Mechanistic Details of Pd(II)-Catalyzed C-H Iodination with Molecular I2: Oxidative Addition vs Electrophilic Cleavage

Journal of the American Chemical Society

Volumn 137, Issue 28, 2015, Pages 9022-9031

  Haines, Brandon E ^a   Xu, Huiying ^a,c   Verma, Pritha ^b   Wang, Xiao Chen ^b   Yu, Jin Quan ^b   Musaev, Djamaladdin G ^a  

^a EMORY UNIVERSITY   (United States)

^b SCRIPPS RESEARCH INSTITUTE   (United States)

^c SUN YAT SEN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYSTS; HALOGENATION; IODINE; METAL HALIDES; OXIDANTS; PALLADIUM COMPOUNDS; TRANSITION METALS;

ACTIVE CATALYST; CHEMICAL EQUATIONS; DIRECTING GROUPS; ELECTROPHILES; EXPERIMENTAL CONDITIONS; FUNCTIONALIZED; MOLECULAR BROMINE; OXIDATIVE ADDITIONS;

PALLADIUM;

MONOMER; PALLADIUM; HYDROCARBON; IODINE; OXIDIZING AGENT;

ARTICLE; BROMINATION; CATALYST; COLUMN CHROMATOGRAPHY; CONTROLLED STUDY; COVALENT BOND; DIMERIZATION; DISSOCIATION; ELECTRON; ELECTROPHILICITY; ENTHALPY; ENTROPY; IODINATION; ISOMER; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; OXIDATION REDUCTION REACTION; REACTION ANALYSIS; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; HALOGENATION;

CATALYSIS; HALOGENATION; HYDROCARBONS; IODINE; MODELS, MOLECULAR; OXIDANTS; OXIDATION-REDUCTION; PALLADIUM;

EID: 84937701914     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b03410     Document Type: Article

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