Nano/Micro and Hierarchical Structured Surfaces in Polymer Blends

Nanostructured Polymer Blends

Volumn , Issue , 2013, Pages 357-421

  Rodríguez Hernández, Juan ^a  

^a INSTITUTO DE CIENCIA Y TECNOLOGÍA DE POLÍMEROS   (Spain)

Author keywords

Hierarchically structured blend surfaces; Nano micro surface structures; Phase separation; Polymer blend surfaces; Stimuli responsive nanostructures

Indexed keywords

BLENDING; BLOCK COPOLYMERS; FILM PREPARATION; FUNCTIONAL POLYMERS; PHASE SEPARATION; POLYMER FILMS; SELF ASSEMBLY; STIFFNESS; THERMAL EXPANSION; THIN FILMS; TOPOGRAPHY; TOUGHNESS;

ELECTRICAL CONDUCTIVITY; FREE-SURFACE TOPOGRAPHY; NANOSTRUCTURED SURFACE; PREPARATION CONDITIONS; PROCESSING CONDITION; STIMULI-RESPONSIVE; TEMPERATURE RESPONSIVE POLYMERS; TIME-CONSUMING PROCEDURE;

POLYMER BLENDS;

EID: 84903657267     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1016/B978-1-4557-3159-6.00011-0     Document Type: Chapter

References (309)

1. Bates F.S. Polymer-polymer phase behavior. Science 1991, 251:898-905.
2. Nakanishi H., Fisher M.E. Critical phenomena in fluid films-critical-temperature-shifts. J Phys C: Solid State Phys 1983, 16:L95-L97.
3. Berggren M., Inganas O., Gustafsson G., Rasmusson J., Andersson M.R., Hjertberg T., et al. Light-emitting-diodes with variable colors from polymer blends. Nature 1994, 372:444-446.
4. Halls J.J.M., Walsh C.A., Greenham N.C., Marseglia E.A., Friend R.H., Moratti S.C., et al. Efficient photodiodes from interpenetrating polymer networks. Nature 1995, 376:498-500.
5. Walheim S., Ramstein M., Steiner U. Morphologies in ternary polymer blends after spin-coating. Langmuir 1999, 15:4828-4836.
6. Arias A.C., MacKenzie J.D., Stevenson R., Halls J.J.M., Inbasekaran M., Woo E.P., et al. Photovoltaic performance and morphology of polyfluorene blends: a combined microscopic and photovoltaic investigation. Macromolecules 2001, 34:6005-6013.
7. Sabu T., Gabriel G., Charef H. Micro- and nanostructured polymer blends. Micro- and nanostructured multiphase polymer blend systems 2005, CRC Press, p. 1-42.
8. Krausch G. Surface induced self assembly in thin polymer films. Mater Sci Eng, R 1995, 14:1-94.
9. Binder K. Phase transitions of polymer blends and block copolymer melts in thin films. In: Advances in Polymer Science, vol. 138, Polymers in Confined Environments, 1999; 1-89.
10. Budkowski A. Interfacial phenomena in thin polymer films: phase coexistence and segregation. In: Advances in Polymer Science, vol. 148 Intervaces Crystallization Viscoelasticity, 1999; 1-111.
11. Geoghegan M., Krausch G. Wetting at polymer surfaces and interfaces. Prog Polym Sci 2003, 28:261-302.
12. Moons E. Conjugated polymer blends: linking film morphology to performance of light emitting diodes and photodiodes. J Phys: Condens Matter 2002, 14:12235-12260.
13. Gutmann J.S., Muller-Buschbaum P., Stamm M. Complex pattern formation by phase separation of polymer blends in thin films. Faraday Discuss 1999, 112:285-297.
14. Budkowski A., Bernasik A., Cyganik P., Rysz J., Brenn R. Surface-directed phase separation in nanometer polymer films: self-stratification and pattern replication. E-Polymers 2002, 006.
15. Macosko C.W. Morphology development and control in immiscible polymer blends. Macromol Symp 2000, 149:171-184.
16. Puri S., Frisch H.L. Surface-directed spinodal decomposition: modelling and numerical simulations. J Phys: Condens Matter 1997, 9:2109-2133.
17. Kumar S.K., Tang H., Szleifer I. Phase-transitions in thin-films of symmetrical binary polymer mixtures. Mol Phys 1994, 81:867-872.
18. Rouault Y., Baschnagel J., Binder K. Phase-separation of symmetrical polymer mixtures in thin-film geometry. J Stat Phys 1995, 80:1009-1031.
19. Rouault Y., Dunweg B., Baschnagel J., Binder K. Concentration profile near the surface of polymer mixtures: a Monte Carlo study. Polymer 1996, 37:297-304.
20. Binder K. Phase-transitions in Polymer blends and block-copolymer melts - some recent developments. Theories and Mechanism of Phase Transitions, Heterophase Polymerizations, Homopolymerization, Addition Polymerization 1994;112:181-99.
21. Tang H., Szleifer I., Kumar S.K. Critical-temperature shifts in thin polymer blend films. J Chem Phys 1994, 100:5367-5371.
22. Puri S., Binder K., Frisch H.L. Surface effects on spinodal decomposition in binary mixtures: the case with long-ranged surface fields. Phys Rev E 1997, 56:6991-7000.
23. Reich S., Cohen Y. Phase separation of polymer blends in thin films. J Polym Sci, Part A-2 (B): Polym Phys 1981, 19:1255-1267.
24. Nesterov A.E., Lipatov Y.S., Horichko V.V., Gritsenko O.T. Filler effects on the compatibility and phase separation kinetics of poly(vinyl acetate)-poly(methyl methacrylate) mixtures. Polymer 1992, 33:619-622.
25. Ball R.C., Essery R.L.H. Spinodal decomposition and pattern formation near surfaces. J Phys: Condens Matter 1990, 2:10303-10320.
26. Jones R.A.L., Norton L.J., Kramer E.J., Bates F.S., Wiltzius P. Surface-directed spinodal decomposition. Phys Rev Lett 1991, 66:1326-1329.
27. Xue L., Zhang J., Han Y. Phase separation induced ordered patterns in thin polymer blend films. Prog Polym Sci (Oxford) 2012, 37:564-594.
28. Ogawa H., Kanaya T., Nishida K., Matsuba G. Phase separation and dewetting in polystyrene/poly(vinyl methyl ether) blend thin films in a wide thickness range. Polymer 2008, 49:254-262.
29. Tanaka K., Takahara A., Kajiyama T. Film thickness dependence of the surface structure of immiscible polystyrene/poly(methyl methacrylate) blends. Macromolecules 1996, 29:3232-3239.
30. Ton-That C., Shard A.G., Teare D.O.H., Bradley R.H. XPS and AFM surface studies of solvent-cast PS/PMMA blends. Polymer 2001, 42:1121-1129.
31. Li X., Han Y., An L. Annealing effects on the surface morphologies of thin PS/PMMA blend films with different film thickness. Appl Surf Sci 2004, 230:115-124.
32. Wang H., Composto R.J. Wetting and phase separation in polymer blend films: identification of four thickness regimes with distinct morphological pathways. Interface Sci 2003, 11:237-248.
33. Tanaka K., Yoon J.S., Takahara A., Kajiyama T. Ultrathinning-induced surface phase separation of polystyrene/poly(vinyl methyl ether) blend film. Macromolecules 1995, 28:934-938.
34. Walheim S., Böltau M., Mlynek J., Krausch G., Steiner U. Structure formation via polymer demixing in spin-cast films. Macromolecules 1997, 30:4995-5003.
35. Affrossman S., O'Neill S.A., Stamm M. Topography and surface composition of thin films of blends of polystyrene with brominated polystyrenes: effects of varying the degree of bromination and annealing. Macromolecules 1998, 31:6280-6288.
36. Slep D., Asselta J., Rafailovich M.H., Sokolov J., Winesett D.A., Smith A.P., et al. Phase separation of polystyrene and bromo-polystyrene mixtures in equilibrium structures in thin films. Langmuir 1998, 14:4860-4864.
37. Raczkowska J., Rysz J., Budkowski A., Lekki J., Lekka M., Bernasik A., et al. Surface patterns in solvent-cast polymer blend films analyzed with an integral-geometry approach. Macromolecules 2003, 36:2419-2427.
38. Jones R.A.L., Kramer E.J., Rafailovich M.H., Sokolov J., Schwarz S.A. Surface enrichment in an isotopic polymer blend. Phys Rev Lett 1989, 62:280-283.
39. Gutmann J.S., Müller-Buschbaum P., Schubert D.W., Stribeck N., Stamm M. Influence of the blend compatibility on the morphology of thin polymer blend films. J Macromol Sci, Phys 1999, 38.
40. Affrossman S., Henn G., O'Neill S.A., Pethrick R.A., Stamm M. Surface topography and composition of deuterated polystyrene-poly(bromostyrene) blends. Macromolecules 1996, 29:5010-5016.
41. Raczkowska J., Bernasik A., Budkowski A., Sajewicz K., Penc B., Lekki J., et al. Structures formed in spin-cast films of polystyrene blends with poly(butyl methacrylate) isomers. Macromolecules 2004, 37:7308-7315.
42. Genzer J., Composto R.J. Effect of molecular weight on the interfacial excess, tension, and width in a homopolymer/binary polymer blend system. Macromolecules 1998, 31:870-878.
43. Cyganik P., Budkowski A., Raczkowska J., Postawa Z. AFM/LFM surface studies of a ternary polymer blend cast on substrates covered by a self-assembled monolayer. Surface Science 2002, 507-510:700-706.
44. Hariharan A., Kumar S.K., Russell T.P. Surface segregation in binary polymer mixtures: a lattice model. Macromolecules 1991, 24:4909-4917.
45. Zhao X., Zhao W., Sokolov J., Rafailovich M.H., Schwarz S.A., Wilkens B.J., et al. Determination of the concentration profile at the surface of d-PS/h-PS blends using high-resolution ion scattering techniques. Macromolecules 1991, 24:5991-5996.
46. Li X., Han Y., An L. Surface morphology control of immiscible polymer-blend thin films. Polymer 2003, 44:8155-8165.
47. Müller-Buschbaum P., Gutmann J.S., Stamm M. Influence of blend composition on phase separation and dewetting of thin polymer blend films. Macromolecules 2000, 33:4886-4895.
48. Yao L., Xuming X., Qi Z., Liming T. Formation of cylindrical phase structure in PMMA/HBP polymer blend films. Polymer 2005, 46:12004-12009.
49. Ton-That C., Shard A.G., Bradley R.H. Surface feature size of spin cast PS/PMMA blends. Polymer 2002, 43:4973-4977.
50. Ton-That C., Shard A.G., Daley R., Bradley R.H. Effects of annealing on the surface composition and morphology of PS/PMMA blend. Macromolecules 2000, 33:8453-8459.
51. Hopkinson I., Myatt M. Phase separation in ternary polymer solutions induced by solvent loss. Macromolecules 2002, 35:5153-5160.
52. Schmidt J.J., Gardella J.A., Salvati L. Surface studies of polymer blends. 2. An ESCA and IR study of poly(methyl methacrylate)/poly(vinyl chloride) homopolymer blends. Macromolecules 1989, 22:4489-4495.
53. Müller-Buschbaum P., Gutmann J.S., Wolkenhauer M., Kraus J., Stamm M., Smilgies D., et al. Solvent-induced surface morphology of thin polymer films. Macromolecules 2001, 34:1369-1375.
54. Strawhecker K.E., Kumar S.K., Douglas J.F., Karim A. The critical role of solvent evaporation on the roughness of spin-cast polymer films [1]. Macromolecules 2001, 34:4669-4672.
55. Cui L., Ding Y., Li X., Wang Z., Han Y. Solvent and polymer concentration effects on the surface morphology evolution of immiscible polystyrene/poly(methyl methacrylate) blends. Thin Solid Films 2006, 515:2038-2048.
56. Kumacheva E., Li L., Winnik M.A., Shinozaki D.M., Cheng P.C. Direct imaging of surface and bulk structures in solvent cast polymer blend films. Langmuir 1997, 13:2483-2488.
57. Huraux K., Narita T., Frétigny C., Lequeux F. Solution drying and phase separation morphology of polyacrylamide/ polyethylene glycol/water system. Macromolecules 2007, 40:8336-8341.
58. Matsushita Y., Furukawa H., Okada M. Crystal-like pattern formation in polymerization-induced phase separation. Phys Rev E: Stat Nonlinear Soft Matter Phys 2004, 70:40501-40513.
59. Tanaka H., Lovinger A.J., Davis D.D. Pattern evolution caused by dynamic coupling between wetting and phase separation in binary liquid mixture containing glass particles. Phys Rev Lett 1994, 72:2581-2584.
60. Steiner U., Klein J., Eiser E., Budkowski A., Fetters L.J. Complete wetting from polymer mixtures. Science 1992, 258:1126-1129.
61. Reiter G. Dewetting of thin polymer-films. Phys Rev Lett 1992, 68:75-78.
62. Lambooy P., Phelan K.C., Haugg O., Krausch G. Dewetting at the liquid-liquid interface. Phys Rev Lett 1996, 76:1110-1113.
63. Binder K. Collective diffusion, nucleation, and spinodal decomposition in polymer mixtures. J Chem Phys 1983, 79:6387-6409.
64. Nakanishi H., Fisher M.E. Critical-point shifts in films. J Chem Phys 1983, 78:3279-3293.
65. Li H., Paczuski M., Kardar M., Huang K. Surface ordering and finite-size effects in liquid-crystal films. Phys Rev B 1991, 44:8274-8283.
66. Wu Y.N., Alexander F.J., Lookman T., Chen S.Y. Effects of hydrodynamics on phase-transition kinetics in 2-dimensional binary fluids. Phys Rev Lett 1995, 74:3852-3855.
67. Miguel M.S., Grant M., Gunton J.D. Phase-separation in 2-dimensional binary fluids. Phys Rev A 1985, 31:1001-1005.
68. Bray A.J. Theory of phase-ordering kinetics. Adv Phys 1994, 43:357-459.
69. Furukawa H.A. Dynamic scaling assumption for phase-separation. Adv Phys 1985, 34:703-750.
70. Muller-Buschbaum P., O'Neill S.A., Affrossman S., Stamm M. Phase separation and dewetting of weakly incompatible polymer blend films. Macromolecules 1998, 31:5003-5009.
71. Sprenger M., Walheim S., Budkowski A., Steiner U. Hierarchic structure formation in binary and ternary polymer blends. Interface Sci 2003, 11:225-235.
72. De Gennes P.G. Instabilities during the evaporation of a film: non-glassy polymer+volatile solvent. Eur Phys J E 2001, 6:421-424.
73. Mitov Z., Kumacheva E. Convection-induced patterns in phase-separating polymeric fluids. Phys Rev Lett 1998, 81:3427-3430.
74. Li M.Q., Xu S.Q., Kumacheva E. Convection in polymeric fluids subjected to vertical temperature gradients. Macromolecules 2000, 33:4972-4978.
75. Budkowski A., Bernasik A., Cyganik P., Raczkowska J., Penc B., Bergues B., et al. Substrate-determined shape of free surface profiles in spin-cast polymer blend films. Macromolecules 2003, 36:4060-4067.
76. Lawrence C.J. The mechanics of spin coating of polymer-films. Phys Fluids 1988, 31:2786-2795.
77. Affrossman S., Jerome R., O'Neill S.A., Schmitt T., Stamm M. Surface structure of thin film blends of polystyrene and poly(n-butyl methacrylate). Colloid Polym Sci 2000, 278:993-999.
78. Chen C., Wang J., Woodcock S.E., Chen Z. Surface morphology and molecular chemical structure of poly(n-butyl methacrylate)/polystyrene blend studied by atomic force microscopy (AFM) and sum frequency generation (SFG) vibrational spectroscopy. Langmuir 2002, 18:1302-1309.
79. Gutmann J.S., Muller-Buschbaum P., Schubert D.W., Stribeck N., Stamm M. Influence of the blend compatibility on the morphology of thin polymer blend films. J Macromol Sci, Phys 1999, B38:563-576.
80. Muller-Buschbaum P., Gutmann J.S., Stamm M. Control of surface morphology by the interplay between phase separation and dewetting. J Macromol Sci, Phys 1999, B38:577-592.
81. Dalnoki-Veress K., Forrest J.A., Stevens J.R., Dutcher J.R. Phase separation morphology of thin films of polystyrene/polyisoprene blends. J Polym Sci, Part B: Polym Phys 1996, 34:3017-3024.
82. DalnokiVeress K., Forrest J.A., Stevens J.R., Dutcher J.R. Phase separation morphology of spin-coated polymer blend thin films. Physica A 1997, 239:87-94.
83. Cyganik P., Bernasik A., Budkowski A., Bergues B., Kowalski K., Rysz J., et al. Phase decomposition in polymer blend films cast on substrates patterned with self-assembled monolayers. Vacuum 2001, 63:307-313.
84. Boltau M., Walheim S., Mlynek J., Krausch G., Steiner U. Surface-induced structure formation of polymer blends on patterned substrates. Nature 1998, 391:877-879.
85. Cyganik P., Budkowski A., Steiner U., Rysz J., Bernasik A., Walheim S., et al. Substructure formation during pattern transposition from substrate into polymer blend film. Europhys Lett 2003, 62:855-861.
86. Müller-Buschbaum P., Stamm M. Film thickness dependence of the domain size in weakly incompatible thin polymer blend films. Colloid Polym Sci 2001, 279:376-381.
87. Gutmann J.S., Müller-Buschbaum P., Stamm M. Film-thickness dependence of structure formation in ultra-thin polymer blend films. Appl Phys A: Mater Trans B 2002, 74:S463-S465.
88. Mareau V.H., Prud'homme R.E. Growth rates and morphologies of miscible PCL/PVC blend thin and thick films. Macromolecules 2003, 36:675-684.
89. Meier R., Ruderer M.A., Diethert A., Kaune G., Körstgens V., Roth S.V., et al. Influence of film thickness on the phase separation mechanism in ultrathin conducting polymer blend films. J Phys Chem B 2011, 115:2899-2909.
90. You J., Shi T., Liao Y., Li X., Su Z., An L. Temperature dependence of surface composition and morphology in polymer blend film. Polymer 2008, 49:4456-4461.
91. Keblinski P., Kumar S.K., Maritan A., Koplik J., Banavar J.R. Interfacial roughening induced by phase separation. Phys Rev Lett 1996, 76:1106-1109.
92. Muller-Buschbaum P., Gutmann J.S., Stamm M., Cubitt R., Cunis S., von Krosigk G., et al. Dewetting of thin polymer-blend films examined with GISAS. Physica B 2000, 283:53-59.
93. Ogawa H., Kanaya T., Nshida K., Matsuba G. Composition fluctuations before dewetting in polystyrene/poly(vinyl methyl ether) blend thin films. Polymer 2008, 49:2553-2559.
94. Clarke N. Toward a model for pattern formation in ultrathin-film binary mixtures. Macromolecules 2005, 38:6775-6778.
95. Oron M., Kerle T., Yerushalmi-Rozen R., Klein J. Persistent droplet motion in liquid-liquid dewetting. Phys Rev Lett 2004, 92:236104.
96. Yerushalmi-Rozen R., Kerle T., Klein J. Alternative dewetting pathways of thin liquid films. Science 1999, 285:1254-1256.
97. Liao Y.G., Su Z.H., Sun Z.Y., Shi T.F., An L.J. Dewetting and phase behaviors for ultrathin films of polymer blend. Macromol Rapid Commun 2006, 27:351-355.
98. You J., Hu S., Liao Y., Song K., Men Y., Shi T., et al. Composition effect on dewetting of ultrathin films of miscible polymer blend. Polymer 2009, 50:4745-4752.
99. You J., Liao Y., Men Y., Shi T., An L., Li X. Composition effect on interplay between phase separation and dewetting in PMMA/SAN blend ultrathin films. Macromolecules 2011, 44:5318-5325.
100. El-Mabrouk K., Belaiche M., Bousmina M. Phase separation in PS/PVME thin and thick films. J Colloid Interface Sci 2007, 306:354-367.
101. Liao Y., You J., Shi T., An L., Dutta P.K. Phase behavior and dewetting for polymer blend films studied by in situ AFM and XPS: from thin to ultrathin films. Langmuir 2007, 23:11107-11111.
102. You J., Liao Y., Men Y., Shi T., An L. Film thickness dependence of phase separation and dewetting behaviors in PMMA/SAN blend films. Langmuir 2010, 26:14530-14534.
103. Chung H.J., Composto R.J. Breakdown of dynamic scaling in thin film binary liquids undergoing phase separation. Phys Rev Lett 2004, 92.
104. Chung H.J., Wang H., Composto R.J. A morphology map based on phase evolution in polymer blend films. Macromolecules 2006, 39:153-161.
105. Wang H., Composto R.J. Hydrodynamic-flow-driven wetting in thin film polymer blends: growth kinetics and morphology. Physical Review E 2000, 61:1659-1663.
106. Wang H., Composto R.J. Understanding morphology evolution and roughening in phase-separating thin-film polymer blends. Europhys Lett 2000, 50:622-627.
107. Wang H., Composto R.J. Thin film polymer blends undergoing phase separation and wetting: identification of early, intermediate, and late stages. J Chem Phys 2000, 113:10386-10397.
108. El Mabrouk K., Bousmina M. Effect of hydrodynamics on dynamics of phase separation in polystyrene/poly(vinyl methyl ether) blend. Polymer 2005, 46:9005-9014.
109. Ogawa H., Kanaya T., Nishida K., Matsuba G., Majewski J.P., Watkins E. Time-resolved specular and off-specular neutron reflectivity measurements on deuterated polystyrene and poly(vinyl methyl ether) blend thin films during dewetting process. J Chem Phys 2009, 131.
110. Thomas K.R., Clarke N., Poetes R., Morariu M., Steiner U. Wetting induced instabilities in miscible polymer blends. Soft Matter 2010, 6:3517-3523.
111. Sharma A., Mittal J., Verma R. Instability and dewetting of thin films induced by density variations. Langmuir 2002, 18:10213-10220.
112. Ma M., He Z., Yang J., Chen F., Wang K., Zhang Q., et al. Effect of film thickness on morphological evolution in dewetting and crystallization of polystyrene/poly(epsilon-caprolactone) blend films. Langmuir 2011, 27:13072-13081.
113. Xue L., Han Y. Inhibition of dewetting of thin polymer films. Prog Mater Sci 2012, 57:947-979.
114. Kargupta K., Sharma A. Dewetting of thin films on periodic physically and chemically patterned surfaces. Langmuir 2002, 18:1893-1903.
115. Chen X.-C., Li H.-M., Fang F., Wu Y.-W., Wang M., Ma G.-B., et al. Confinement-induced ordering in dewetting and phase separation of polymer blend films. Adv Mater 2012, 24:2637-2641.
116. Chen D., Zhao W., Wei D., Russell T.P. Dewetting on curved interfaces: a simple route to polymer nanostructures. Macromolecules 2011, 44:8020-8027.
117. de Gennes P.G. Instabilities during the evaporation of a film: non-glassy polymer plus volatile solvent. Eur Phys J E 2001, 6:421-424.
118. Heriot S.Y., Jones R.A.L. An interfacial instability in a transient wetting layer leads to lateral phase separation in thin spin-cast polymer-blend films. Nat Mater 2005, 4:782-786.
119. Bodenschatz E., Pesch W., Ahlers G. Recent developments in Rayleigh-Benard convection. Annu Rev Fluid Mech 2000, 32:709-778.
120. Vanhook S.J., Schatz M.F., Swift J.B., McCormick W.D., Swinney H.L. Long-wavelength surface-tension-driven Benard convection: experiment and theory. J Fluid Mech 1997, 345:45-78.
121. Cui L., Wang H.F., Ding Y., Han Y.C. Tunable ordered droplets induced by convection in phase-separating P2VP/PS blend film. Polymer 2004, 45:8139-8146.
122. Sakurai S., Furukawa C., Okutsu A., Miyoshi A., Nomura S. Control of mesh pattern of surface corrugation via rate of solvent evaporation in solution casting of polymer film in the presence of convection. Polymer 2002, 43:3359-3364.
123. Tanaka K., Yoon J.-S., Takahara A., Kajiyama T. Ultrathinning-induced surface phase separation of polystyrene/poly(vinyl methyl ether) blend film. Macromolecules 1995, 28:934-938.
124. Bruder F., Brenn R. Spinodal decomposition in thin-films of a polymer blend. Phys Rev Lett 1992, 69:624-627.
125. Kajiyama T., Tanaka K., Ohki I., Ge S.R., Yoon J.S., Takahara A. Imaging of dynamic viscoelastic properties of a phase-separated polymer surface by forced oscillation atomic-force microscopy. Macromolecules 1994, 27:7932-7934.
126. Steiner U., Klein J., Fetters L.J. Surface phase inversion in finite-sized binary-mixtures. Phys Rev Lett 1994, 72:1498-1501.
127. Krausch G., Dai C.A., Kramer E.J., Marko J.F., Bates F.S. Interference of spinodal waves in thin polymer-films. Macromolecules 1993, 26:5566-5571.
128. Katzen D., Reich S. Image-analysis of phase-separation in polymers blends. Europhys Lett 1993, 21:55-60.
129. Karim A., Slawecki T.M., Kumar S.K., Douglas J.F., Satija S.K., Han C.C., et al. Phase-separation-induced surface patterns in thin polymer blend films. Macromolecules 1998, 31:857-862.
130. Kawaguchi D., Tanaka K., Torikai N., Takahara A., Kajiyama T. Surface and interfacial segregation in blends of polystyrene with functional end groups and deuterated polystyrene. Langmuir 2007, 23:7269-7275.
131. Affrossman S., Bertrand P., Hartshorne M., Kiff T., Leonard D., Pethrick R.A., et al. Surface segregation in blends of polystyrene and perfluorohexane double end capped polystyrene studied by static SIMS, ISS, and XPS. Macromolecules 1996, 29:5432-5437.
132. Geoghegan M., Jones R.A.L., Sivia D.S., Penfold J., Clough A.S. Experimental study of surface segregation and wetting in films of a partially miscible polymer blend. Phys Rev E: Stat Phys, Plasmas, Fluids 1996, 53:825-837.
133. Schaub T.F., Kellogg G.J., Mayes A.M., Kulasekere R., Ankner J.F., Kaiser H. Surface modification via chain end segregation in polymer blends. Macromolecules 1996, 29:3982-3990.
134. Karim A., Douglas J.F., Lee B.P., Glotzer S.C., Rogers J.A., Jackman R.J., et al. Phase separation of ultrathin polymer-blend films on patterned substrates. Phys Rev E: Stat Phys, Plasmas, Fluids 1998, 57:R6273-R6276.
135. Ermi B.D., Nisato G., Douglas J.F., Rogers J.A., Karim A. Coupling between phase separation and surface deformation modes in self-organizing polymer blend films. Phys Rev Lett 1998, 81:3900-3903.
136. Nisato G., Ermi B.D., Douglas J.F., Karim A. Excitation of surface deformation modes of a phase-separating polymer blend on a patterned substrate. Macromolecules 1999, 32:2356-2364.
137. Rockford L., Liu Y., Mansky P., Russell T.P., Yoon M., Mochrie S.G.J. Polymers on nanoperiodic, heterogeneous surfaces. Phys Rev Lett 1999, 82:2602-2605.
138. Fukunaga K., Elbs H., Krausch G. Thin film phase separation on a nanoscopically patterned substrate. Langmuir 2000, 16:3474-3477.
139. Composto R.J., Stein R.S., Kramer E.J., Jones R.A.L., Mansour A., Karim A., et al. Surface enrichment in polymer blends - A neutron reflection test. Physica B: Physics of Condensed Matter 1989, 156-157:434-436.
140. Sokolov J., Rafailovich M.H., Jones R.A.L., Kramer E.J. Enrichment depth profiles in polymer blends measured by forward recoil spectrometry. Appl Phys Lett 1989, 54:590-592.
141. Cifra P., Bruder F., Brenn R. Surface segregation in a polymer blend. Comparison between Monte Carlo simulation and mean-field theory. J Chem Phys 1993, 99:4121-4127.
142. Hariharan A., Kumar S.K., Russell T.P. Reversal of the isotopic effect in the surface behavior of binary polymer blends. J Chem Phys 1993, 98:4163-4173.
143. Hariharan A., Kumar S.K., Russell T.P. Free surfaces of polymer blends. I. Theoretical framework and application to symmetric polymer blends. J Chem Phys 1993, 98:6516-6525.
144. Hariharan A., Kumar S.K., Russell T.P. Free surfaces of polymer blends. II. Effects of molecular weight and applications to asymmetric polymer blends. J Chem Phys 1993, 99:4041-4050.
145. Hariharan A., Kumar S.K., Rafailovich M.H., Sokolov J., Zheng X., Duong D., et al. The effect of finite film thickness on the surface segregation in symmetric binary polymer mixtures. J Chem Phys 1993, 99:656-663.
146. Genzer J., Faldi A., Composto R.J. Self-consistent mean-field calculation of surface segregation in a binary polymer blend. Phys Rev E 1994, 50:2373-2376.
147. Luzinov I., Minko S., Tsukruk V.V. Adaptive and responsive surfaces through controlled reorganization of interfacial polymer layers. Prog Polym Sci 2004, 29(7):635-698.
148. Russell T.P. Surface-responsive materials. Science 2002, 297(5583):964-967.
149. Foster M.D., Greenberg C.C., Teale D.M., Turner C.M., Corona-Galvan S., Cloutet E., et al. Effective x and surface segregation in blends of star and linear polystyrene. Macromol Symp 2000, 149:263-268.
150. Muisener P.A.V.O.R., Jalbert C.A., Yuan C., Baetzold J., Mason R., Wong D., et al. Measurement and modeling of end group concentration depth profiles for omega-fluorosilane polystyrene and its blends. Macromolecules 2003, 36(8):2956-2966.
151. Lee J.S., Quirk R.P., Foster M.D., Hammouda B., Majkrzak C.F. Surface segregation and bulk thermodynamics in blends of linear and highly branched polymers. Polym Prep 2005, 46:479-480.
152. Cho D., Hu W., Koberstein J.T., Lingelser J.P., Gallot Y. Segregation dynamics of block copolymers to immiscible polymer blend interfaces. Macromolecules 2000, 33:5245-5251.
153. Shull K.R., Kramer E.J., Hadziioannou G., Tang W. Segregation of block copolymers to interfaces between immiscible homopolymers. Macromolecules 1990, 23:4780-4787.
154. Shull KR, Kramer EJ, Hadziioannou G, Wing T. Segregation of block copolymers to interfaces between immiscible homopolymers. 1990;681-85.
155. Ouhadi T., Fayt R., Jerome R., Teyssie P. Molecular design of multicomponent polymer systems: emulsifying effect of poly(alpha-methylstyrene-b-methyl methacrylate) in poly(vinylidene fluoride)/poly(alpha-methylstyrene) blends. Polym Commun Guildford 1986, 27:212-215.
156. Leibler L. Emulsifying effects of block copolymers in incompatible polymer blends. Makromol Chem Macromol Symp 1988, 16:1-17.
157. Green P.F., Russell T.P. Segregation of low molecular weight symmetric diblock copolymers at the interface of high molecular weight homopolymers. Macromolecules 1991, 24:2931-2935.
158. Fredrickson G.H. Surface ordering phenomena in block copolymer melts. Macromolecules 1987, 20:2535-2542.
159. Anastasiadis S.H., Russell T.P., Satija S.K., Majkrzak C.F. Neutron reflectivity studies of the surface-induced ordering of diblock copolymer films. Phys Rev Lett 1989, 62:1852-1855.
160. Menelle A., Russell T.P., Anastasiadis S.H., Satija S.K., Majkrzak C.F. Ordering of thin diblock copolymer films. Phys Rev Lett 1992, 68:67-70.
161. Iyengar D.R., Perutz S.M., Dai C.-A., Ober C.K., Kramer E.J. Surface segregation studies of fluorine-containing diblock copolymers. Macromolecules 1996, 29:1229-1234.
162. Semenov A.N. Theory of diblock-copolymer segregation to the interface and free surface of a homopolymer layer. Macromolecules 1992, 25:4967-4977.
163. Shard A.G., Davies M.C., Li Y.X., Volland C., Kissel T. XPS and SSIMS analysis revealing surface segregation and short-range order in solid films of block copolymers of PEO and PLGA. Macromolecules 1997, 30:3051-3057.
164. Yokoyama H., Miyamae T., Han S., Ishizone T., Tanaka K., Takahara A., et al. Spontaneously formed hydrophilic surfaces by segregation of block copolymers with water-soluble blocks. Macromolecules 2005, 38:5180-5189.
165. Lin H.C., Wang C.F., Kuo S.W., Tung P.H., Huang C.F., Lin C.H., et al. Effect of intermolecular hydrogen bonding on low-surface-energy material of poly(vinylphenol). J Phys Chem A 2007, 111:3404-3410.
166. Bernasik A., Włodarczyk-Miśkiewicz J., Łuzny W., Kowalski K., Raczkowska J., Rysz J., et al. Lamellar structures formed in spin-cast blends of insulating and conducting polymers. Synth Met 2004, 144:253-257.
167. Geoghegan M., Jones R.A.L., Payne R.S., Sakellariou P., Clough A.S., Penfold J. Lamellar structure in a thin polymer blend film. Polymer 1994, 35:2019-2027.
168. Aitkek J. Breath figures. Nature 1911, 86:516-517.
169. Aitkek J. Breath figures. Nature 1912, 90:619-621.
170. Giltay J.W. Breath figures. Nature 1911, 86:585-586.
171. Rayleigh L. Breath figures. Nature 1911, 86:416-417.
172. Rayleigh L. Breath figures. Nature 1912, 90:436-438.
173. Widawski G., Rawiso M., François B. Self-organized honeycomb morphology of star-polymer polystyrene films. Nature 1994, 369:387-389.
174. Jenekhe S.A., Chen X.L. Self-assembly of ordered microporous materials from rod-coil block copolymers. Science 1999, 283:372-375.
175. Srinivasarao M., Collings D., Philips A., Patel S. Three-dimensionally ordered array of air bubbles in a polymer film. Science 2001, 292:79-83.
176. Bunz U.H.F. Breath figures as a dynamic templating method for polymers and nanomaterials. Adv Mater 2006, 18:973-989.
177. Sun H., Wu L.X. Ordered honeycomb-patterned films via breath figures. Prog Chem 2010, 22:1784-1798.
178. Hernandez-Guerrero M., Stenzel M.H. Honeycomb structured polymer films via breath figures. Polym Chem 2012, 3:563-577.
179. Escale P., Rubatat L., Billon L., Save M. Recent advances in honeycomb-structured porous polymer films prepared via breath figures. Eur Polym J 2012, 48:1001-1025.
180. Ostuni E., Chen C.S., Ingber D.E., Whitesides G.M. Selective deposition of proteins and cells in arrays of microwells. Langmuir 2001, 17:2828-2834.
181. Joannopoulos J.D., Johnson S.G., Winn J.N., Meade R.D. Photonic crystals: molding the flow of light 2008, Princeton University Press. 2nd ed.
182. Yoshida M. Novel thin film with cylindrical nanopores that open and close depending on temperature: first successful synthesis. Macromolecules 1996, 29:8987-8989.
183. Ting S.R.S., Min E.H., Escale P., Save M., Billon L., Stenzel M.H. Lectin recognizable biomaterials synthesized via nitroxide-mediated polymerization of a methacryloyl galactose monomer. Macromolecules 2009, 42:9422-9434.
184. Escalé P., Ting S.R.S., Khoukh A., Rubatat L., Save M., Stenzel M.H., et al. Synthetic route effect on macromolecular architecture: from block to gradient copolymers based on acryloyl galactose monomer using RAFT polymerization. Macromolecules 2011, 44:5911-5919.
185. Cui L., Peng J., Ding Y., Li X., Han Y.C. Ordered porous polymer films via phase separation in humidity environment. Polymer 2005, 46:5334-5340.
186. Cui L., Han Y.C. Honeycomb pattern formation via polystyrene/poly(2-vinylpyridine) phase separation. Langmuir 2005, 21:11085-11091.
187. Cui L., Xuan Y., Li X., Ding Y., Li B.Y., Han Y.C. Polymer surfaces with reversibly switchable ordered morphology. Langmuir 2005, 21:11696-11703.
188. Ge W., Lu C. Hierarchical honeycomb patterns with tunable microstructures: controllable fabrication and application as replication templates. Soft Matter 2011, 7:2790-2796.
189. Madej W., Budkowski A., Raczkowska J., Rysz J. Breath figures in polymer and polymer blend films spin-coated in dry and humid ambience. Langmuir 2008, 24:3517-3524.
190. Gliemann H., Almeida A.T., Petri D.F.S., Schimmel T. Nanostructure formation in polymer thin films influenced by humidity. Surf Interface Anal 2007, 39:1-8.
191. Stenzel-Rosenbaum M.H., Davis T.P., Fane A.G., Chen V. Porous polymer films and honeycomb structures made by the self-organization of well-defined macromolecular structures created by living radical polymerization techniques. Angew Chem Int Ed 2001, 40:3428-3432.
192. Muñoz-Bonilla A., Ibarboure E., Bordege V., Fernandez-Garcia M., Rodriguez-Hernandez J. Fabrication of honeycomb-structured porous surfaces decorated with glycopolymers. Langmuir 2010, 26:8552-8558.
193. de León A.S., Muñoz-Bonilla A., Fernández-García M., Rodríguez-Hernández J. Breath figures method to control the topography and the functionality of polymeric surfaces in porous films and microspheres. J Polym Sci, Part A: Polym Chem 2012, 50:851-859.
194. Yabu H., Shimomura M. Mesoscale pincushions, microrings, and microdots prepared by heating and peeling of self-organized honeycomb-patterned films deposited on a solid substrate. Langmuir 2006, 22:4992-4997.
195. Yabu H., Hirai Y., Shimomura M. Electroless plating of honeycomb and pincushion polymer films prepared by self-organization. Langmuir 2006, 22:9760-9764.
196. Tzanetos N.P., Dracopoulos V., Kallitsis J.K., Deimede V.A. Morphological study of the organization behavior of rod-coil copolymers and their blends in thin solid films. Langmuir 2005, 21:9339-9345.
197. Muñoz-Bonilla A., Ibarboure E., Papon E., Rodriguez-Hernandez J. Self-organized hierarchical structures in polymer surfaces: self-assembled nanostructures within breath figures. Langmuir 2009, 25:6493-6499.
198. de León A.S., del Campo A., Fernández-García M., Rodríguez-Hernández J., Muñoz-Bonilla A. Hierarchically structured multifunctional porous interfaces through water templated self-assembly of ternary systems. Langmuir 2012, 28(25):9978-9987.
199. Wan L.-S., Li Q.-L., Chen P.-C., Xu Z.-K. Patterned biocatalytic films via one-step self-assembly. Chem Commun 2012, 48:4417-4419.
200. de Gennes P.G. Conformations of polymers attached to an interface. Macromolecules 1980, 13:1069-1075.
201. Löwenhaupt B., Steurer A., Hellmann G.P., Gallot Y. Microphases and macrophases in polymer blends with a diblock copolymer. Macromolecules 1994, 27:908-916.
202. Tanaka H., Hasegawa H., Hashimoto T. Ordered structure in mixtures of a block copolymer and homopolymers. 1. Solubilization of low molecular weight homopolymers. Macromolecules 1991, 24:240-251.
203. Tanaka H., Hashimoto T. Ordered structures of block polymer/homopolymer mixtures. 3. Temperature dependence. Macromolecules 1991, 24:5713-5720.
204. Hashimoto T., Tanaka H., Hasegawa H. Ordered structure in mixtures of a block copolymer and homopolymers. 2. Effects of molecular weights of homopolymers. Macromolecules 1990, 23:4378-4386.
205. Winey K.I., Thomas E.L., Fetters L.J. The ordered bicontinuous double-diamond morphology in diblock copolymer/homopolymer blends. Macromolecules 1992, 25:422-428.
206. Winey K.I., Thomas E.L., Fetters L.J. Swelling of lamellar diblock copolymer by homopolymer: influences of homopolymer concentration and molecular weight. Macromolecules 1991, 24:6182-6188.
207. Mayes A.M., Russell T.P., Satija S.K., Majkrzak C.F. Homopolymer distributions in ordered block copolymers. Macromolecules 1992, 25:6523-6531.
208. Leibler L., Orland H., Wheeler J.C. Theory of critical micelle concentration for solutions of block copolymers. J Chem Phys 1983, 79:3550-3557.
209. Shull K.R., Winey K.I., Thomas E.L., Kramer E.J. Segregation of block copolymer micelles to surfaces and interfaces. Macromolecules 1991, 24:2748-2751.
210. Ibarboure E., Bousquet A., Toquer G., Papon E., Rodríguez-Hernández J. Tunable hierarchical assembly on polymer surfaces: combining microphase and macrophase separation in copolymer/homopolymer blends. Langmuir 2008, 24:6391-6394.
211. Mayes A.M., Russell T.P., Deline V.R., Satija S.K., Majkrzak C.F. Block copolymer mixtures as revealed by neutron reflectivity. Macromolecules 1994, 27:7447-7453.
212. Koneripalli N., Levicky R., Bates F.S., Matsen M.W., Satija S.K., Ankner J., et al. Ordering in blends of diblock copolymers. Macromolecules 1998, 31:3498-3508.
213. Orso K.A., Green P.F. Phase behavior of thin film blends of block copolymers and homopolymers: changes in domain dimensions. Macromolecules 1999, 32:1087-1092.
214. Seo Y.-S., Kim K.S., Galambos A., Lammertink R.G.H., Vancso G.J., Sokolov J., et al. Nanowire and mesh conformations of diblock copolymer blends at the air/water interface. Nano Letters 2003, 4:483-486.
215. Smith M.D., Green P.F., Saunders R. Anisochemical homopolymer/diblock copolymer thin film blends. Macromolecules 1999, 32:8392-8398.
216. Jeong U., Ryu D.Y., Kho D.H., Lee D.H., Kim J.K., Russell T.P. Phase behavior of mixtures of block copolymer and homopolymers in thin films and bulk. Macromolecules 2003, 36:3626-3634.
217. Jeong U., Ryu D.Y., Kim J.K., Kim D.H., Wu X., Russell T.P. Precise control of nanopore size in thin film using mixtures of asymmetric block copolymer and homopolymer. Macromolecules 2003, 36:10126-10129.
218. Jeong U., Kim H.C., Rodriguez R.L., Tsai I.Y., Stafford C.M., Kim J.K., et al. Asymmetric block copolymers with homopolymers: routes to multiple length scale nanostructures. Adv Mater 2002, 14:274-276.
219. Jeong U., Ryu D.Y., Kho D.H., Kim J.K., Goldbach J.T., Kim D.H., et al. Enhancement in the orientation of the microdomain in block copolymer thin films upon the addition of homopolymer. Adv Mater 2004, 16:533-536.
220. Xuan Y., Peng J., Cui L., Wang H., Li B., Han Y. Morphology development of ultrathin symmetric diblock copolymer film via solvent vapor treatment. Macromolecules 2004, 37:7301-7307.
221. Peng J., Xuan Y., Wang H.F., Yang Y.M., Li B.Y., Han Y.C. Solvent-induced microphase separation in diblock copolymer thin films with reversibly switchable morphology. J Chem Phys 2004, 120:11163-11170.
222. Peng J., Gao X., Wei Y., Wang H., Li B., Han Y. Controlling the size of nanostructures in thin films via blending of block copolymers and homopolymers. J Chem Phys 2005, 122:114706.
223. Spontak R.J., Fung J.C., Braunfeld M.B., Sedat J.W., Agard D.A., Kane L., et al. Phase behavior of ordered diblock copolymer blends: effect of compositional heterogeneity. Macromolecules 1996, 29:4494-4507.
224. Yamaguchi D., Takenaka M., Hasegawa H., Hashimoto T. Macro- and microphase transitions in binary blends of block copolymers with complementarily asymmetric compositions†. Macromolecules 2001, 34:1707-1719.
225. Sakurai S., Irie H., Umeda H., Nomura S., Lee H.H., Kim J.K. Gyroid structures and morphological control in binary blends of polystyrene-block-polyisoprene diblock copolymers. Macromolecules 1998, 31:336-343.
226. Kane L., Satkowski M.M., Smith S.D., Spontak R.J. Phase behavior and morphological characteristics of compositionally symmetric diblock copolymer blends. Macromolecules 1996, 29:8862-8870.
227. Yamaguchi D., Shiratake S., Hashimoto T. Ordered structure in blends of block copolymers. 5. Blends of lamella-forming block copolymers showing both microphase separation involving unique morphological transitions and macrophase separation. Macromolecules 2000, 33:8258-8268.
228. Yamaguchi D., Bodycomb J., Koizumi S., Hashimoto T. Ordered structure in blends of block copolymers. 4. Location of the short diblock. Macromolecules 1999, 32:5884-5894.
229. Lin E.K., Gast A.P., Shi A.-C., Noolandi J., Smith S.D. Effect of short diblock copolymers at internal interfaces of large diblock copolymer mesophases. Macromolecules 1996, 29:5920-5925.
230. Shi A.-C., Noolandi J. Effects of short diblocks at interfaces of strongly segregated long diblocks. Macromolecules 1994, 27:2936-2944.
231. Shi A.-C., Noolandi J. Binary mixtures of diblock copolymers. Phase diagrams with a new twist. Macromolecules 1995, 28:3103-3109.
232. Seo Y.S., Kim K.S., Galambos A., Lammertink R.G.H., Vancso G.J., Sokolov J., et al. Nanowire and mesh conformations of diblock copolymer blends at the air/water interface. Nano Letters 2004, 4:483-486.
233. Tang C., Lennon E.M., Fredrickson G.H., Kramer E.J., Hawker C.J. Evolution of block copolymer lithography to highly ordered square arrays. Science 2008, 322:429-432.
234. Stuart M.A.C., Huck W.T.S., Genzer J., Muller M., Ober C., Stamm M., et al. Emerging applications of stimuli-responsive polymer materials. Nat Mater 2010, 9:101-113.
235. Xu F.J., Su F.B., Deng S.B., Yang W.T. Novel stimuli-responsive polyelectrolyte brushes. Macromolecules 2010, 43:2630-2633.
236. Bousquet A., Ibarboure E., Teran F.J., Ruiz L., Garay M.T., Laza J.M., et al. PH responsive surfaces with nanoscale topography. J Polym Sci, Part A: Polym Chem 2010, 48:2982-2990.
237. Rodriguez-Hernandez J., Ibarboure E., Papon E. Surface segregation of polypeptide-based block copolymer micelles: an approach to engineer nanostructured and stimuli responsive surfaces. Eur Polym J 2011, 47:2063-2068.
238. Bousquet A., Ibarboure E., Papon E., Labrugère C., Rodríguez-Hernández J. Structured multistimuli-responsive functional polymer surfaces obtained by interfacial diffusion of amphiphilic block copolymers. J Polym Sci, Part A: Polym Chem 2010, 48:1952-1961.
239. Muñoz-Bonilla A., Ibarboure E., Papon E., Rodríguez-Hernández J. Engineering polymer surfaces with variable chemistry and topography. J Polym Sci, Part A: Polym Chem 2009, 47:2262-2271.
240. Martinelli E., Agostini S., Galli G., Chiellini E., Glisenti A., Pettitt M.E., et al. Nanostructured films of amphiphilic fluorinated block copolymers for fouling release application. Langmuir 2008, 24:13138-13147.
241. Bormashenko E., Balter S., Pogreb R., Aurbach D. Single-step technique allowing formation of microscaled thermally stable polymer honeycomb reliefs demonstrating reversible wettability. Polym Adv Technol 2011, 22:94-98.
242. Park H., Kim J.U., Park S. High-throughput preparation of complex multi-scale patterns from block copolymer/homopolymer blend films. Nanoscale 2012, 4:1362-1367.
243. Simionescu B., Bordianu I.E., Aflori M., Doroftei F., Mares M., Patras X., et al. Hierarchically structured polymer blends based on silsesquioxane hybrid nanocomposites with quaternary ammonium units for antimicrobial coatings. Mater Chem Phys 2012, 134:190-199.
244. Geldhauser T., Walheim S., Schimmel T., Leiderer P., Boneberg J. Influence of the relative humidity on the demixing of polymer blends on prepatterned substrates. Macromolecules 2009, 43:1124-1128.
245. Hecht U., Schilz C.M., Stratmann M. Influence of relative humidity during film formation processes on the structure of ultrathin polymeric films. Langmuir 1998, 14:6743-6748.
246. Byun M., Hong S.W., Qiu F., Zou Q., Lin Z. Evaporative organization of hierarchically structured polymer blend rings. Macromolecules 2008, 41:9312-9317.
247. Huang C., Moosmann M., Jin J., Heiler T., Walheim S., Schimmel T. Polymer blend lithography: a versatile method to fabricate nanopatterned self-assembled monolayers. Beilstein Int J Nanotechnol 2012, 3:620-628.
248. Bennett R.D., Miller A.C., Kohen N.T., Hammond P.T., Irvine D.J., Cohen R.E. Strategies for controlling the planar arrangement of block copolymer micelles and inorganic nanoclusters. Macromolecules 2005, 38:10728-10735.
249. Ho P.K.H., Thomas D.S., Friend R.H., Tessler N. All-polymer optoelectronic devices. Science 1999, 285:233-236.
250. Zhang L., Li Y., Sun J., Shen J. Mechanically stable antireflection and antifogging coatings fabricated by the layer-by-layer deposition process and postcalcination. Langmuir 2008, 24:10851-10857.
251. Park M.S., Kim J.K. Broad-band antireflection coating at near-infrared wavelengths by a breath figure. Langmuir 2005, 21:11404-11408.
252. Zhang L., Qiao Z.-A., Zheng M., Huo Q., Sun J. Rapid and substrate-independent layer-by-layer fabrication of antireflection- and antifogging-integrated coatings. J Mater Chem 2010, 20:6125-6130.
253. Walheim S., Schaffer E., Mlynek J., Steiner U. Nanophase-separated polymer films as high-performance antireflection coatings. Science 1999, 283:520-522.
254. Li X., Gao J., Xue L., Han Y. Porous polymer films with gradient-refractive-index structure for broadband and omnidirectional antireflection coatings. Adv Funct Mater 2010, 20:259-265.
255. Li X., Xue L., Han Y. Broadband antireflection of block copolymer/homopolymer blend films with gradient refractive index structures. J Mater Chem 2011, 21:5817-5826.
256. Budkowski A., Zemła J., Moons E., Awsiuk K., Rysz J., Bernasik A., et al. Polymer blends spin-cast into films with complementary elements for electronics and biotechnology. J Appl Polym Sci 2012, 125:4275-4284.
257. Zemła J., Lekka M., Raczkowska J., Bernasik A., Rysz J., Budkowski A. Selective protein adsorption on polymer patterns formed by self-organization and soft lithography. Biomacromolecules 2009, 10:2101-2109.
258. Fukuhira Y., Yabu H., Ijiro K., Shimomura M. Interfacial tension governs the formation of self-organized honeycomb-patterned polymer films. Soft Matter 2009, 5:2037-2041.
259. Hoa M.L.K., Lu M., Zhang Y. Preparation of porous materials with ordered hole structure. Adv Colloid Interface Sci 2006, 121:9-23.
260. Ma H., Hao J. Ordered patterns and structures via interfacial self-assembly: superlattices, honeycomb structures and coffee rings. Chem Soc Rev 2011, 40:5457-5471.
261. Li L., Chen C., Li J., Zhang A., Liu X., Xu B., et al. Robust and hydrophilic polymeric films with honeycomb pattern and their cell scaffold applications. J Mater Chem 2009, 19:2789-2796.
262. Ke B.-B., Wan L.-S., Xu Z.-K. Controllable construction of carbohydrate microarrays by site-directed grafting on self-organized porous films. Langmuir 2010, 26:8946-8952.
263. Munoz-Bonilla A., Ibarboure E., Bordege V., Fernandez-Garcia M., Rodriguez-Hernandez J. Fabrication of honeycomb-structured porous surfaces decorated with glycopolymers. Langmuir 2010, 26:8552-8558.
264. de Leon A.S., Rodriguez-Hernandez J., Cortajarena A.L. Honeycomb patterned surfaces functionalized with polypeptide sequences forrecognition and selective bacterial adhesion. Biomaterials 2013, 34:1453-1460.
265. Qi W., Wu L. Polyoxometalate/polymer hybrid materials: fabrication and properties. Polym Int 2009, 58:1217-1225.
266. Hester J.F., Banerjee P., Mayes A.M. Preparation of protein-resistant surfaces on poly(vinylidene fluoride) membranes via surface segregation. Macromolecules 1999, 32:1643-1650.
267. Jaczewska J., Budkowski A., Bernasik A., Raptis I., Moons E., Goustouridis D., et al. Ordering domains of spin cast blends of conjugated and dielectric polymers on surfaces patterned by soft- and photo-lithography. Soft Matter 2009, 5:234-241.
268. Svanstrom C.M.B., Rysz J., Bernasik A., Budkowski A., Zhang F., Inganas O., et al. Device performance of APFO-3/PCBM solar cells with controlled morphology. Adv Mater 2009, 21:4398-4403.
269. Bjorstrom C.M., Bernasik A., Rysz J., Budkowski A., Nilsson S., Svensson M., et al. Multilayer formation in spin-coated thin films of low-bandgap polyfluorene: PCBM blends. J Phys: Condens Matter 2005, 17:L529-L534.
270. Nilsson S., Bernasik A., Budkowski A., Moons E. Morphology and phase segregation of spin-casted films of Polyfluorene/PCBM blends. Macromolecules 2007, 40:8291-8301.
271. Bjorstrom C.M., Nilsson S., Bernasik A., Budkowski A., Andersson M., Magnusson K.O., et al. Vertical phase separation in spin-coated films of a low bandgap polyfluorene/PCBM blend - Effects of specific substrate interaction. Appl Surf Sci 2007, 253:3906-3912.
272. Jaczewska J., Budkowski A., Bernasik A., Raptis I., Raczkowska J., Goustoruidis D., et al. Humidity and solvent effects in spin-coated polythiophene-polystyrene blends. J Appl Polym Sci 2007, 105:67-79.
273. Jaczewska J., Raptis I., Budkowski A., Goustouridis D., Raczkowska J., Sanopoulou A., et al. Swelling of poly(3-alkylthiophene) films exposed to solvent vapors and humidity: evaluation of solubility parameters. Synth Met 2007, 157:726-732.
274. Jaczewska J., Budkowski A., Bernasik A., Moons E., Rysz J. Polymer vs. solvent diagram of film structures formed in spin-cast poly(3-alkylthiophene) blends. Macromolecules 2008, 41:4802-4810.
275. Raczkowska J., Budkowski A., Rysz J., Czuba P., Lekka M., Bernasik A. Effect of diblock copolymers on the film structure of spin cast polymer blends. Journal of Nanostructured Polymers and Nanocomposites 2005, 1:23-33.
276. Arias A.C. Vertically segregated polymer blends: their use in organic electronics. Polym Rev 2006, 46:103-125.
277. Arias A.C., Corcoran N., Banach M., Friend R.H., MacKenzie J.D., Huck W.T.S. Vertically segregated polymer-blend photovoltaic thin-film structures through surface-mediated solution processing. Appl Phys Lett 2002, 80:1695-1697.
278. Yu G., Heeger A.J. Charge separation and photovoltaic conversion in polymer composites with internal donor-acceptor heterojunctions. J Appl Phys 1995, 78:4510-4515.
279. Yu G., Nishino H., Heeger A.J., Chen T.A., Rieke R.D. Enhanced electroluminescence from semiconducting polymer blends. Synth Met 1995, 72:249-252.
280. Yu G., Gao J., Hummelen J.C., Wudl F., Heeger A.J. Polymer photovoltaic cells-enhanced efficiencies via a network of internal donor-acceptor heterojunctions. Science 1995, 270:1789-1791.
281. Shaheen S.E., Brabec C.J., Sariciftci N.S., Padinger F., Fromherz T., Hummelen J.C. 2.5% efficient organic plastic solar cells. Appl Phys Lett 2001, 78:841-843.
282. Snaith H.J., Arias A.C., Morteani A.C., Silva C., Friend R.H. Charge generation kinetics and transport mechanisms in blended polyfluorene photovoltaic devices. Nano Letters 2002, 2:1353-1357.
283. Halls J.J.M., Arias A.C., MacKenzie J.D., Wu W., Inbasekaran M., Woo E.P., et al. Photodiodes based on polyfluorene composites: influence of morphology. Adv Mater 2000, 12:498-502.
284. Morgado J., Moons E., Friend R.H., Cacialli F. De-mixing of polyfluorene-based blends by contact with acetone: electro- and photo-luminescence probes. Adv Mater 2001, 13:810-814.
285. Morteani A.C., Dhoot A.S., Kim J.S., Silva C., Greenham N.C., Murphy C., et al. Barrier-free electron-hole capture in polymer blend heterojunction light-emitting diodes. Adv Mater 2003, 15:1708-1712.
286. Cina S., Baynes N., Moons E., Friend R.H., Burroughes J.H., Towns C.R., et al. New efficient light-emitting polymer diode for flat-panel display applications 2001, 221-228.
287. Wilkinson C.I., Lidzey D.G., Palilis L.C., Fletcher R.B., Martin S.J., Wang X.H., et al. Enhanced performance of pulse driven small area polyfluorene light emitting diodes. Appl Phys Lett 2001, 79:171-173.
288. Morgado J., Friend R.H., Cacialli F. Improved efficiency of light-emitting diodes based on polyfluorene blends upon insertion of a poly(p-phenylene vinylene) electron-confinement layer. Appl Phys Lett 2002, 80:2436-2438.
289. Corcoran N., Arias A.C., Kim J.S., MacKenzie J.D., Friend R.H. Increased efficiency in vertically segregated thin-film conjugated polymer blends for light-emitting diodes. Appl Phys Lett 2003, 82:299-301.
290. Kim J.S., Ho P.K.H., Murphy C.E., Baynes N., Friend R.H. Nature of non-emissive black spots in polymer light-emitting diodes by in-situ micro-raman spectroscopy. Adv Mater 2002, 14:206-209.
291. Kim J.S., Ho P.K.H., Murphy C.E., Friend R.H. Phase separation in polyfluorene-based conjugated polymer blends: lateral and vertical analysis of blend spin-cast thin films. Macromolecules 2004, 37:2861-2871.
292. Park I.J., Lee S.-B., Choi C.K. Surface properties of the fluorine-containing graft copolymer of poly((perfluoroalkyl)ethyl methacrylate)-g-poly(methyl methacrylate). Macromolecules 1998, 31:7555-7558.
293. Gao L., McCarthy T.J. The "lotus effect" explained: Two reasons why two length scales of topography are important. Langmuir 2006, 22:2966-2967.
294. Lin J.J., Chu C.C., Chiang M.L., Tsai W.C. Manipulating assemblies of high-aspect-ratio clays and fatty amine salts to form surfaces exhibiting a lotus effect. Adv Mater 2006, 18:3248-3252.
295. Schutzius T.M., Bayer I.S., Tiwari M.K., Megaridis C.M. Novel fluoropolymer blends for the fabrication of sprayable multifunctional superhydrophobic nanostructured composites. Ind Eng Chem Res 2011, 50:11117-11123.
296. Tiwari M.K., Bayer I.S., Jursich G.M., Schutzius T.M., Megaridis C.M. Highly liquid-repellent, large-area, nanostructured poly(vinylidene fluoride)/poly(ethyl 2-cyanoacrylate) composite coatings: particle filler effects. ACS Applied Materials & Interfaces 2010, 2:1114-1119.
297. Yang C., Castelvetro V., Bianchi S., Alderighi M., Zhang Y. Hierarchical dual-sized film surface morphologies self-generated from fluorinated binary latex blends boost hydrophobicity and lipophobicity. J Colloid Interface Sci 2012, 378:210-221.
298. Lin D.-J., Lin C.-L., Guo S.-Y. Network nano-porous poly(vinylidene fluoride-co-hexafluoropropene) membranes by nano-gelation assisted phase separation of poly(vinylidene fluoride-co-hexafluoropropene)/poly(methyl methacrylate) blend precursor in toluene. Macromolecules 2012, 45:8824-8832.
299. Rahimpour A., Madaeni S.S., Shockravi A., Ghorbani S. Preparation and characterization of hydrophile nano-porous polyethersulfone membranes using synthesized poly(sulfoxide-amide) as additive in the casting solution. J Membr Sci 2009, 334:64-73.
300. Beltsios K., Athanasiou E., Aidinis C., Kanellopoulos N. Microstructure formation phenomena in phase inversion membranes. J Macromol Sci, Phys 1999, B38:1-25.
301. Yeo H.T., Lee S.T., Han M.J. Role of a polymer additive in casting solution in preparation of phase inversion polysulfone membranes. J Chem Eng Jpn 2000, 33:180-184.
302. Jung B., Yoon J.K., Kim B., Rhee H.W. Effect of molecular weight of polymeric additives on formation, permeation properties and hypochlorite treatment of asymmetric polyacrylonitrile membranes. J Membr Sci 2004, 243:45-57.
303. Guo C., Bailey T.S. Highly distensible nanostructured elastic hydrogels from AB diblock and ABA triblock copolymer melt blends. Soft Matter 2010, 6:4807-4818.
304. Scalfani V.F., Bailey T.S. Access to nanostructured hydrogel networks through photocured body-centered cubic block copolymer melts. Macromolecules 2011, 44:6557-6567.
305. Norris I.D., Shaker M.M., Ko F.K., MacDiarmid A.G. Electrostatic fabrication of ultrafine conducting fibers: polyaniline/polyethylene oxide blends. Synth Met 2000, 114:109-114.
306. MacDiarmid A.G., Jones W.E., Norris I.D., Gao J., Johnson A.T., Pinto N.J., et al. Electrostatically-generated nanofibers of electronic polymers. Synth Met 2001, 119:27-30.
307. Zubia J., Arrue J. Plastic optical fibers: an introduction to their technological processes and applications. Opt Fiber Technol 2001, 7:101-140.
308. van Duijnhoven F., Bastiaansen C. Gradient refractive index polymers produced in a centrifugal field. Adv Mater 1999, 11:567-570.
309. van Duijnhoven F.G.H., Bastiaansen C.W.M. Monomers and polymers in a centrifugal field: a new method to produce refractive-index gradients in polymers. Appl Opt 1999, 38:1008-1014.