst in neutral water containing phosphate and Co2+

Science

Volumn 321, Issue 5892, 2008, Pages 1072-1075

  Kanan, Matthew W ^a   Nocera, Daniel G ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT; OXYGEN; PHOSPHATE;

CATALYSIS; COBALT; ELECTRODE; OXIDE; PHOSPHATE; PHOTOSYNTHESIS; SOLAR POWER;

ANALYTIC METHOD; ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; CHEMICAL REACTION; OXIDATION; PHOTOSYNTHESIS; POLARIZATION; PRIORITY JOURNAL; SOLAR ENERGY;

CATALYSIS; COBALT; ELECTROCHEMISTRY; ELECTRODES; ELECTROLYSIS; HYDROGEN-ION CONCENTRATION; OXIDATION-REDUCTION; OXYGEN; PHOSPHATES; PHOTOSYNTHESIS; POTASSIUM COMPOUNDS; WATER;

EID: 50149121231     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1162018     Document Type: Article

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25. This work was supported by a grant from the NSF Chemical Bonding Center (CHE-0802907). M.W.K. is supported by a Ruth L. Kirchenstein National Research Service Award postdoctoral fellowship provided by NIH (F32GM07782903). We thank E. Shaw for obtaining XPS spectra, G. Henoch for providing the videos in the supporting online material, and Y. Surendranath for many productive discussions.