Mechanism study of the gold-catalyzed cycloisomerization of α-aminoallenes: Oxidation state of active species and influence of counterion

Journal of Physical Chemistry A

Volumn 114, Issue 13, 2010, Pages 4689-4696

  Zhu, Rong Xiu ^a   Zhang, Dong Ju ^a   Guo, Jin Xin ^a   Mu, Jing Lin ^a   Duan, Chong Gang ^b   Liu, Cheng Bu ^a  

^a BEIJING UNIVERSITY OF POSTS AND TELECOMMUNICATIONS   (China)

^b Shandong Institute of Pharmaceutical Industry   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SPECIES; ALLENES; AU-COMPLEXES; B3LYP DENSITY FUNCTIONAL; CATALYTIC ACTIVITY; CATALYTIC CYCLES; CATALYTIC PERFORMANCE; CATALYTIC REACTIONS; CATALYTICALLY ACTIVE SPECIES; COMPUTATIONAL STUDIES; COUNTERIONS; CYCLOISOMERIZATIONS; DEMETALATION; DOUBLE BONDS; GOLD OXIDATION; NUCLEOPHILIC ATTACK; OXIDATION STATE; REACTION MECHANISM;

CATALYSIS; CATALYST ACTIVITY; CHEMICAL BONDS; COORDINATION REACTIONS; DENSITY FUNCTIONAL THEORY; GOLD COMPOUNDS; HYDROCARBONS;

CATALYTIC OXIDATION;

ALKADIENE; AMINE; GOLD; GOLD DERIVATIVE; ION; PROTON; SOLVENT;

ALGORITHM; AMINATION; ARTICLE; CATALYSIS; CHEMICAL MODEL; CHEMISTRY; CYCLIZATION; ENZYME ACTIVE SITE; ISOMERISM; OXIDATION REDUCTION REACTION; QUANTUM THEORY;

ALGORITHMS; ALKADIENES; AMINATION; AMINES; CATALYSIS; CATALYTIC DOMAIN; CYCLIZATION; GOLD; GOLD COMPOUNDS; IONS; ISOMERISM; MODELS, CHEMICAL; OXIDATION-REDUCTION; PROTONS; QUANTUM THEORY; SOLVENTS;

EID: 77950466851     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp100291c     Document Type: Article

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