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The differential capacitance measured at -0.75 V is independent of the presence of alkanethiol in a solution, thus indicafing that no physical adsorption occurs at this potential.
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The diameter of a Hg drop varied between 0.84 and 1 mm. The final diameter of a spontaneously formed tunneling junction was always ca. 26% of a drop diameter for both monolayer and bilayer junctions. The current density was independent of the junction radius.
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(d) Bruckner-Lea, C.; Janata, J.; Conroy, A.; Pungor, K.; Caldwell, K. Langmuir 1993, 9, 3612.
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(1993)
Langmuir
, vol.9
, pp. 3612
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Bruckner-Lea, C.1
Janata, J.2
Conroy, A.3
Pungor, K.4
Caldwell, K.5
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