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As in the cases with most redox monolayere, we observed small (∼10 mV) initial peak-to-peak splitting, which does not disappear at the scan rates as low as 1-5 mV/s. The initial peak-to-peak separation was subtracted from the scan-rate-dependent peak-to-peak splitting when making estimates of the electron transfer rate constants for MNFcP monolayers.
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34
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See the Supporting Information for details of the calculation of the electron transfer constant
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See the Supporting Information for details of the calculation of the electron transfer constant.
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note
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We claim that electron transfer occurs through the mediatory mechanism because, on the redox-inactive monolayers of similar length and structure, which have no ferrocene headgroups, we did not observe significant current flow upon addition of ascorbic acid to the solution. See the Supporting Information for the details.
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