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Cyclometalated Pd(II) complexes such as 2 are in equilibrium with monometallic Pd(II) complexes bearing an additional ligand. See
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1H NMR spectroscopy using an internal standard
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1H NMR spectroscopy using an internal standard.
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25
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72249109350
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2 was used. The yield of 4 from 3 in the absence of 1 could be increased from 6 to 82% by addition of 20 equiv of pyridine prior to reductive elimination. For details, see the Supporting Information
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2 was used. The yield of 4 from 3 in the absence of 1 could be increased from 6 to 82% by addition of 20 equiv of pyridine prior to reductive elimination. For details, see the Supporting Information.
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