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(a) Zhao, J.; Campo, M.; Larock, R. C. Angew. Chem., Int. Ed. 2005, 44, 1873-1875 and references therein.
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Recent work indicates that this process is rather unlikely: Hughes, C. C.; Trauner, D. Angew. Chem., Int. Ed. 2002, 41, 1569-1572.
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D = 4) was found in the Pd-catalyzed synthesis of oxindoles via C-H functionalization: Hennessy, E. J.; Buchwald, S. L. J. Am. Chem. Soc. 2003, 125, 12084-12085.
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(a) González, J. J.; García, N.; Gómez-Lor, B.; Echavarren, A. M. J. Org. Chem. 1997, 62, 1286-1291.
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31944445988
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note
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(a) See Supporting Information, (b) Phenanthrenes 9a, 9b, 9d, and 9e were also synthesized by Suzuki couplings of 9-bromophenanthrene.
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30
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Huang, X.; Anderson, K. W.; Zim, D.; Jiang, L.; Klapars, A.; Buchwald, S. L. J. Am. Chem. Soc. 2003, 125, 6653-6655.
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Balcells, D.1
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(a) Biswas, B.; Sugimoto, M.; Sakaki, S. Organometallics 2000, 19, 3895-3908.
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(b) See also: Davies, D. L.; Donald, S. M. A.; Macgregor, S. A. J. Am. Chem. Soc. 2005, 127, 13754-13755.
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37
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31944446452
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note
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Neither in TS2 nor in TS3 (nor in TS2′ and TS3′, of the intermolecular pathway) does the phenyl ring present the distribution of Mulliken charges expected for an electrophilic substitution.
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