The renaissance of black phosphorus

Proceedings of the National Academy of Sciences of the United States of America

Volumn 112, Issue 15, 2015, Pages 4523-4530

  Ling, Xi ^a   Wang, Han ^c   Huang, Shengxi ^a   Xia, Fengnian ^d   Dresselhaus, Mildred S ^a,b  

^a USA   (United States)

^b MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

^c Ming Hsieh Department of Electrical Engineering University of Southern California ^*  (United States)

^d Yale University   (United States)

Author keywords

2D material; Anisotropic; Black phosphorus; Nanoelectronic; Optoelectronic

Indexed keywords

BLACK PHOSPHORUS; PHOSPHORUS; UNCLASSIFIED DRUG;

ANISOTROPY; ATOMIC FORCE MICROSCOPY; ELECTRIC CONDUCTIVITY; ELECTRON; ENERGY CONVERSION; FILM; INFRARED SPECTROSCOPY; MOLECULAR ELECTRONICS; PHOTOLUMINESCENCE; PHOTOOXIDATION; PRIORITY JOURNAL; REVIEW; SHORT CIRCUIT CURRENT; THERMAL CONDUCTIVITY; THICKNESS; X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 84928137367     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.1416581112     Document Type: Review

References (108)

1. Li L, et al. (2014) Black phosphorus field-effect transistors. Nat Nanotechnol 9(5):372-377.
2. Xia F, Wang H, Jia Y (2014) Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics. Nat Commun 5:4458.
3. Liu H, et al. (2014) Phosphorene: An unexplored 2D semiconductor with a high hole mobility. ACS Nano 8(4):4033-4041.
4. Koenig SP, Doganov RA, Schmidt H, Neto AHC, Özyilmaz B (2014) Electric field effect in ultrathin black phosphorus. Appl Phys Lett 104(10):103106.
5. Rodin AS, Carvalho A, Castro Neto AH (2014) Strain-induced gap modification in black phosphorus. Phys Rev Lett 112(17):176801.
6. Qiao J, Kong X, Hu Z-X, Yang F, Ji W (2014) High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus. Nat Commun 5:4475.
7. Churchill HOH, Jarillo-Herrero P (2014) Two-dimensional crystals: Phosphorus joins the family. Nat Nanotechnol 9(5):330-331.
8. Liu H, Du Y, Deng Y, Ye PD (2015) Semiconducting black phosphorus: Synthesis, transport properties and electronic applications. Chem Soc Rev, 10.1039/C4CS00257A.
9. Clark SM, Zaug JM (2010) Compressibility of cubic white, orthorhombic black, rhombohedral black, and simple cubic black phosphorus. Phys Rev B 82(13):134111.
10. Morita A (1986) Semiconducting black phosphorus. Appl Phys A Solids Surf 39(4):227-242.
11. Asahina H, Shindo K, Morita A (1982) Electronic structure of black phosphorus in self-consistent pseudopotential approach. J Phys Soc Jpn 51(4):1193-1199.
12. Takao Y, Morita A (1981) Electronic structure of black phosphorus: Tight binding approach. Phys B+C 105(1-3):93-98.
13. Bridgman PW (1914) Two new modifications of phosphorus. J Am Chem Soc 36(7):1344-1363.
14. Jamieson JC (1963) Crystal structures adopted by black phosphorus at high pressures. Science 139(3561):1291-1292.
15. Brown A, Rundqvist S (1965) Refinement of the crystal structure of black phosphorus. Acta Crystallogr 19(4):684-685.
16. Akahama Y, Endo S, Narita S (1983) Electrical properties of black phosphorus single crystals. J Phys Soc Jpn 52(6):2148-2155.
17. Ikezawa M, Kondo Y, Shirotani I (1983) Infrared optical absorption due to one and two phonon processes in black phosphorus. J Phys Soc Jpn 52(5):1518-1520.
18. Suzuki N, Aoki M (1987) Interplanar forces of black phosphorus caused by electron-lattice interaction. Solid State Commun 61(10):595-600.
19. Kawamura H, Shirotani I, Tachikawa K (1985) Anomalous superconductivity and pressure induced phase transitions in black phosphorus. Solid State Commun 54(9):775-778.
20. Wittig J, Matthias BT (1968) Superconducting phosphorus. Science 160(3831):994-995.
21. Park C-M, Sohn H-J (2007) Black phosphorus and its composite for lithium rechargeable batteries. Adv Mater 19(18):2465-2468.
22. Nagao M, Hayashi A, Tatsumisago M (2011) All-solid-state lithium secondary batteries with high capacity using black phosphorus negative electrode. J Power Sources 196(16):6902-6905.
23. Sun J, et al. (2014) Formation of stable phosphorus-carbon bond for enhanced performance in black phosphorus nanoparticle-graphite composite battery anodes. Nano Lett 14(8):4573-4580.
24. Keyes R (1953) The electrical properties of black phosphorus. Phys Rev 92(3):580-584.
25. Morita A, Sasaki T (1989) Electron-phonon interaction and anisotropic mobility in black phosphorus. J Phys Soc Jpn 58(5):1694-1704.
26. Asahina H, Morita A (1984) Band structure and optical properties of black phosphorus. J Phys C Solid State Phys 17(11):1839-1852.
27. Sugai S, Shirotani I (1985) Raman and infrared reflection spectroscopy in black phosphorus. Solid State Commun 53(9):753-755.
28. Shibata K, Sasaki T, Morita A (1987) The energy band structure of black phosphorus and angle-resolved ultraviolet photoelectron spectra. J Phys Soc Jpn 56(6):1928-1931.
29. Narita S, et al. (1983) Far-infrared cyclotron resonance absorptions in black phosphorus single crystals. J Phys Soc Jpn 52(10):3544-3553.
30. Baba M, Izumida F, Morita A, Koike Y, Fukase T (1991) Electrical properties of black phosphorus single crystals prepared by the bismuth-flux method. Jpn J Appl Phys 30(Part 1, No 8):1753-1758.
31. Tran V, Soklaski R, Liang Y, Yang L (2014) Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus. Phys Rev B 89(23):235319.
32. Rudenko AN, Katsnelson MI (2014) Quasiparticle band structure and tight-binding model for single- and bilayer black phosphorus. Phys Rev B 89(20):201408.
33. Kim H (2014) Effect of van der Waals interaction on the structural and cohesive properties of black phosphorus. J Korean Phys Soc 64(4):547-553.
34. Li Y, Yang S, Li J (2014) Modulation of the electronic properties of ultrathin black phosphorus by strain and electrical field. J Phys Chem C 118(41):23970-23976.
35. Fei R, Yang L (2014) Strain-engineering the anisotropic electrical conductance of few-layer black phosphorus. Nano Lett 14(5):2884-2889.
36. Wei Q, Peng X (2014) Superior mechanical flexibility of phosphorene and few-layer black phosphorus. Appl Phys Lett 104(25):251915.
37. Fei R, Yang L (2014) Lattice vibrational modes and Raman scattering spectra of strained phosphorene. Appl Phys Lett 105(8):083120.
38. Peng X, Wei Q, Copple A (2014) Strain-engineered direct-indirect band gap transition and its mechanism in two-dimensional phosphorene. Phys Rev B 90(8):085402.
39. Liu Y, Xu F, Zhang Z, Penev ES, Yakobson BI (2014) Two-dimensional mono-elemental semiconductor with electronically inactive defects: The case of phosphorus. Nano Lett 14(12): 6782-6786.
40. Yu X, Ushiyama H, Yamashita K (2014) Comparative study of Na/Li intercalation and diffusion mechanism in black phosphorus from first-principles simulation. Chem Lett 43(12):1940-1942.
41. Zhu Z, Tománek D (2014) Semiconducting layered blue phosphorus: A computational study. Phys Rev Lett 112(17):176802.
42. Guan J, Zhu Z, Tománek D (2014) Phase coexistence and metalinsulator transition in few-layer phosphorene: A computational study. Phys Rev Lett 113(4):046804.
43. Ramasubramaniam A, Muniz AR (2014) Ab initio studies of thermodynamic and electronic properties of phosphorene nanoribbons. Phys Rev B 90(8):085424.
44. Tran V, Yang L (2014) Scaling laws for the band gap and optical response of phosphorene nanoribbons. Phys Rev B 89(24):245407.
45. Guo H, Lu N, Dai J, Wu X, Zeng XC (2014) Phosphorene nanoribbons, phosphorus nanotubes, and van der Waals multilayers. J Phys Chem C 118(25):14051-14059.
46. Peng X, Copple A, Wei Q (2014) Edge effects on the electronic properties of phosphorene nanoribbons. J Appl Phys 116(14):144301.
47. Han X, Stewart HM, Shevlin SA, Catlow CRA, Guo ZX (2014) Strain and orientation modulated bandgaps and effective masses of phosphorene nanoribbons. Nano Lett 14(8):4607-4614.
48. Dai J, Zeng XC (2014) Bilayer phosphorene: Effect of stacking order on bandgap and its potential applications in thin-film solar cells. J Phys Chem Lett 5(7):1289-1293.
49. Castellanos-Gomez A, et al. (2014) Isolation and characterization of few-layer black phosphorus. 2D Mater 1(2):025001.
50. Zhang S, et al. (2014) Extraordinary photoluminescence and strong temperature/angle-dependent Raman responses in few-layer phosphorene. ACS Nano 8(9):9590-9596.
51. Lu W, et al. (2014) Plasma-assisted fabrication of monolayer phosphorene and its Raman characterization. Nano Res 7(6):853-859.
52. Dai J, Zeng XC (2014) Structure and stability of two dimensional phosphorene with =O or =NH functionalization. RSC Adv 4(89):48017-48021.
53. Wood JD, et al. (2014) Effective passivation of exfoliated black phosphorus transistors against ambient degradation. Nano Lett 14(12):6964-6970.
54. Favron A, et al. (2014) Exfoliating pristine black phosphorus down to the monolayer: Photo-oxidation and electronic confinement effects. arXiv:14080345v2.
55. Na J, et al. (2014) Few-layer black phosphorus field-effect transistors with reduced current fluctuation. ACS Nano 8(11):11753-11762.
56. Jiang J-W, Park HS (2014) Negative Poisson's ratio in single-layer black phosphorus. Nat Commun 5:4727.
57. Jiang J-W, Park HS (2014) Mechanical properties of single-layer black phosphorus. J Phys D Appl Phys 47(38):385304.
58. Wang H, et al. (2014) Black phosphorus radio-frequency transistors. Nano Lett 14(11):6424-6429.
59. Du Y, Liu H, Deng Y, Ye PD (2014) Device perspective for black phosphorus field-effect transistors: Contact resistance, ambipolar behavior, and scaling. ACS Nano 8(10):10035-10042.
60. Liu H, Neal AT, Si M, Du Y, Ye PD (2014) The effect of dielectric capping on few-layer phosphorene transistors: Tuning the Schottky barrier heights. IEEE Electron Device Lett 35(7):795-797.
61. Das S, et al. (2014) Tunable transport gap in phosphorene. Nano Lett 14(10):5733-5739.
62. Engel M, Steiner M, Avouris P (2014) A black phosphorus photo-detector for multispectral, high-resolution imaging. arXiv:14072534.
63. Low T, Engel M, Steiner M, Avouris P (2014) Origin of photoresponse in black phosphorus phototransistors. Phys Rev B 90(8):081408.
64. Buscema M, et al. (2014) Fast and broadband photoresponse of few-layer black phosphorus field-effect transistors. Nano Lett 14(6):3347-3352.
65. Deng Y, et al. (2014) Black phosphorus-monolayer MoS2 van der Waals heterojunction p-n diode. ACS Nano 8(8):8292-8299.
66. Buscema M, Groenendijk DJ, Steele GA, van der Zant HSJ, Castellanos-Gomez A (2014) Photovoltaic effect in few-layer black phosphorus PN junctions defined by local electrostatic gating. Nat Commun 5:4651.
67. Hong T, et al. (2014) Polarized photocurrent response in black phosphorus field-effect transistors. Nanoscale 6(15):8978-8983.
68. Qin G, et al. (2014) Hinge-like structure induced unusual properties of black phosphorus and new strategies to improve the thermoelectric performance. Sci Rep 4:6946.
69. Fei R, et al. (2014) Enhanced thermoelectric efficiency via orthogonal electrical and thermal conductances in phosphorene. Nano Lett 14(11):6393-6399.
70. Kou L, Frauenheim T, Chen C (2014) Phosphorene as a superior gas sensor: Selective adsorption and distinct I - V response. J Phys Chem Lett 5(15):2675-2681.
71. Wang X, et al. (2014) Highly anisotropic and robust excitons in monolayer black phosphorus. arXiv:14111695v1.
72. Ezawa M (2014) Topological origin of quasi-flat edge band in phosphorene. New J Phys 16(11):115004.
73. Wu Q, et al. (2014) Band gaps and giant stark effect in nonchiral phosphorene nanoribbons. arXiv:14053077v3.
74. Novoselov KS, et al. (2005) Two-dimensional gas of massless Dirac fermions in graphene. Nature 438(7065):197-200.
75. Zhang Y, Tan Y-W, Stormer HL, Kim P (2005) Experimental observation of the quantum Hall effect and Berry's phase in graphene. Nature 438(7065):201-204.
76. Mak KF, Lee C, Hone J, Shan J, Heinz TF (2010) Atomically thin MoS2: A new direct-gap semiconductor. Phys Rev Lett 105(13):136805.
77. Splendiani A, et al. (2010) Emerging photoluminescence in monolayer MoS2. Nano Lett 10(4):1271-1275.
78. Jones AM, et al. (2014) Spin-layer locking effects in optical orientation of exciton spin in bilayer WSe2. Nat Phys 10(2):130-134.
79. Britnell L, et al. (2013) Strong light-matter interactions in heterostructures of atomically thin films. Science 340(6138):1311-1314.
80. Low T, et al. (2014) Tunable optical properties of multilayer black phosphorus thin films. Phys Rev B 90(7):075434.
81. Liang L, et al. (2014) Electronic bandgap and edge reconstruction in phosphorene materials. Nano Lett 14(11):6400-6406.
82. Gong K, Zhang L, Ji W, Guo H (2014) Electrical contacts to monolayer black phosphorus: A first-principles investigation. Phys Rev B 90(12):125441.
83. Low T, et al. (2014) Plasmons and screening in monolayer and multilayer black phosphorus. Phys Rev Lett 113(10):106802.
84. Lv H, Lu W, Shao D, Sun Y (2014) Large thermoelectric power factors in black phosphorus and phosphorene. arXiv:14045171v1.
85. Zhang J, et al. (2014) Phosphorene nanoribbon as a promising candidate for thermoelectric applications. Sci Rep 4:6452.
86. Zhang S, et al. (2014) Extraordinary PL and strong temperature angle-dependent Raman responses in few-layer phosphorene. arXiv:14070502.
87. Rissi EN, Soignard E, McKiernan KA, Benmore CJ, Yarger JL (2012) Pressure-induced crystallization of amorphous red phosphorus. Solid State Commun 152(5):390-394.
88. Endo S, Akahama Y, Terada S, Narita S (1982) Growth of large single crystals of black phosphorus under high pressure. Jpn J Appl Phys 21(Part 2, No 8):L482-L484.
89. Krebs H, Weitz H, Worms KH (1955) Die katalytische darstellung des schwarzen phosphors [The catalytic preparation of black phosphorus]. Z Anorg Allg Chem 280(1-3):119-133.
90. Lange S, Schmidt P, Nilges T (2007) Au3SnP7@black phosphorus: An easy access to black phosphorus. Inorg Chem 46(10):4028-4035.
91. Nilges T, Kersting M, Pfeifer T (2008) A fast low-pressure transport route to large black phosphorus single crystals. J Solid State Chem 181(8):1707-1711.
92. Köpf M, et al. (2014) Access and in situ growth of phosphorene-precursor black phosphorus. J Cryst Growth 405:6-10.
93. Luo X, et al. (2014) Temporal and thermal stability of Al2O3-passivated phosphorene MOSFETs. arXiv:14100994v1.
94. Avsar A, et al. (2014) Electrical characterization of fully encapsulated ultra thin black phosphorus-based heterostructures with graphene contacts. Arxiv: 14121191.
95. Osters O, et al. (2012) Synthesis and identification of metastable compounds: Black arsenic-science or fiction? Angew Chem Int Ed Engl 51(12):2994-2997.
96. Xia F, Wang H, Xiao D, Dubey M, Ramasubramaniam A (2014) Two-dimensional material nanophotonics. Nat Photonics 8(12):899-907.
97. Liang X, Fu Z, Chou SY (2007) Graphene transistors fabricated via transfer-printing in device active-areas on large wafer. Nano Lett 7(12):3840-3844.
98. Lemme MC, Echtermeyer TJ, Baus M, Kurz H (2007) A graphene field-effect device. IEEE Electron Device Lett 28(4):282-284.
99. Das A, et al. (2008) Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor. Nat Nanotechnol 3(4):210-215.
100. Kedzierski J, et al. (2008) Epitaxial graphene transistors on SiC substrates. IEEE Trans Electron Dev 55(8):2078-2085.
101. Park J, et al. (2012) Single-gate bandgap opening of bilayer graphene by dual molecular doping. Adv Mater 24(3):407-411.
102. Szafranek BN, Schall D, Otto M, Neumaier D, Kurz H (2011) High on/off ratios in bilayer graphene field effect transistors realized by surface dopants. Nano Lett 11(7):2640-2643.
103. Ayari A, Cobas E, Ogundadegbe O, Fuhrer MS (2007) Realization and electrical characterization of ultrathin crystals of layered transition-metal dichalcogenides. J Appl Phys 101(1):014507.
104. Kim S, et al. (2012) High-mobility and low-power thin-film transistors based on multilayer MoS2 crystals. Nat Commun 3:1011.
105. Wu W, et al. (2013) High mobility and high on/off ratio field-effect transistors based on chemical vapor deposited single-crystal MoS2 grains. Appl Phys Lett 102(14):142106.
106. Fang H, et al. (2012) High-performance single layered WSe2 p-FETs with chemically doped contacts. Nano Lett 12(7):3788-3792.
107. Liu W, et al. (2013) Role of metal contacts in designing highperformance monolayer n-type WSe2 field effect transistors. Nano Lett 13(5):1983-1990.
108. Ovchinnikov D, Allain A, Huang Y-S, Dumcenco D, Kis A (2014) Electrical transport properties of single-layer WS2. ACS Nano 8(8):8174-8181.