Surface modification via chain end segregation in polymer blends

Macromolecules

Volumn 29, Issue 11, 1996, Pages 3982-3990

  Schaub, T F ^a   Kellogg, G J ^a   Mayes, A M ^a   Kulasekere, R ^b   Ankner, J F ^b   Kaiser, H ^b  

^a Massachusetts Institute of Technology Cambridge   (United States)

^b UNIVERSITY OF MISSOURI   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FLUOROCARBONS; FREE ENERGY; MATHEMATICAL MODELS; MOLECULAR WEIGHT; NEUTRON REFLECTION; OLIGOMERS; PLASTIC FILMS; POLYSTYRENES; SURFACE PROPERTIES; SURFACE TENSION; SYNTHESIS (CHEMICAL);

CHAIN END SEGREGATION; CONTACT ANGLE MEASUREMENTS; FREE ENERGY MODEL; OLIGOTETRAFLUOROETHYLENE CHAIN ENDS; SURFACE MODIFICATION;

POLYMER BLENDS;

EID: 0030143141     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9510810     Document Type: Article

References (28)

1. Wu, S. Polymer Interface and Adhesion; Marcel Dekker: New York, 1982.
2. Garbassi, F.; Morra, M.; Occhiello, E. Polymer Surfaces: From Physics to Technology; John Wiley and Sons: New York, 1994.
3. Hunt, M. O.; Belu, A.; Linton, R.; DeSimone, J. M. Macromolecules 1993, 26, 4854.
4. Jalbert, C. J. Ph.D. Thesis, University of Connecticut, 1993.
5. Elman, J. F.; Johs, B. D.; Long, T. E.; Koberstein, J. T. Macromolecules 1994, 27, 5341.
6. Affrossman, S.; Hartshorne, M.; Kiff, T.; Pethrick, R. A.; Richards, R. W. Macromolecules 1994, 27, 1588.
7. Schaub, T. F, SM Thesis, Massachusetts Institute of Technology, Cambridge, MA, 1995.
8. Jalbert, C.; Koberstein, J. T.; Yilgor, I.; Gallagher, P.; Krukonis, V. Macromolecules 1993, 26, 3069.
9. Jalbert, C. J.; Koberstein, J. T.; Balaji, R,; Bhatia, Q.; Salvati, L.; Yilgor, I. Macromolecules 1994, 27, 2409.
10. Fleischer, C. A.; Morales, A. R.; Koberstein, J. T. Macromolecules 1994, 27, 379.
11. Norton, L. J.; Smigolova, V.; Pralle, M. U.; Hubenko, A.; Dai, K. H.; Kramer, E. J.; Hahn, S.; Berglund, C.; DeKoven, B. Macromolecules 1995, 28, 1999.
12. Scott, C. E.; Macosko, C. W. Polymer 1994, 35, 5422.
13. Scott, C.; Macosko, C. J. Polym. Sci., Part B: Polym. Phys. 1994, 32, 205.
14. Chen, X.; Gardella, J. A. Macromolecules 1994, 27, 3363.
15. Hariharan, A.; Kumar, S. K.; Russell, T. P. Macromolecules 1990, 23, 3584.
16. Kaiser, H.; Hamacher, K.; Kulasekere, R.; Lee, W.-T.; Ankner, J. F.; DeFacio, B.; Miceli, P.; Worcester, D. L. Proc. SPIE-Int. Soc. Opt. Eng. 1994, 2241, 78.
17. Russell, T. P. Mater. Sci. Rep. 1990, 5, 171.
18. Mayes, A. M.; Russell, T. P.; Satija, S. K.; Majkrzak, C. F. Macromolecules 1992, 25, 5677.
19. Parratt, L. G. J. Chem. Phys. 1956, 53, 597.
20. Jones, R. A. L.; Kramer, E. J.; Rafailovich, M. H.; Sokolov, J.; Schwartz, S. A. Phys. Rev. Lett. 1989, 62, 280.
21. Hariharan, A.; Kumar, S. K.; Rafailovich, M. H.; Sokolov, J.; Zheng, X.; Duong, D.; Schwarz, S. A.; Russell, T. P. J. Chem. Phys. 1993, 99, 656.
22. Hong, P. P.; Boerio, F. J.; Smith, S. D. Macromolecules 1994, 27, 596.
23. The areal contribution of the TFE tails is estimated here as ca. 2 times the segmental area of PS.
24. DeGennes, P.-G. R. Acad. Sci. (Paris) 1988, 307, 1841.
25. Leibler, L.; Orland, H.; Wheeler, J. C. J. Chem. Phys. 1983, 79, 3550.
26. Mayes, A. M.; Olvera de la Cruz, M. Macromolecules 1988, 21, 2543.
27. Carslaw, H. S.; Jaeger, J. C. Conduction of Heat in Solids, 2nd ed.; Oxford University Press: London, 1959; pp 198-99, 233, 331, 335-336, 366-370.
28. Fleischer, C. A.; Koberstein, J. T.; Krukonis, V.; Wetmore, P. A. Macromolecules 1993, 26, 4172.