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0011342076
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note
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A pH-controlled environment requires water, and CITS experiments of this type are extremely difficult in an aqueous environment due to leak current with the water. Efforts are under way to study this effect with STM tips that are sufficiently well insulated that their I-V response is not dominated by leak.
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note
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11S-SAM (362 mV vs Ag/AgCl, see: Sumner, J.J.; Weber, K.S.; Hockett, L.A.; Creager, S.E. J. Phys. Chem. B 2000, 104, 7449-7454.) are too similar to expect a significant change in the position of NDR. We hope to study this effect on a wider range of electroactive SAMs soon.
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