Half-sandwich iridium complexes for homogeneous water-oxidation catalysis

Journal of the American Chemical Society

Volumn 132, Issue 45, 2010, Pages 16017-16029

  Blakemore, James D ^a   Schley, Nathan D ^a   Balcells, David ^b,c   Hull, Jonathan F ^a   Olack, Gerard W ^a   Incarvito, Christopher D ^a   Eisenstein, Odile ^c   Brudvig, Gary W ^a   Crabtree, Robert H ^a  

^a YALE UNIVERSITY   (United States)

^b UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^c UNIVERSITÉ DE MONTPELLIER   (France)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIUM NITRATE; CATALYST PRECURSORS; CATIONIC COMPLEXES; CHELATE LIGANDS; DFT CALCULATION; DIOXYGENS; ELECTROCHEMICAL STUDIES; HALF-SANDWICH; HALF-SANDWICH COMPLEXES; HOMOGENEOUS CATALYST; HOMOGENEOUS OXIDATION; IRIDIUM COMPLEX; IRIDIUM DIOXIDE; KINETIC EXPERIMENT; KINETIC STUDY; NANO PARTICULATES; NO OXIDATION; OXIDATION CATALYSIS; OXYGEN ATOM; OXYGEN EVOLUTION; RATE DETERMINING STEP; TURNOVER FREQUENCY; WATER OXIDATION;

AMMONIUM COMPOUNDS; CATALYSIS; CATALYSTS; CERIUM; DYES; EXPERIMENTS; IRIDIUM; IRIDIUM COMPOUNDS; ISOTOPES; OXYGEN; SULFUR COMPOUNDS;

CATALYTIC OXIDATION;

AMMONIUM NITRATE; CATION; CERIUM; IRIDIUM COMPLEX; ISOTOPE; METAL NANOPARTICLE; OXYGEN; OXYGEN 18; WATER;

ARTICLE; CATALYSIS; CATALYST; CHELATION; CHEMICAL BOND; CONTROLLED STUDY; DENSITY FUNCTIONAL THEORY; ELECTROCHEMISTRY; KINETICS; OXIDATION; PH; TURNOVER TIME;

CATALYSIS; CRYSTALLOGRAPHY, X-RAY; IRIDIUM; LIGANDS; OXIDATION-REDUCTION; WATER;

EID: 78449264304     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja104775j     Document Type: Article

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