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42
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Binstead, R.A.1
Chronister, C.W.2
Ni, J.F.3
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Meyer, T.J.5
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50
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0000464071
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F.P. Rotzinger, S. Munavalli, P. Comte, J.K. Hurst, M. Grätzel, F.-J. Pern, and A.J. Frank J. Am. Chem. Soc. 109 1987 6619
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Rotzinger, F.P.1
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Frank, A.J.7
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P. Comte, M.K. Nazeruddin, F.P. Rotzinger, A.J. Frank, and M. Grätzel J. Mol. Catal. 52 1989 63
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Comte, P.1
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Frank, A.J.4
Grätzel, M.5
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55
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11844253992
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-
note
-
The activity measured by Doppelt and Meyer was so low that they could not exclude the possibility that it was derived from impurities in the preparation.
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-
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57
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11844304485
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T.R. Weaver, T.J. Meyer, S.A. Adeyemi, G.M. Brown, R.P. Eckland, W.E. Hatfield, E.C. Johnson, R.W. Murray, and D. Unterecker J. Am. Chem. Soc. 97 1975 3040
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J. Am. Chem. Soc.
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Weaver, T.R.1
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Adeyemi, S.A.3
Brown, G.M.4
Eckland, R.P.5
Hatfield, W.E.6
Johnson, E.C.7
Murray, R.W.8
Unterecker, D.9
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58
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0001382574
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J.R. Schoonover, J.F. Ni, L. Roecker, P.S. White, and T.J. Meyer Inorg. Chem. 35 1996 5885
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(1996)
Inorg. Chem.
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, pp. 5885
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-
Schoonover, J.R.1
Ni, J.F.2
Roecker, L.3
White, P.S.4
Meyer, T.J.5
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60
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0001557834
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J. Sanders-Loehr, W.D. Wheeler, A.D. Shiemke, B.A. Averill, and T.M. Loehr J. Am. Chem. Soc. 111 1989 8084
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Sanders-Loehr, J.1
Wheeler, W.D.2
Shiemke, A.D.3
Averill, B.A.4
Loehr, T.M.5
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62
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11844269440
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note
-
s [46]. This cannot be ascribed simply to a larger bending angle, however, because in this oxidation state, the RuO lengths in the RuORu unit are also unequal [58], i.e., the stretching mode is inherently asymmetric regardless of the bending angle. Consequently, the O atom will also move in this mode when the RuORu bond is linear.
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66
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0022418084
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G.E. Cabaniss, A.A. Diamantis, W.R. Murphy, R.W. Linton, and T.J. Meyer J. Am. Chem. Soc. 107 1985 1845
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J. Am. Chem. Soc.
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-
Cabaniss, G.E.1
Diamantis, A.A.2
Murphy, W.R.3
Linton, R.W.4
Meyer, T.J.5
-
68
-
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11844250109
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-
note
-
These oxidation states were confirmed by another experiment in which equimolar solutions of the {3,3} and electrochemically prepared {5,5} ions were mixed to give a solution whose spectrum was that of the intermediate ({4,4}) [49]. Had either the most highly oxidized species not been {5,5} or the intermediate been {4,5}, the product solution would have contained significant amounts of {3,4}, which is readily detectable in the optical spectra.
-
-
-
-
69
-
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11844285822
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note
-
2, {3,3} would be rapidly oxidized in additional steps to {4,4}. In general, because redox cross-reactions between the complexes are rapid relative to decomposition of the {5,5} [41,42], the distribution of oxidation states will reflect the overall redox poise of the solution at any point in time.
-
-
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75
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11844262205
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note
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3H. Meyer and coworkers report complex precipitation also occurs under certain circumstances in triflate-containing media [42], although we have never observed this.
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77
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0037100536
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R. Arakawa, N. Kubota, T. Fukuo, O. Ishitani, and E. Ando Inorg. Chem. 41 2002 3749
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Arakawa, R.1
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Fukuo, T.3
Ishitani, O.4
Ando, E.5
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85
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0000612645
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I. Rappaport, L. Helm, A.E. Merbach, P. Bernhard, and A. Lundi Inorg. Chem. 27 1988 873
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Inorg. Chem.
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, pp. 873
-
-
Rappaport, I.1
Helm, L.2
Merbach, A.E.3
Bernhard, P.4
Lundi, A.5
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89
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84860061009
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-
J.A. Halfen, S. Mahapatra, E.C. Wilkinson, S. Kaderli, V.G. Young Jr., L. Que, A.D. Zuberbühler, and W.B. Tolman Science 271 1996 1379
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Halfen, J.A.1
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Wilkinson, E.C.3
Kaderli, S.4
Young Jr., V.G.5
Que, L.6
Zuberbühler, A.D.7
Tolman, W.B.8
-
90
-
-
11844268244
-
-
note
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4+ [59].
-
-
-
-
91
-
-
11844250107
-
-
note
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4+.
-
-
-
-
92
-
-
11844291506
-
-
note
-
2 evolution. Since the concentration levels of this intermediate would necessarily be very low and exchange at the cis-positions in other higher oxidation states of the μ-oxo ion is undetectably slow, this mechanism is not very appealing. It, however, cannot presently be excluded.
-
-
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-
94
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0000812210
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R.A. Binstead, M.E. McGuire, A. Dovletoglou, W.K. Seok, L.E. Roecker, and T.J. Meyer J. Am. Chem. Soc. 114 1992 173
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J. Am. Chem. Soc.
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-
-
Binstead, R.A.1
McGuire, M.E.2
Dovletoglou, A.3
Seok, W.K.4
Roecker, L.E.5
Meyer, T.J.6
-
99
-
-
11844303043
-
-
note
-
The {4,4} ion is either even-spin or diamagnetic, and would not be expected to give an X-band epr signal. This signal could arise from the {4,5} ion if the one-electron reduction potentials of the {3,4} and {4,4} ions exhibited temperature dependencies that favored {4,4} accumulation at room temperature and {4,5} accumulation at low temperatures.
-
-
-
-
100
-
-
11844293592
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note
-
- should occur preferentially at the ring 4-position [23-25].
-
-
-
-
106
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0033525908
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J. Limburg, J.S. Vrettos, L.M. Liable-Sands, A.R. Rheingold, R.H. Crabtree, and G.W. Brudvig Science 283 1999 1524
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Limburg, J.1
Vrettos, J.S.2
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Rheingold, A.R.4
Crabtree, R.H.5
Brudvig, G.W.6
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107
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0035941496
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J. Limburg, J.S. Vrettos, H. Chen, J.C. dePaula, R.H. Crabtree, and G.W. Brudvig J. Am. Chem. Soc. 123 2001 423
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Limburg, J.1
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