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71749119981
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log).
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77
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71749109217
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To report all rectification ratios consistently as values greater than or equal to unity, and because junctions incorporating alkanethiolates show enhanced current at positive bias, we use the definition of R for such junctions so that R = |J(V)|/|J(-V)| for junctions in which |J(V)| > |J(-V)|.
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log.
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71749102645
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3 and the observed value of β in a separate paper.
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Armstrong, N.; Hoft, R. C.; McDonagh, A.; Cortie, M. B.; Ford, M. J. Nano Lett. 2007, 7, 3018.
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Armstrong, N.1
Hoft, R.C.2
McDonagh, A.3
Cortie, M.B.4
Ford, M.J.5
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71749083407
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Reus, W. F.; Nijhuis, C. A.; Whitesides, G. M., unpublished experiments
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Reus, W. F.; Nijhuis, C. A.; Whitesides, G. M., unpublished experiments.
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TS surfaces, an electrometer, and wires to connect all components.
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Our setup is not completely vibration free. Vibration caused some of the junctions to fail during data collection. A small tick on the Faraday cage, in which our setup is installed, during data collection caused the junctions to short.
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A detailed physical-organic study to control the potential drops along the SAM, including J(V) curves measured at different temperatures, to elucidate the mechanism of rectification in more detail, will be reported in a separate paper: Nijhuis, C. A.; Reus, W. F.; Whitesides, G. M., manuscript in preparation.
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