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For this specific substrate regioselective elimination is observed, however some ene-allenes eliminate to give a regioisomeric mixture; see
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3PAu]-vinyl complex; see reference [3d].
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3PAu]-vinyl complex; see reference [3d].
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50
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70349925345
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Compound 3 is one of only a few vinyl-gold(I) species not stabilized by an electron-withdrawing group;
-
Compound 3 is one of only a few vinyl-gold(I) species not stabilized by an electron-withdrawing group; see reference [3d].
-
see reference [3d]
-
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51
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70349925339
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The observed distances are similar to those published by Laguna; see reference [3d, X-ray crystal structure data for 3 at 100 K: C 36H36AuO6P, Mr, 792.61 gmol 1, triclinic, space group P1̄, a, 8.7814(5, b, 13.7359(7, c, 14.3110(7) Å a, 105.099(2, β, 96.500(2, γ, 97.267(2)°, V= 1633.85(15) Å3, Z, 2, ρcalcd, 1.611 gem-3, R1, 0.0186 (0.0188, wR2, 0.0448-(0.0449, for 5692 reflections with I 2σ(I, for 5759 reflections (Rint, 0.0294) with a total of 27480 measured reflections, goodness of fit on F2, 1.121, largest diff. peak (hole, 0.0930, 0.725 e Å-3) see the Supporting Information. CCDC736429 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
-
-3) see the Supporting Information. CCDC736429 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
-
-
-
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52
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70349932367
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Compound 3 also protodeaurated when placed onto a column of silica gel, and only partially survives chromatography using short plugs of alumina; see references [3c] and [5a] for comparison
-
Compound 3 also protodeaurated when placed onto a column of silica gel, and only partially survives chromatography using short plugs of alumina; see references [3c] and [5a] for comparison.
-
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53
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70349897418
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See reference [3g];
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See reference [3g];
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70349934472
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31P NMR methods, and compared to literature values (see the Supporting Information).
-
31P NMR methods, and compared to literature values (see the Supporting Information).
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