Structures formed in spin-cast films of polystyrene blends with poly(butyl methacrylate) isomers

Macromolecules

Volumn 37, Issue 19, 2004, Pages 7308-7315

  Raczkowska, J ^a   Bernasik, A ^a,b   Budkowski, A ^a   Sajewicz, K ^a   Penc, B ^a   Lekki, J ^c   Lekka, M ^c   Rysz, J ^a   Kowalski, K ^a,b   Czuba, P ^a  

^a JAGIELLONIAN UNIVERSITY   (Poland)

^b AGH UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Poland)

^c INSTITUTE OF NUCLEAR PHYSICS   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMIC FORCE MICROSCOPY; GLASS TRANSITION; ISOMERS; PHASE SEPARATION; POLYSTYRENES; SECONDARY ION MASS SPECTROMETRY; SILICON WAFERS; SURFACE CHEMISTRY; TOLUENE; X RAY PHOTOELECTRON SPECTROSCOPY;

POLYSTYRENE (PS) BLENDS; SPIN-CAST FILMS; SURFACE SEGREGATION;

POLYMER BLENDS;

EID: 4944242223     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma035815h     Document Type: Article

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74. 15 this effect is less important here.
75. A careful inspection of Figure 4a reveals that for low PBMA content this phase, present mainly in well defined dropletlike domains (holes for PS/PnBMA, islands for PS/PtBMA), is additionally distributed elsewhere (e.g., in vertical arrangements - remnants of early stage of interfacial instability in PS/PnBMA layers with φ = 0.30 and 0.40).