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Volumn 20, Issue 16, 2004, Pages 6631-6638

Anion effect on mediated electron transfer through ferrocene-terminated self-assembled monolayers

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CYCLIC VOLTAMMETRY; ELECTRON TRANSPORT PROPERTIES; HYDRATION; HYDROPHOBICITY; NEGATIVE IONS; RATE CONSTANTS; REACTION KINETICS;

EID: 4043115546     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la0364800     Document Type: Article
Times cited : (169)

References (50)
  • 33
    • 4043074246 scopus 로고    scopus 로고
    • note
    • As in the cases with most redox monolayere, we observed small (∼10 mV) initial peak-to-peak splitting, which does not disappear at the scan rates as low as 1-5 mV/s. The initial peak-to-peak separation was subtracted from the scan-rate-dependent peak-to-peak splitting when making estimates of the electron transfer rate constants for MNFcP monolayers.
  • 34
    • 4043169206 scopus 로고    scopus 로고
    • See the Supporting Information for details of the calculation of the electron transfer constant
    • See the Supporting Information for details of the calculation of the electron transfer constant.
  • 39
    • 4043111367 scopus 로고    scopus 로고
    • note
    • We claim that electron transfer occurs through the mediatory mechanism because, on the redox-inactive monolayers of similar length and structure, which have no ferrocene headgroups, we did not observe significant current flow upon addition of ascorbic acid to the solution. See the Supporting Information for the details.
  • 47
    • 4043133848 scopus 로고    scopus 로고
    • note
    • Data in preparation for publication.
  • 49


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.