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For a structural model mimicking the slippage process in gold catalysis, which is strongly supportive of high levels of charge separation, see
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Anisotropic displacement parameters are drawn at the 50% probability level and hydrogen atoms are omitted for clarity. CCDC 678991 (17), 678992 (19), and 678990 (21a) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif. Short crystallographic summaries can also be found in the Supporting Information.
-
Anisotropic displacement parameters are drawn at the 50% probability level and hydrogen atoms are omitted for clarity. CCDC 678991 (17), 678992 (19), and 678990 (21a) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif. Short crystallographic summaries can also be found in the Supporting Information.
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Only trace amounts of the regioisomeric compound, arising from attack of the alcohol at C6, were detected.
-
Only trace amounts of the regioisomeric compound, arising from attack of the alcohol at C6, were detected.
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67
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53549124585
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Previous reactivity data thought to be supportive of gold carbenes fall into the general categories of Friedel-Crafts reactions, Prins-type processes, and cationic rearrangements, or commence with the attack of a sulfoxide see Refs, 5a-c, according to our analysis, they can be easily accounted for in cationic terms and are therefore by no means inconsistent with the views expressed in this paper
-
Previous reactivity data thought to be supportive of gold carbenes fall into the general categories of Friedel-Crafts reactions, Prins-type processes, and cationic rearrangements, or commence with the attack of a sulfoxide (see Refs. [5a-c]); according to our analysis, they can be easily accounted for in cationic terms and are therefore by no means inconsistent with the views expressed in this paper.
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