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4444344996
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note
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3AuCl/AgOTf) was employed as the catalyst.
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note
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Major diastereomer was assigned on the basis of the NOE measurements detailed in Supporting Information.
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23
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3242681337
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For a recent report of chirality transfer in the rearrangement of olefin epoxides to bicyclo[3.1.0]hexanes, see: Hodgson, D. M.; Chung, Y. K.; Paris, J.-M. J. Am. Chem. Soc. 2004, 126, 8664.
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2-catalyzed cycloisomerization of 1,6-enynes: (a) Fürstner, A.; Szillat, H.; Gabor, B.; Mynott, R. J. Am. Chem. Soc. 1998, 120, 8305.
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