Manganese cluster in photosynthesis: Where plants oxidize water to dioxygen

Chemical Reviews

Volumn 96, Issue 7, 1996, Pages 2927-2950

  Yachandra, Vittal K ^a   Sauer, Kenneth ^a,b   Klein, Melvin P ^a  

^a LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0040070502     PISSN: 00092665     EISSN: None     Source Type: Journal    
DOI: 10.1021/cr950052k     Document Type: Article

References (200)

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112. For reviews of the Mn-O/N distances in multinuclear Mn complexes see refs 1b and 9 and references therein.(a) Wieghardt, K.; Bossek, U.; Ventur, D.; Weiss, J. J. Chem. Soc., Chem. Commun. 1985, 347-349. (b) Vincent, J. B.; Chang, H.-R.; Folting, K.; Huffman, J. C.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1987, 109, 5703-5711. (c) Christou, G.; Vincent, J. B. Metal Clusters in Proteins; Que, L., Ed; ACS Symp. Ser. 372; American Chemical Society: Washington, DC, 1988; pp 238-255. (d) Auger, N.; Girerd, J.-J.; Corbella, M.; Gleizes, A.; Zimmermann, J.-L. J. Am. Chem. Soc. 1990, 112, 448-450. (e) Vincent, J. B.; Christmas, C.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 236-238. (f) Wang, S.; Folting, K.; Streib, W. E.; Schmitt, E. A.; McCusker, J. K.; Hendrickson, D. N.; Christou, G. Angew. Chem., Int. Ed. Engl. 1991, 30 , 305-306.
113. For reviews of the Mn-O/N distances in multinuclear Mn complexes see refs 1b and 9 and references therein.(a) Wieghardt, K.; Bossek, U.; Ventur, D.; Weiss, J. J. Chem. Soc., Chem. Commun. 1985, 347-349. (b) Vincent, J. B.; Chang, H.-R.; Folting, K.; Huffman, J. C.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1987, 109, 5703-5711. (c) Christou, G.; Vincent, J. B. Metal Clusters in Proteins; Que, L., Ed; ACS Symp. Ser. 372; American Chemical Society: Washington, DC, 1988; pp 238-255. (d) Auger, N.; Girerd, J.-J.; Corbella, M.; Gleizes, A.; Zimmermann, J.-L. J. Am. Chem. Soc. 1990, 112, 448-450. (e) Vincent, J. B.; Christmas, C.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 236-238. (f) Wang, S.; Folting, K.; Streib, W. E.; Schmitt, E. A.; McCusker, J. K.; Hendrickson, D. N.; Christou, G. Angew. Chem., Int. Ed. Engl. 1991, 30 , 305-306.
114. For reviews of the Mn-O/N distances in multinuclear Mn complexes see refs 1b and 9 and references therein.(a) Wieghardt, K.; Bossek, U.; Ventur, D.; Weiss, J. J. Chem. Soc., Chem. Commun. 1985, 347-349. (b) Vincent, J. B.; Chang, H.-R.; Folting, K.; Huffman, J. C.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1987, 109, 5703-5711. (c) Christou, G.; Vincent, J. B. Metal Clusters in Proteins; Que, L., Ed; ACS Symp. Ser. 372; American Chemical Society: Washington, DC, 1988; pp 238-255. (d) Auger, N.; Girerd, J.-J.; Corbella, M.; Gleizes, A.; Zimmermann, J.-L. J. Am. Chem. Soc. 1990, 112, 448-450. (e) Vincent, J. B.; Christmas, C.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 236-238. (f) Wang, S.; Folting, K.; Streib, W. E.; Schmitt, E. A.; McCusker, J. K.; Hendrickson, D. N.; Christou, G. Angew. Chem., Int. Ed. Engl. 1991, 30 , 305-306.
115. For reviews of the Mn-O/N distances in multinuclear Mn complexes see refs 1b and 9 and references therein.(a) Wieghardt, K.; Bossek, U.; Ventur, D.; Weiss, J. J. Chem. Soc., Chem. Commun. 1985, 347-349. (b) Vincent, J. B.; Chang, H.-R.; Folting, K.; Huffman, J. C.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1987, 109, 5703-5711. (c) Christou, G.; Vincent, J. B. Metal Clusters in Proteins; Que, L., Ed; ACS Symp. Ser. 372; American Chemical Society: Washington, DC, 1988; pp 238-255. (d) Auger, N.; Girerd, J.-J.; Corbella, M.; Gleizes, A.; Zimmermann, J.-L. J. Am. Chem. Soc. 1990, 112, 448-450. (e) Vincent, J. B.; Christmas, C.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 236-238. (f) Wang, S.; Folting, K.; Streib, W. E.; Schmitt, E. A.; McCusker, J. K.; Hendrickson, D. N.; Christou, G. Angew. Chem., Int. Ed. Engl. 1991, 30 , 305-306.
116. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
117. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
118. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
119. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
120. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
121. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
122. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
123. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
124. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
125. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
126. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
127. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
128. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r)
129. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
130. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
131. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
132. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
133. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
134. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
135. For comprehensive reviews of the Mn-Mn distances in multinuclear Mn complexes see refs 1b and 9 and references therein. Also see (ref 43). A representative, but not a complete, list of references is listed here, (a) Stebler, M.; Ludi, A.; Burgi, H.-B. Inorg. Chem. 1986, 25, 4743-4750. (b) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G., Blondin, G.; Girerd, J. J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651-653. (c) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398-7411. (d) Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H.-R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1987, 1303-1305. (e) Bashkin, J. S.; Chang, H.-R.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1987, 109, 6502-6504. (f) Sheats, J. E.; Czernuszewicz, R. S.; Dismukes, G. C.; Rheingold, A. L.; Petrouleas, V.; Stubbe, J.; Armstrong, W. H.; Beer, R. H.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 1435-1444. (g) Wieghardt, K.; Bossek., U.; Bonvoisin, J.; Beauvillain, P.; Girerd, J.-J.; Nuber, B.; Weiss, J.; Heinze, J. Angew. Chem. 1986, 98, 1026-1027. (h) Wieghardt, K.; Bossek, U.; Gebert, W. Angew. Chem. 1983, 95, 320 (i) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967-969. (j) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc., Chem. Commun. 1987, 1659-1660. (k) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167-168. (l) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477-480. (m) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606-3608. (n) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037-4040. (o) Brewer, K. J.; Liegeois, A.; Otvos, J. W.; Calvin, M.; Spreer, L. O. J. Chem. Soc., Chem. Commun. 1988, 1219-1220. (p) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763-1766. (q) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503-508. (r) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 28, 4446-4451. (s) Oki, A. R.; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435-2441. (t) Glerup, J.; Goodson, P. A.; Hazell, A.; Hazell, R.; Hodgson, D. J.; McKenzie, C. J.; Michelsen, K.; Rychlewska, U.; Toftlund. Inorg. Chem. 1994, 33, 4105-4111.
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