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A "full" layer is the one in which all the ferrocene moieties are well packed and no more can fit due to steric interactions. Even if the headgroups are well packed, a certain degree of disorder can be found in the underlying alkyl chains, due the difference in size between the ferrocene moieties and the alkyl chains, as shown in the calculation for the theoretical curve of the charge densities versus the solution composition.
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15 where the increase of chain length of both components (ferrocene thiol and unsubstituted thiol) does not affect the ferrocene surface coverage. In that case both components have comparable chain length; therefore, no discrimination could be expected on the basis of different lateral interaction.
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