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A number of workers have demonstrated rectification by organic monolayers using scanning probe microscopy. We focus here on results obtained from measurements on ensembles of molecules. For example, see: Pomerantz, M.; A. Aviram, McCorkle, R. A.; Li, L.; Schrott, A. G. Science 1992, 255, 1115-1118; Dhirani, A.; Lin, P.-H.; Guyot-Sionnest, P.; Zehner R. W.; Sita, L. R. J. Chem. Phys. 1997, 106, 5249-5253.
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8
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A number of workers have demonstrated rectification by organic monolayers using scanning probe microscopy. We focus here on results obtained from measurements on ensembles of molecules. For example, see: Pomerantz, M.; A. Aviram, McCorkle, R. A.; Li, L.; Schrott, A. G. Science 1992, 255, 1115-1118; Dhirani, A.; Lin, P.-H.; Guyot-Sionnest, P.; Zehner R. W.; Sita, L. R. J. Chem. Phys. 1997, 106, 5249-5253.
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16
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0034807793
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Holmlin, R. E.; Haag, R.; Chabinyc, M. L.; Ismagilov, R. F.; Cohen, A. E.; Terfort, A.; Rampi, M.; Whitesides, G. M. J. Am. Chem. Soc. 2001, 123, 5075-5085.
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Whitesides, G.M.8
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17
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0035907729
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Holmlin, R. E.; Ismagilov, R. F.; Haag, R.; Mujica, V.; Ratner, M. A.; Rampi, M.; Whitesides, G. M. Angew. Chem., Int. Ed. 2001, 40, 2316-2320.
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Holmlin, R.E.1
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18
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0033546682
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Slowinski, K.; Fong, H. K. Y.; Majda, M. J. Am. Chem. Soc. 1999, 121, 7257-7261.
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Slowinski, K.1
Fong, H.K.Y.2
Majda, M.3
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22
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2142740569
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-
note
-
The refractive index of the SAM was assumed to be the same as that for a SAM of an alkanethiolate (1.45). We do not believe that the assumption of this value of the refractive index will create a substantial error in the derived value of the thickness.
-
-
-
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23
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0035797731
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Metzger, R. M.; Xu, T.; Peterson, I. R. J. Phys. Chem. B 2001, 105, 7280-7290.
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Metzger, R.M.1
Xu, T.2
Peterson, I.R.3
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24
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0035120385
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Ashwell, G. J.; Gandolfo, D. S. J. Mater. Chem. 2001, 11, 246-248. Ashwell and co-workers have observed rectification using different donor acceptor systems in a MIM jumnction: Ashwell, G. J.; Gandolfo, D. S. J. Mater. Chem. 2002, 12, 411-415. Ashwell, G. J.; Gandolfo, D. S.; Hamilton, R. J. Mater. Chem. 2002, 12, 416-419.
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Ashwell, G.J.1
Gandolfo, D.S.2
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25
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0036193738
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Ashwell, G. J.; Gandolfo, D. S. J. Mater. Chem. 2001, 11, 246-248. Ashwell and co-workers have observed rectification using different donor acceptor systems in a MIM jumnction: Ashwell, G. J.; Gandolfo, D. S. J. Mater. Chem. 2002, 12, 411-415. Ashwell, G. J.; Gandolfo, D. S.; Hamilton, R. J. Mater. Chem. 2002, 12, 416-419.
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J. Mater. Chem.
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Ashwell, G.J.1
Gandolfo, D.S.2
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26
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0036199084
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Ashwell and co-workers have observed rectification using different donor acceptor systems in a MIM jumnction: Ashwell, G. J.; Gandolfo, D. S. J. Mater. Chem. 2002, 12, 411-415. Ashwell, G. J.; Gandolfo, D. S.; Hamilton, R. J. Mater. Chem. 2002, 12, 416-419.
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J. Mater. Chem.
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Ashwell, G.J.1
Gandolfo, D.S.2
Hamilton, R.3
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28
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2142838563
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-
note
-
Majda and co-workers have observed this behavior in a similar MIM junction where both metal electrodes are formed from liquid mercury. Ref 17, 18.
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29
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2142848779
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-
note
-
The refractive index of the SAM was assumed to be the same as that for a SAM of an alkanethiolate (1.45). We do not believe that the assumption of this value of the refractive index will create a substantial error in the derived value of the thickness.
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-
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30
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0006163257
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Porter, M. D.; Bright, T. B.; Allara, D. L.; Chidsey, C. E. D. J. Am. Chem. Soc. 1987, 109, 3559-3568.
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Liu, Y.-P.6
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32
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0035805279
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Metzger has shown that the rectification in MIM junctions formed with HQ-TCNQ is not caused by electrodes containing a metal oxide as well: Xu, T.; Peterson, I. R.; Lakshmikantham, M. V.; Metzger, R. M. Angew. Chem., Int. Ed. 2001, 40, 1749-1752.
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Peterson, I.R.2
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Metzger, R.M.4
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34
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2142775570
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note
-
We base our discussion on a valence orbital representation and treat the orbitals of TCNQ separately from those of the alkyl chain. The π symmetry states of TCNQ are unlikely to mix strongly with the alkyl chain due to symmetry and difference in energy.
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Mallard, W. G., Linstrom, P. J., Eds.; National Institute of Standards and Technology: Gaithersburg, MD
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Ag-(Cn)II(C16)-Hg where the insulating layer contains only one type of functional group). See ref 16.
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2142721143
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note
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It is difficult to determine whether this assumption is valid for the junctions studied here. We assume that the qualitative predictions of the model are valid, but a more detailed analysis of the system will require testing of this assumption.
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48
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2842602678
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Experimental evidence and model theoretical calculations indicate that, for many homogeneous molecular MIM junctions, the voltage drops at the two metal-molecule interfaces and also across the molecular bridge: Samanta, M. P.; Tian, W.; Datta, S.; Henderson, J. I.; Kubiak, C. P. Phys. Rev. B 1996, 53, R7626-R7629. Damle, P. S.; Ghosh, A. W.; Datta, S. Phys. Rev. B 2001, 64, 201403-1.
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49
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0035890458
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Experimental evidence and model theoretical calculations indicate that, for many homogeneous molecular MIM junctions, the voltage drops at the two metal-molecule interfaces and also across the molecular bridge: Samanta, M. P.; Tian, W.; Datta, S.; Henderson, J. I.; Kubiak, C. P. Phys. Rev. B 1996, 53, R7626-R7629. Damle, P. S.; Ghosh, A. W.; Datta, S. Phys. Rev. B 2001, 64, 201403-1.
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