Two-State Reactivity in Low-Valent Iron-Mediated C-H Activation and the Implications for Other First-Row Transition Metals

Journal of the American Chemical Society

Volumn 138, Issue 11, 2016, Pages 3715-3730

  Sun, Yihua ^a   Tang, Hao ^a   Chen, Kejuan ^a   Hu, Lianrui ^a   Yao, Jiannian ^a   Shaik, Sason ^b   Chen, Hui ^a  

^a INSTITUTE OF CHEMISTRY   (China)

^b HEBREW UNIVERSITY OF JERUSALEM   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; BIOACTIVITY; CALCULATIONS; CHEMICAL ACTIVATION; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; EXCITED STATES; GROUND STATE; IRON; LIGANDS; MANGANESE; METALS; NUMERICAL METHODS; SINGLE ELECTRON TRANSISTORS; STABILIZATION; TRANSIENTS; TRANSITION METALS;

C-H FUNCTIONALIZATION; CH-BOND ACTIVATION; COMPARATIVE STUDIES; COUPLED-CLUSTER CALCULATIONS; FIRST ROW TRANSITION METALS; HIGH-SPIN GROUND STATE; SINGLE ELECTRON TRANSFER; TWO-STATE REACTIVITY;

IRON COMPOUNDS;

COBALT; COPPER; FERROUS ION; IRON; MANGANESE; NICKEL;

AB INITIO CALCULATION; ARTICLE; ARYLATION; CALCULATION; CATALYSIS; CATALYST; COMPARATIVE STUDY; CONTROLLED STUDY; CROSS COUPLING REACTION; DENSITY FUNCTIONAL THEORY; ELECTRON TRANSPORT; ENERGY CONSUMPTION; HYDROGEN BOND; OXIDATION; REACTION ANALYSIS;

EID: 84962109460     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b12150     Document Type: Article

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