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Our dPS/PVME blend films were observed to dewet either when cast on unetched hydrophilic Si or when the blend film (moisture sensitive PVME) was exposed to air for several days.
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85034479748
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w) molecular weights is utilized in the present paper.
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85034466715
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note
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Due to the glassy nature of dPS, the rate of remixing at room temperature is extremely slow and does not significantly affect our AFM measurements.
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-
34
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85034460824
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PhD. Thesis, Penn State University
-
Significant off-specular scattering was only observed after several hours of annealing at 170°C. See Slawecki, T. M., PhD. Thesis, Penn State University, 1995. Thus we believe our NR results provide a reliable estimate of surface segregation. A more detailed study on the temperature and composition dependence of the NR data will be reported separately.
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Slawecki, T.M.1
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85034483353
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note
-
Calibration measurements on thick liquid polymer films and pure polystyrene films show that the friction on the shallow flat regions is almost the same as that of pure liquid PVME while that on the protrusions is a factor of ∼3 higher than that of pure PS.
-
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38
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85034485332
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note
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Since the viscous penetration depth is on the order of centimeters, these measurements probe the full depth of the film.
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39
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