Exceptional sensitivity of metal-aryl bond energies to ortho-fluorine substituents: Influence of the metal, the coordination sphere, and the spectator ligands on M-C/H-C bond energy correlations

Journal of the American Chemical Society

Volumn 131, Issue 22, 2009, Pages 7817-7827

  Clot, Eric ^a   Mégret, Claire ^a   Eisenstein, Odile ^a   Perutz, Robin N ^b  

^a UNIVERSITÉ DE MONTPELLIER   (France)

^b UNIVERSITY OF YORK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ARYL RINGS; BOND ENERGIES; C-H OXIDATIVE; COORDINATION SPHERE; DFT CALCULATION; FLUORINE SUBSTITUENTS; FLUORINE SUBSTITUTION; IONICITY; LINEAR FUNCTIONS; METAL FRAGMENTS; PERIODIC TABLE; SPECTATOR LIGANDS;

BENZENE; LIGANDS; METALS; PLATINUM; SULFUR COMPOUNDS;

FLUORINE;

BENZENE; BENZENE DERIVATIVE; CARBON; FLUORINE; FLUORINE DERIVATIVE; HYDROGEN; METAL; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; TRANSITION ELEMENT; FLUOROBENZENE; LIGAND; ORGANOMETALLIC COMPOUND; RHODIUM;

ADDITION REACTION; ARTICLE; CALCULATION; CHEMICAL BOND; CHEMICAL STRUCTURE; COORDINATION; DENSITY FUNCTIONAL THEORY; ENERGY; ENERGY TRANSFER; SUBSTITUTION REACTION; CHEMISTRY; OXIDATION REDUCTION REACTION; THERMODYNAMICS;

BENZENE; FLUOROBENZENES; LIGANDS; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; RHODIUM; THERMODYNAMICS;

EID: 67650531384     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja901640m     Document Type: Article

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