Mechanism of the transition-metal-catalyzed hydroarylation of bromo-alkynes revisited: Hydrogen versus bromine migration

Chemistry - A European Journal

Volumn 18, Issue 17, 2012, Pages 5401-5415

  Huang, Genping ^a,c   Cheng, Bing ^a   Xu, Liang ^a   Li, Yahong ^b   Xia, Yuanzhi ^a  

^a WENZHOU UNIVERSITY   (China)

^b SOOCHOW UNIVERSITY   (China)

^c QINGHAI INSTITUTE OF SALT LAKES   (China)

Author keywords

alkynes; cycloisomerization; density functional calculations; hydroarylation; transition metals

Indexed keywords

ACTIVATION BARRIERS; ALKYNES; BIPHENYL DERIVATIVES; CATALYZED REACTIONS; COMPLEX PRODUCTS; CYCLIZATION PATHWAYS; CYCLOISOMERIZATIONS; FLUORENES; HYDROARYLATION; MECHANISTIC STUDIES;

ACETYLENE; ACTIVATION ENERGY; BROMINE; CATALYSIS; CATALYST SELECTIVITY; CHLORINE COMPOUNDS; DENSITY FUNCTIONAL THEORY; FLUORINE CONTAINING POLYMERS; HYDROGEN; ISOMERIZATION; PLATINUM; REACTION INTERMEDIATES; TRANSITION METALS;

CYCLIZATION;

EID: 84859907753     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201102692     Document Type: Article

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