SCOPUS 정보 검색 플랫폼

Dalton Transactions

Volumn 42, Issue 36, 2013, Pages 13251-13264

Synthesis and study of olefin metathesis catalysts supported by redox-switchable diaminocarbene[3]ferrocenophanes

(5) Varnado Jr , C Daniel a Rosen, Evelyn L a Collins, Mary S a Lynch, Vincent M a Bielawski, Christopher W a

a UNIVERSITY OF TEXAS AT AUSTIN (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; IRIDIUM; OXIDATION; RATE CONSTANTS; REDUCTION; RING OPENING POLYMERIZATION; SPECTROSCOPIC ANALYSIS; X RAY CRYSTALLOGRAPHY;

DECAMETHYLFERROCENE; ELECTROCHEMICAL PROCESS; ELECTRONIC PARAMETERS; POLYMERIZATION RATES; REDOX-ACTIVE LIGAND; RING OPENING METATHESIS POLYMERIZATION; SPECTROSCOPIC MEASUREMENTS; SUBSEQUENT REDUCTION;

SYNTHESIS (CHEMICAL);

EID: 84882771556 PISSN: 14779226 EISSN: 14779234 Source Type: Journal
DOI: 10.1039/c3dt51278a Document Type: Article

Times cited : (72)

References (164)

1
- 0031960505
- A. M. Allgeier C. A. Mirkin Angew. Chem., Int. Ed. 1998 37 894 908
- (1998) Angew. Chem., Int. Ed. , vol.37 , pp. 894-908
- Allgeier, A.M.¹ Mirkin, C.A.²

2
- 79953275935
- A. J. D. Magenau N. C. Strandwitz A. Gennaro K. Matyjaszewski Science 2011 332 81 84
- (2011) Science , vol.332 , pp. 81-84
- Magenau, A.J.D.¹ Strandwitz, N.C.² Gennaro, A.³ Matyjaszewski, K.⁴

3
- 19544386162
- N. Hadei E. A. B. Kantchev C. J. O'Brien M. G. Organ Org. Lett. 2005 7 1991 1994
- (2005) Org. Lett. , vol.7 , pp. 1991-1994
- Hadei, N.¹ Kantchev, E.A.B.² O'Brien, C.J.³ Organ, M.G.⁴

4
- 24344504109
- C. J. O'Brien E. A. B. Kantchev G. A. Chass N. Hadei A. C. Hopkinson M. G. Organ D. H. Setiadi T.-H. Tang D.-C. Fang Tetrahedron 2005 61 9723 9735
- (2005) Tetrahedron , vol.61 , pp. 9723-9735
- O'Brien, C.J.¹ Kantchev, E.A.B.² Chass, G.A.³ Hadei, N.⁴ Hopkinson, A.C.⁵ Organ, M.G.⁶ Setiadi, D.H.⁷ Tang, T.-H.⁸ Fang, D.-C.⁹

5
- 70349921088
- T. Vorfalt S. Leuthäußer H. Plenio Angew. Chem., Int. Ed. 2009 48 5191 5194
- (2009) Angew. Chem., Int. Ed. , vol.48 , pp. 5191-5194
- Vorfalt, T.¹ Leuthäußer, S.² Plenio, H.³

6
- 44949203422
- D. M. Khramov E. L. Rosen J. A. V. Er P. D. Vu V. M. Lynch C. W. Bielawski Tetrahedron 2008 64 6853 6862
- (2008) Tetrahedron , vol.64 , pp. 6853-6862
- Khramov, D.M.¹ Rosen, E.L.² Er, J.A.V.³ Vu, P.D.⁴ Lynch, V.M.⁵ Bielawski, C.W.⁶

7
- 0001692524
- I. M. Lorkovic Jr. R. R. Duff M. S. Wrighton J. Am. Chem. Soc. 1995 117 3617 3618
- (1995) J. Am. Chem. Soc. , vol.117 , pp. 3617-3618
- Lorkovic Jr., I.M.¹ Duff, R.R.² Wrighton, M.S.³

8
- 0030771665
- C. S. Slone C. A. Mirkin G. P. A. Yap I. A. Guzei A. L. Rheingold J. Am. Chem. Soc. 1997 119 10743 10753
- (1997) J. Am. Chem. Soc. , vol.119 , pp. 10743-10753
- Slone, C.S.¹ Mirkin, C.A.² Yap, G.P.A.³ Guzei, I.A.⁴ Rheingold, A.L.⁵

9
- 14844351559
- T. Hino T. Wada T. Fujihara K. Tanaka Chem. Lett. 2004 1596 1597
- (2004) Chem. Lett. , pp. 1596-1597
- Hino, T.¹ Wada, T.² Fujihara, T.³ Tanaka, K.⁴

10
- 33745053344
- C. K. A. Gregson V. C. Gibson N. J. Long E. L. Marshall P. J. Oxford A. J. P. White J. Am. Chem. Soc. 2006 128 7410 7411
- (2006) J. Am. Chem. Soc. , vol.128 , pp. 7410-7411
- Gregson, C.K.A.¹ Gibson, V.C.² Long, N.J.³ Marshall, E.L.⁴ Oxford, P.J.⁵ White, A.J.P.⁶

11
- 38349173628
- M. R. Ringenberg S. L. Kokatam Z. M. Heiden T. B. Rauchfuss J. Am. Chem. Soc. 2008 130 788 789
- (2008) J. Am. Chem. Soc. , vol.130 , pp. 788-789
- Ringenberg, M.R.¹ Kokatam, S.L.² Heiden, Z.M.³ Rauchfuss, T.B.⁴

12
- 42149173855
- J. T. Muckerman D. E. Polyansky T. Wada K. Tanaka E. Fujita Inorg. Chem. 2008 47 1787 1802
- (2008) Inorg. Chem. , vol.47 , pp. 1787-1802
- Muckerman, J.T.¹ Polyansky, D.E.² Wada, T.³ Tanaka, K.⁴ Fujita, E.⁵

13
- 40949099527
- K. J. Blackmore N. Lal J. W. Ziller A. F. Heyduk J. Am. Chem. Soc. 2008 130 2728 2729
- (2008) J. Am. Chem. Soc. , vol.130 , pp. 2728-2729
- Blackmore, K.J.¹ Lal, N.² Ziller, J.W.³ Heyduk, A.F.⁴

14
- 61849135658
- J. L. Boyer T. R. Cundari N. J. DeYonker T. B. Rauchfuss S. R. Wilson Inorg. Chem. 2008 48 638 645
- (2008) Inorg. Chem. , vol.48 , pp. 638-645
- Boyer, J.L.¹ Cundari, T.R.² Deyonker, N.J.³ Rauchfuss, T.B.⁴ Wilson, S.R.⁵

15
- 79959262427
- E. M. Broderick N. Guo C. S. Vogel C. Xu J. Sutter J. T. Miller K. Meyer P. Mehrkhodavandi P. L. Diaconescu J. Am. Chem. Soc. 2011 133 9278 9281
- (2011) J. Am. Chem. Soc. , vol.133 , pp. 9278-9281
- Broderick, E.M.¹ Guo, N.² Vogel, C.S.³ Xu, C.⁴ Sutter, J.⁵ Miller, J.T.⁶ Meyer, K.⁷ Mehrkhodavandi, P.⁸ Diaconescu, P.L.⁹

16
- 80052099336
- E. M. Broderick N. Guo T. Wu C. S. Vogel C. Xu J. Sutter J. T. Miller K. Meyer T. Cantat P. L. Diaconescu Chem. Commun. 2011 47 9897 9899
- (2011) Chem. Commun. , vol.47 , pp. 9897-9899
- Broderick, E.M.¹ Guo, N.² Wu, T.³ Vogel, C.S.⁴ Xu, C.⁵ Sutter, J.⁶ Miller, J.T.⁷ Meyer, K.⁸ Cantat, T.⁹ Diaconescu, P.L.¹⁰

17
- 27544469881
- M. Sußner H. Plenio Angew. Chem., Int. Ed. 2005 44 6885 6888
- (2005) Angew. Chem., Int. Ed. , vol.44 , pp. 6885-6888
- Sußner, M.¹ Plenio, H.²

18
- 67650485773
- G. Liu H. He J. Wang Adv. Synth. Catal. 2009 351 1610 1620
- (2009) Adv. Synth. Catal. , vol.351 , pp. 1610-1620
- Liu, G.¹ He, H.² Wang, J.³

19
- 0000609674
- Angew. Chem. Int. Ed. 1998 37 1174 1196
- D. P. Curran Angew. Chem. 1998 110 1230 1255 Angew. Chem. Int. Ed. 1998 37 1174 1196
- (1998) Angew. Chem. , vol.110 , pp. 1230-1255
- Curran, D.P.¹

20
- 77957690438
- L. H. Peeck S. Leuthaüsser H. Plenio Organometallics 2010 29 4339 4345
- (2010) Organometallics , vol.29 , pp. 4339-4345
- Peeck, L.H.¹ Leuthaüsser, S.² Plenio, H.³

21
- 0036007772
- M. D. Ward J. A. McCleverty J. Chem. Soc., Dalton Trans. 2002 275 288
- (2002) J. Chem. Soc., Dalton Trans. , pp. 275-288
- Ward, M.D.¹ McCleverty, J.A.²

22
- 33745751802
- P. Zanello M. Corsini Coord. Chem. Rev. 2006 250 2000 2022
- (2006) Coord. Chem. Rev. , vol.250 , pp. 2000-2022
- Zanello, P.¹ Corsini, M.²

23
- 71649092554
- J. L. Boyer J. Rochford M.-K. Tsai J. T. Muckerman E. Fujita Coord. Chem. Rev. 2010 254 309 330
- (2010) Coord. Chem. Rev. , vol.254 , pp. 309-330
- Boyer, J.L.¹ Rochford, J.² Tsai, M.-K.³ Muckerman, J.T.⁴ Fujita, E.⁵

24
- 0003108729
- J. C. Kotz C. L. Nivert J. M. Lieber R. C. Reed J. Organomet. Chem. 1975 91 87 95
- (1975) J. Organomet. Chem. , vol.91 , pp. 87-95
- Kotz, J.C.¹ Nivert, C.L.² Lieber, J.M.³ Reed, R.C.⁴

25
- 0001343338
- T. M. Miller K. J. Ahmed M. S. Wrighton Inorg. Chem. 1989 28 2347 2355
- (1989) Inorg. Chem. , vol.28 , pp. 2347-2355
- Miller, T.M.¹ Ahmed, K.J.² Wrighton, M.S.³

26
- 0000563187
- I. M. Lorkovic M. S. Wrighton W. M. Davis J. Am. Chem. Soc. 1994 116 6220 6228
- (1994) J. Am. Chem. Soc. , vol.116 , pp. 6220-6228
- Lorkovic, I.M.¹ Wrighton, M.S.² Davis, W.M.³

27
- 0000959168
- L. K. Yeung J. E. Kim Y. K. Chung P. H. Rieger D. A. Sweigart Organometallics 1996 15 3891 3897
- (1996) Organometallics , vol.15 , pp. 3891-3897
- Yeung, L.K.¹ Kim, J.E.² Chung, Y.K.³ Rieger, P.H.⁴ Sweigart, D.A.⁵

28
- 0000371726
- H. H. Downs R. M. Buchanan C. G. Pierpont Inorg. Chem. 1979 18 1736 1740
- (1979) Inorg. Chem. , vol.18 , pp. 1736-1740
- Downs, H.H.¹ Buchanan, R.M.² Pierpont, C.G.³

29
- 0007341624
- F. Hartl A. Vlcek Inorg. Chem. 1991 30 3048 3053
- (1991) Inorg. Chem. , vol.30 , pp. 3048-3053
- Hartl, F.¹ Vlcek, A.²

30
- 0000957070
- K. Yang S. G. Bott M. G. Richmond Organometallics 1995 14 2387 2394
- (1995) Organometallics , vol.14 , pp. 2387-2394
- Yang, K.¹ Bott, S.G.² Richmond, M.G.³

31
- 2342590711
- T. Wada T. Fujihara M. Tomori D. Ooyama K. Tanaka Bull. Chem. Soc. Jpn. 2004 77 741 749
- (2004) Bull. Chem. Soc. Jpn. , vol.77 , pp. 741-749
- Wada, T.¹ Fujihara, T.² Tomori, M.³ Ooyama, D.⁴ Tanaka, K.⁵

32
- 34548604579
- N. Bellec J. Massue T. Roisnel D. Lorcy Inorg. Chem. Commun. 2007 10 1172 1176
- (2007) Inorg. Chem. Commun. , vol.10 , pp. 1172-1176
- Bellec, N.¹ Massue, J.² Roisnel, T.³ Lorcy, D.⁴

33
- 23844521950
- K. J. Blackmore J. W. Ziller A. F. Heyduk Inorg. Chem. 2005 44 5559 5561
- (2005) Inorg. Chem. , vol.44 , pp. 5559-5561
- Blackmore, K.J.¹ Ziller, J.W.² Heyduk, A.F.³

34
- 0031017921
- A. M. Allgeier C. S. Slone C. A. Mirkin L. M. Liable-Sands G. P. A. Yap A. L. Rheingold J. Am. Chem. Soc. 1997 119 550 559
- (1997) J. Am. Chem. Soc. , vol.119 , pp. 550-559
- Allgeier, A.M.¹ Slone, C.S.² Mirkin, C.A.³ Liable-Sands, L.M.⁴ Yap, G.P.A.⁵ Rheingold, A.L.⁶

35
- 0000375789
- Although metallocenes are commonly utilized, other types of redox-active ligands have been used to modulate catalytic reactions. For example, Rauchfuss reported 5d that an Ir complex containing 2-(2-trifluoromethyl)anilino-4,6-di- tert-butylphenol activated H2 upon oxidation; likewise, oxidation also increased the electrophilicity of a Pt complex containing the same ligand. 5g We reported that Ni complexes containing 1,3- dimesitylnaphthoquinimidazolylidene (NQMes) 23 modulate Kumada coupling reactions as a function of the ligand's oxidation state. 21
- C. A. Sassano C. A. Mirkin J. Am. Chem. Soc. 1995 117 11379 11380
- (1995) J. Am. Chem. Soc. , vol.117 , pp. 11379-11380
- Sassano, C.A.¹ Mirkin, C.A.²

36
- 0001286592
- A. J. Arduengo III R. L. Harlow M. Kline J. Am. Chem. Soc. 1991 113 361 363
- (1991) J. Am. Chem. Soc. , vol.113 , pp. 361-363
- Arduengo III, A.J.¹ Harlow, R.L.² Kline, M.³

37
- 0032723198
- A. J. Arduengo III Acc. Chem. Res. 1999 32 913 921
- (1999) Acc. Chem. Res. , vol.32 , pp. 913-921
- Arduengo III, A.J.¹

38
- 9744248685
- C. M. Crudden D. P. Allen Coord. Chem. Rev. 2004 248 2247 2273
- (2004) Coord. Chem. Rev. , vol.248 , pp. 2247-2273
- Crudden, C.M.¹ Allen, D.P.²

39
- 53049091364
- For reviews of catalytically-active transition metal complexes containing NHCs, see
- F. E. Hahn M. C. Jahnke Angew. Chem., Int. Ed. 2008 47 3122 3172
- (2008) Angew. Chem., Int. Ed. , vol.47 , pp. 3122-3172
- Hahn, F.E.¹ Jahnke, M.C.²

40
- 0037090932
- W. A. Herrmann Angew. Chem., Int. Ed. 2002 41 1290 1309
- (2002) Angew. Chem., Int. Ed. , vol.41 , pp. 1290-1309
- Herrmann, W.A.¹

41
- 9644254490
- E. Peris R. H. Crabtree Coord. Chem. Rev. 2004 248 2239 2246
- (2004) Coord. Chem. Rev. , vol.248 , pp. 2239-2246
- Peris, E.¹ Crabtree, R.H.²

42
- 2942612461
- K. J. Cavell D. S. McGuiness Coord. Chem. Rev. 2004 248 671 681
- (2004) Coord. Chem. Rev. , vol.248 , pp. 671-681
- Cavell, K.J.¹ McGuiness, D.S.²

43
- 34250797354
- E. A. B. Kantchev C. J. O'Briend M. G. Organ Angew. Chem., Int. Ed. 2007 46 2768 2813
- (2007) Angew. Chem., Int. Ed. , vol.46 , pp. 2768-2813
- Kantchev, E.A.B.¹ O'Briend, C.J.² Organ, M.G.³

44
- 33846821470
- E. Colacino J. Martinez F. Lamaty Coord. Chem. Rev. 2007 251 726 764
- (2007) Coord. Chem. Rev. , vol.251 , pp. 726-764
- Colacino, E.¹ Martinez, J.² Lamaty, F.³

45
- 84908659806
- S. Díez-González N. Marion S. P. Nolan Chem. Rev. 2009 109 3612 3676
- (2009) Chem. Rev. , vol.109 , pp. 3612-3676
- Díez-González, S.¹ Marion, N.² Nolan, S.P.³

46
- 68949140962
- C. Samojłowicz M. Bieniek K. Grela Chem. Rev. 2009 109 3708 3742
- (2009) Chem. Rev. , vol.109 , pp. 3708-3742
- Samojłowicz, C.¹ Bieniek, M.² Grela, K.³

47
- 47949103773
- N. M. Scott H. Clavier P. Mahjoor E. D. Stevens S. P. Nolan Organometallics 2008 27 3181 3186
- (2008) Organometallics , vol.27 , pp. 3181-3186
- Scott, N.M.¹ Clavier, H.² Mahjoor, P.³ Stevens, E.D.⁴ Nolan, S.P.⁵

48
- 0002708119
- L. Jafarpour E. D. Stevens S. P. Nolan J. Organomet. Chem. 2000 606 49 54
- (2000) J. Organomet. Chem. , vol.606 , pp. 49-54
- Jafarpour, L.¹ Stevens, E.D.² Nolan, S.P.³

49
- 33750109251
- in, Springer, Berlin, Heidelberg, 47-82
- S. Díez-González and S. Nolan, in N-Heterocyclic Carbenes in Transition Metal Catalysis, Springer, Berlin, Heidelberg, 2007, vol. 21, pp. 47-82
- (2007) N-Heterocyclic Carbenes in Transition Metal Catalysis , vol.21
- Díez-González, S.¹ Nolan, S.²

50
- 33645451955
- N. Marion O. Navarro J. Mei E. D. Stevens N. M. Scott S. P. Nolan J. Am. Chem. Soc. 2006 128 4101 4111
- (2006) J. Am. Chem. Soc. , vol.128 , pp. 4101-4111
- Marion, N.¹ Navarro, O.² Mei, J.³ Stevens, E.D.⁴ Scott, N.M.⁵ Nolan, S.P.⁶

51
- 30744453567
- O. Navarro N. Marion Y. Oonishi R. A. Kelly III S. P. Nolan J. Org. Chem. 2006 71 685 692
- (2006) J. Org. Chem. , vol.71 , pp. 685-692
- Navarro, O.¹ Marion, N.² Oonishi, Y.³ Kelly III, R.A.⁴ Nolan, S.P.⁵

52
- 0036643424
- A. C. Hillier G. A. Grasa M. S. Viciu H. M. Lee C. Yang S. P. Nolan J. Organomet. Chem. 2002 653 69 82
- (2002) J. Organomet. Chem. , vol.653 , pp. 69-82
- Hillier, A.C.¹ Grasa, G.A.² Viciu, M.S.³ Lee, H.M.⁴ Yang, C.⁵ Nolan, S.P.⁶

53
- 0037163998
- M. Jörgensen S. Lee X. Liu J. P. Wolkowski J. F. Hartwig J. Am. Chem. Soc. 2002 124 12557 12565
- (2002) J. Am. Chem. Soc. , vol.124 , pp. 12557-12565
- Jörgensen, M.¹ Lee, S.² Liu, X.³ Wolkowski, J.P.⁴ Hartwig, J.F.⁵

54
- 0037176243
- J. Louie J. E. Gibby M. V. Farnworth T. N. Tekavec J. Am. Chem. Soc. 2002 124 15188 15189
- (2002) J. Am. Chem. Soc. , vol.124 , pp. 15188-15189
- Louie, J.¹ Gibby, J.E.² Farnworth, M.V.³ Tekavec, T.N.⁴

55
- 0033598258
- M. Scholl S. Ding C. W. Lee R. H. Grubbs Org. Lett. 1999 1 953 956
- (1999) Org. Lett. , vol.1 , pp. 953-956
- Scholl, M.¹ Ding, S.² Lee, C.W.³ Grubbs, R.H.⁴

56
- 33745472389
- C. J. O'Brien E. A. B. Kantchev C. Valente N. Hadei G. A. Chass A. Lough A. C. Hopkinson M. G. Organ Chem.-Eur. J. 2006 12 4743 4748
- (2006) Chem.-Eur. J. , vol.12 , pp. 4743-4748
- O'Brien, C.J.¹ Kantchev, E.A.B.² Valente, C.³ Hadei, N.⁴ Chass, G.A.⁵ Lough, A.⁶ Hopkinson, A.C.⁷ Organ, M.G.⁸

57
- 53549118600
- D. M. Khramov E. L. Rosen V. M. Lynch C. W. Bielawski Angew. Chem., Int. Ed. 2008 47 2267 2270
- (2008) Angew. Chem., Int. Ed. , vol.47 , pp. 2267-2270
- Khramov, D.M.¹ Rosen, E.L.² Lynch, V.M.³ Bielawski, C.W.⁴

58
- 71949124011
- E. L. Rosen C. D. Varnado Jr. A. G. Tennyson D. M. Khramov J. W. Kamplain D. H. Sung P. T. Cresswell V. M. Lynch C. W. Bielawski Organometallics 2009 28 6695 6706
- (2009) Organometallics , vol.28 , pp. 6695-6706
- Rosen, E.L.¹ Varnado Jr., C.D.² Tennyson, A.G.³ Khramov, D.M.⁴ Kamplain, J.W.⁵ Sung, D.H.⁶ Cresswell, P.T.⁷ Lynch, V.M.⁸ Bielawski, C.W.⁹

59
- 84908659807
- A. G. Tennyson V. M. Lynch C. W. Bielawski J. Am. Chem. Soc. 2010 132 9420 9429
- (2010) J. Am. Chem. Soc. , vol.132 , pp. 9420-9429
- Tennyson, A.G.¹ Lynch, V.M.² Bielawski, C.W.³

60
- 69249184363
- C. D. Varnado Jr. V. M. Lynch C. W. Bielawski Dalton Trans. 2009 7253 7261
- (2009) Dalton Trans. , pp. 7253-7261
- Varnado Jr., C.D.¹ Lynch, V.M.² Bielawski, C.W.³

61
- 33845929780
- M. D. Sanderson J. W. Kamplain C. W. Bielawski J. Am. Chem. Soc. 2006 128 16514 16515
- (2006) J. Am. Chem. Soc. , vol.128 , pp. 16514-16515
- Sanderson, M.D.¹ Kamplain, J.W.² Bielawski, C.W.³

62
- 84881230443
- 10.1002/chem.201301247
- K. Arumugam C. D. Varnado Jr. S. Sproules V. M. Lynch C. W. Bielawski Chem.-Eur. J. 2013 10.1002/chem.201301247
- (2013) Chem.-Eur. J.
- Arumugam, K.¹ Varnado Jr., C.D.² Sproules, S.³ Lynch, V.M.⁴ Bielawski, C.W.⁵

63
- 57549104517
- U. Siemeling C. Färber C. Bruhn Chem. Commun. 2009 98 100
- (2009) Chem. Commun. , pp. 98-100
- Siemeling, U.¹ Färber, C.² Bruhn, C.³

64
- 72149103256
- U. Siemeling C. Färber M. Leibold C. Bruhn P. Mücke R. F. Winter B. Sarkar M. V. Hopffgarten G. Frenking Eur. J. Inorg. Chem. 2009 4607 4612
- (2009) Eur. J. Inorg. Chem. , pp. 4607-4612
- Siemeling, U.¹ Färber, C.² Leibold, M.³ Bruhn, C.⁴ Mücke, P.⁵ Winter, R.F.⁶ Sarkar, B.⁷ Hopffgarten, M.V.⁸ Frenking, G.⁹

65
- 84864592290
- U. Siemeling Eur. J. Inorg. Chem. 2012 3523 2546
- (2012) Eur. J. Inorg. Chem. , pp. 3523-2546
- Siemeling, U.¹

66
- 0038682047
- A. R. Chianese X. Li M. C. Janzen J. W. Faller R. H. Crabtree Organometallics 2003 22 1663 1667
- (2003) Organometallics , vol.22 , pp. 1663-1667
- Chianese, A.R.¹ Li, X.² Janzen, M.C.³ Faller, J.W.⁴ Crabtree, R.H.⁵

67
- 9344240844
- G. Altenhoff R. Goddard C. W. Lehmann F. Glorius J. Am. Chem. Soc. 2004 126 15195 15201
- (2004) J. Am. Chem. Soc. , vol.126 , pp. 15195-15201
- Altenhoff, G.¹ Goddard, R.² Lehmann, C.W.³ Glorius, F.⁴

68
- 34548323830
- S. Leuthäusser D. Schwarz H. Plenio Chem.-Eur. J. 2007 13 7195 7203
- (2007) Chem.-Eur. J. , vol.13 , pp. 7195-7203
- Leuthäusser, S.¹ Schwarz, D.² Plenio, H.³

69
- 38949179137
- R. A. Kelly III H. Clavier S. Giudice N. M. Scott E. D. Stevens J. Bordner I. Samardjiev C. D. Hoff L. Cavallo S. P. Nolan Organometallics 2008 27 202 210
- (2008) Organometallics , vol.27 , pp. 202-210
- Kelly III, R.A.¹ Clavier, H.² Giudice, S.³ Scott, N.M.⁴ Stevens, E.D.⁵ Bordner, J.⁶ Samardjiev, I.⁷ Hoff, C.D.⁸ Cavallo, L.⁹ Nolan, S.P.¹⁰

70
- 62849121721
- S. Wolf H. Plenio J. Organomet. Chem. 2009 694 1487 1492
- (2009) J. Organomet. Chem. , vol.694 , pp. 1487-1492
- Wolf, S.¹ Plenio, H.²

71
- 0000785058
- A. Furstner Angew. Chem., Int. Ed. 2000 112 3140 3172
- (2000) Angew. Chem., Int. Ed. , vol.112 , pp. 3140-3172
- Furstner, A.¹

72
- 0003985187
- Academic Press, San Diego, CA, 1st edn
- K. J. Ivin and J. C. Mol, Olefin Metathesis and Metathesis Polymerization, Academic Press, San Diego, CA, 1st edn, 1997
- (1997) Olefin Metathesis and Metathesis Polymerization
- Ivin, K.J.¹ Mol, J.C.²

73
- 0032514162
- K. J. Ivin J. Mol. Catal. A: Chem. 1998 133 1 16
- (1998) J. Mol. Catal. A: Chem. , vol.133 , pp. 1-16
- Ivin, K.J.¹

74
- 0032580376
- R. H. Grubbs S. Chang Tetrahedron 1998 54 4413 4450
- (1998) Tetrahedron , vol.54 , pp. 4413-4450
- Grubbs, R.H.¹ Chang, S.²

75
- 3343012187
- R. H. Grubbs Tetrahedron 2004 60 7117 7140
- (2004) Tetrahedron , vol.60 , pp. 7117-7140
- Grubbs, R.H.¹

76
- 0033750822
- M. R. Buchmeiser Chem. Rev. 2000 100 1565 1604
- (2000) Chem. Rev. , vol.100 , pp. 1565-1604
- Buchmeiser, M.R.¹

77
- 0034746687
- T. M. Trnka R. H. Grubbs Acc. Chem. Res. 2001 34 18 29
- (2001) Acc. Chem. Res. , vol.34 , pp. 18-29
- Trnka, T.M.¹ Grubbs, R.H.²

78
- 0000826186
- Angew. Chem., Int. Ed. Engl. 1995 34 2039 2041
- P. Schwab M. B. France J. W. Ziller R. H. Grubbs Angew. Chem. 1995 107 2179 2181 Angew. Chem., Int. Ed. Engl. 1995 34 2039 2041
- (1995) Angew. Chem. , vol.107 , pp. 2179-2181
- Schwab, P.¹ France, M.B.² Ziller, J.W.³ Grubbs, R.H.⁴

79
- 0001339679
- C. Fraser R. H. Grubbs Macromolecules 1995 28 7248 7255
- (1995) Macromolecules , vol.28 , pp. 7248-7255
- Fraser, C.¹ Grubbs, R.H.²

80
- 0001855961
- P. Schwab R. H. Grubbs J. W. Ziller J. Am. Chem. Soc. 1996 118 100 110
- (1996) J. Am. Chem. Soc. , vol.118 , pp. 100-110
- Schwab, P.¹ Grubbs, R.H.² Ziller, J.W.³

81
- 25144454100
- B. F. Staub Angew. Chem., Int. Ed. 2005 44 5974 5978
- (2005) Angew. Chem., Int. Ed. , vol.44 , pp. 5974-5978
- Staub, B.F.¹

82
- 0033549782
- T. Weskamp F. J. Kohl W. Hieringer D. Gliech W. A. Herrman Angew. Chem., Int. Ed. 1999 38 2416 2419
- (1999) Angew. Chem., Int. Ed. , vol.38 , pp. 2416-2419
- Weskamp, T.¹ Kohl, F.J.² Hieringer, W.³ Gliech, D.⁴ Herrman, W.A.⁵

83
- 0033582991
- M. Scholl T. M. Trnka J. P. Morgan R. H. Grubbs Tetrahedron Lett. 1999 40 2247 2250
- (1999) Tetrahedron Lett. , vol.40 , pp. 2247-2250
- Scholl, M.¹ Trnka, T.M.² Morgan, J.P.³ Grubbs, R.H.⁴

84
- 0034609694
- J. P. Morgan R. H. Grubbs Org. Lett. 2000 2 3153 3155
- (2000) Org. Lett. , vol.2 , pp. 3153-3155
- Morgan, J.P.¹ Grubbs, R.H.²

85
- 0033620417
- J. Huang E. D. Stevens S. P. Nolan J. L. Peterson J. Am. Chem. Soc. 1999 121 2674 2678
- (1999) J. Am. Chem. Soc. , vol.121 , pp. 2674-2678
- Huang, J.¹ Stevens, E.D.² Nolan, S.P.³ Peterson, J.L.⁴

86
- 0030660076
- W. A. Hermann C. Köcher Angew. Chem., Int. Ed. Engl. 1997 36 2162 2187
- (1997) Angew. Chem., Int. Ed. Engl. , vol.36 , pp. 2162-2187
- Hermann, W.A.¹ Köcher, C.²

87
- 0034685462
- For selected examples with unsaturated imidazol-2-ylidenes, see
- A. K. Chatterjee J. P. Morgan M. Scholl R. H. Grubbs J. Am. Chem. Soc. 2000 122 3783 3784
- (2000) J. Am. Chem. Soc. , vol.122 , pp. 3783-3784
- Chatterjee, A.K.¹ Morgan, J.P.² Scholl, M.³ Grubbs, R.H.⁴

88
- 0037620216
- A. Fürstner O. R. Thiel L. Ackermann H. J. Schanz S. P. Nolan J. Org. Chem. 2000 65 2204 2207
- (2000) J. Org. Chem. , vol.65 , pp. 2204-2207
- Fürstner, A.¹ Thiel, O.R.² Ackermann, L.³ Schanz, H.J.⁴ Nolan, S.P.⁵

89
- 0001683692
- A. Briot M. Bujard V. Gouverneur S. P. Nolan C. Mioskowski Org. Lett. 2000 2 1517 1519
- (2000) Org. Lett. , vol.2 , pp. 1517-1519
- Briot, A.¹ Bujard, M.² Gouverneur, V.³ Nolan, S.P.⁴ Mioskowski, C.⁵

90
- 1442360753
- Wiley-VCH, Weinheim, Germany
- R. H. Grubbs, Handbook of Metathesis, Wiley-VCH, Weinheim, Germany, 2003
- (2003) Handbook of Metathesis
- Grubbs, R.H.¹

91
- 33750595439
- For a preliminary account of this work see
- K. J. Harlow A. F. Hill J. D. E. T. Wilton-Ely J. Chem. Soc., Dalton Trans. 1999 285 291
- (1999) J. Chem. Soc., Dalton Trans. , pp. 285-291
- Harlow, K.J.¹ Hill, A.F.² Wilton-Ely, J.D.E.T.³

92
- 84943009992
- PhD Thesis, University of Texas at Austin, The deprotonation of the respective hydrogen tetrafluoroborate salts of and 2 was studied under a variety of conditions. Although the formation of 2 was not observed in solution by ¹H NMR spectroscopy, 1 was characterized by ¹H and ¹³C NMR spectroscopy despite undergoing decomposition upon concentration. See ref. 19 for additional details Although a variety of purification techniques including precipitation, trituration, and column chromatography (neutral or basic Al2O3, and SiO 2) were investigated, the isolated product appeared to readily decompose in all cases; as such, more stable derivatives were pursued
- E. L. Rosen, PhD Thesis, University of Texas at Austin, 2009
- (2009) , vol.1
- Rosen, E.L.¹

93
- 0033578944
- M. Ulman R. H. Grubbs J. Org. Chem. 1999 64 7202 7207
- (1999) J. Org. Chem. , vol.64 , pp. 7202-7207
- Ulman, M.¹ Grubbs, R.H.²

94
- 0038590297
- For recent reviews, see
- A. Fürstner J. Grabowski C. W. Lehmann J. Org. Chem. 1999 64 8275 8280
- (1999) J. Org. Chem. , vol.64 , pp. 8275-8280
- Fürstner, A.¹ Grabowski, J.² Lehmann, C.W.³

95
- 45149133673
- F. Boeda H. Clavier S. P. Nolan Chem. Commun. 2008 2726 2740
- (2008) Chem. Commun. , pp. 2726-2740
- Boeda, F.¹ Clavier, H.² Nolan, S.P.³

96
- 14744296448
- V. Dragutan I. Dragutan F. Verpoort Platinum Met. Rev. 2005 49 33 40
- (2005) Platinum Met. Rev. , vol.49 , pp. 33-40
- Dragutan, V.¹ Dragutan, I.² Verpoort, F.³

97
- 4344593824
- R. Dorta R. A. Kelly S. P. Nolan Adv. Synth. Catal. 2004 346 917 920
- (2004) Adv. Synth. Catal. , vol.346 , pp. 917-920
- Dorta, R.¹ Kelly, R.A.² Nolan, S.P.³

98
- 33751249602
- H. Clavier J. L. Petersen S. P. Nolan J. Organomet. Chem. 2006 691 5444 5477
- (2006) J. Organomet. Chem. , vol.691 , pp. 5444-5477
- Clavier, H.¹ Petersen, J.L.² Nolan, S.P.³

99
- 35048885561
- H. Clavier S. P. Nolan Chem.-Eur. J. 2007 13 8029 8036
- (2007) Chem.-Eur. J. , vol.13 , pp. 8029-8036
- Clavier, H.¹ Nolan, S.P.²

100
- 38949085170
- M. Bieniek A. Michrowska D. L. Usanov K. Grela Chem.-Eur. J. 2008 14 806 818
- (2008) Chem.-Eur. J. , vol.14 , pp. 806-818
- Bieniek, M.¹ Michrowska, A.² Usanov, D.L.³ Grela, K.⁴

101
- 57849141634
- F. Boeda X. Bantreil H. Clavier S. P. Nolan Adv. Synth. Catal. 2008 350 2959 2966
- (2008) Adv. Synth. Catal. , vol.350 , pp. 2959-2966
- Boeda, F.¹ Bantreil, X.² Clavier, H.³ Nolan, S.P.⁴

102
- 38949088658
- S. Monsaert R. Drozdzak V. Dragutan I. Dragutan F. Verpoort Eur. J. Inorg. Chem. 2008 432 440
- (2008) Eur. J. Inorg. Chem. , pp. 432-440
- Monsaert, S.¹ Drozdzak, R.² Dragutan, V.³ Dragutan, I.⁴ Verpoort, F.⁵

103
- 66149123984
- H. Clavier C. A. Urbina-Blanco S. P. Nolan Organometallics 2009 28 2848 2854
- (2009) Organometallics , vol.28 , pp. 2848-2854
- Clavier, H.¹ Urbina-Blanco, C.A.² Nolan, S.P.³

104
- 60849088567
- S. Monsaert E. D. Canck R. Drozdzak P. V. D. Voort F. Verpoort J. C. Martins P. M. S. Hendrickx Eur. J. Org. Chem. 2009 655 665
- (2009) Eur. J. Org. Chem. , pp. 655-665
- Monsaert, S.¹ Canck, E.D.² Drozdzak, R.³ Voort, P.V.D.⁴ Verpoort, F.⁵ Martins, J.C.⁶ Hendrickx, P.M.S.⁷

105
- 70349655524
- H. Clavier A. Correa E. C. Escudero-Adán J. Benet-Buchholz L. Cavallo S. P. Nolan Chem.-Eur. J. 2009 15 10244 10254
- (2009) Chem.-Eur. J. , vol.15 , pp. 10244-10254
- Clavier, H.¹ Correa, A.² Escudero-Adán, E.C.³ Benet-Buchholz, J.⁴ Cavallo, L.⁵ Nolan, S.P.⁶

106
- 77953778254
- L. H. Peeck H. Plenio Organometallics 2010 29 2761 2766
- (2010) Organometallics , vol.29 , pp. 2761-2766
- Peeck, L.H.¹ Plenio, H.²

107
- 79954443661
- C. A. Urbina-Blanco A. Leitgeb C. Slugovc X. Bantreil H. Clavier A. M. Z. Slawin S. P. Nolan Chem.-Eur. J. 2011 17 5045 5053
- (2011) Chem.-Eur. J. , vol.17 , pp. 5045-5053
- Urbina-Blanco, C.A.¹ Leitgeb, A.² Slugovc, C.³ Bantreil, X.⁴ Clavier, H.⁵ Slawin, A.M.Z.⁶ Nolan, S.P.⁷

108
- 76149101592
- H. Clavier J. Broggi S. P. Nolan Eur. J. Org. Chem. 2010 937 943
- (2010) Eur. J. Org. Chem. , pp. 937-943
- Clavier, H.¹ Broggi, J.² Nolan, S.P.³

109
- 84869070835
- X. Bantreil A. Poater C. A. Urbina-Blanco Y. D. Bidal L. Falivene R. A. M. Randall L. Cavallo A. M. Z. Slawin C. S. J. Cazin Organometallics 2012 31 7415 7426
- (2012) Organometallics , vol.31 , pp. 7415-7426
- Bantreil, X.¹ Poater, A.² Urbina-Blanco, C.A.³ Bidal, Y.D.⁴ Falivene, L.⁵ Randall, R.A.M.⁶ Cavallo, L.⁷ Slawin, A.M.Z.⁸ Cazin, C.S.J.⁹

110
- 84863090221
- The complex (10)(PCy3)Cl2Ru(2-phenylindenylid-1- ene) was found to decompose on silica gel and crystallization attempts were unsuccessful. The synthesis of (1)(PCy3)Cl2Ru(2- phenylindenylid-1-ene) has not yet been pursued in our laboratories
- C. Luján S. P. Nolan Catal. Sci. Technol. 2012 2 1027 1032
- (2012) Catal. Sci. Technol. , vol.2 , pp. 1027-1032
- Luján, C.¹ Nolan, S.P.²

111
- 0034734340
- S. B. Garber J. S. Kingsbury B. L. Gray A. H. Hoveyda J. Am. Chem. Soc. 2000 122 8168 8179
- (2000) J. Am. Chem. Soc. , vol.122 , pp. 8168-8179
- Garber, S.B.¹ Kingsbury, J.S.² Gray, B.L.³ Hoveyda, A.H.⁴

112
- 0037420362
- T. M. Trnka J. P. Morgan M. S. Sanford T. E. Wilhelm M. Scholl T.-L. Choi S. Ding M. W. Day R. H. Grubbs J. Am. Chem. Soc. 2003 125 2546 2558
- (2003) J. Am. Chem. Soc. , vol.125 , pp. 2546-2558
- Trnka, T.M.¹ Morgan, J.P.² Sanford, M.S.³ Wilhelm, T.E.⁴ Scholl, M.⁵ Choi, T.-L.⁶ Ding, S.⁷ Day, M.W.⁸ Grubbs, R.H.⁹

113
- 73649147331
- E. L. Rosen D. H. Sung Z. Chen V. M. Lynch C. W. Bielawski Organometallics 2010 29 250 256
- (2010) Organometallics , vol.29 , pp. 250-256
- Rosen, E.L.¹ Sung, D.H.² Chen, Z.³ Lynch, V.M.⁴ Bielawski, C.W.⁵

114
- 77950266144
- V. Sashuk L. H. Peeck H. Plenio Chem.-Eur. J. 2010 16 3983 3993
- (2010) Chem.-Eur. J. , vol.16 , pp. 3983-3993
- Sashuk, V.¹ Peeck, L.H.² Plenio, H.³

115
- 77955838723
- For symmetric (NHC)2Cl2RuCHPh complexes, see
- X. Bantreil R. A. M. Randall A. M. Z. Slawin S. P. Nolan Organometallics 2010 29 3007 3011
- (2010) Organometallics , vol.29 , pp. 3007-3011
- Bantreil, X.¹ Randall, R.A.M.² Slawin, A.M.Z.³ Nolan, S.P.⁴

116
- 0032476166
- T. Weskamp W. C. Schattenmann M. Spiegler W. A. Herrmann Angew. Chem., Int. Ed. 1998 37 2490 2493
- (1998) Angew. Chem., Int. Ed. , vol.37 , pp. 2490-2493
- Weskamp, T.¹ Schattenmann, W.C.² Spiegler, M.³ Herrmann, W.A.⁴

117
- 0038600733
- J. C. Conrad G. P. A. Yap D. E. Fogg Organometallics 2003 22 1986 1988
- (2003) Organometallics , vol.22 , pp. 1986-1988
- Conrad, J.C.¹ Yap, G.P.A.² Fogg, D.E.³

118
- 34347223594
- W. Zhang C. Bai X. Lu R. He J. Organomet. Chem. 2007 692 3563 3567
- (2007) J. Organomet. Chem. , vol.692 , pp. 3563-3567
- Zhang, W.¹ Bai, C.² Lu, X.³ He, R.⁴

119
- 33847282419
- N. Ledoux B. Allaert A. Linden P. Van Der Voort F. Verpoort Organometallics 2007 26 1052 1056
- (2007) Organometallics , vol.26 , pp. 1052-1056
- Ledoux, N.¹ Allaert, B.² Linden, A.³ Van Der Voort, P.⁴ Verpoort, F.⁵

120
- 0347409106
- M. B. Dinger P. Nieczypor J. C. Mol Organometallics 2003 22 5291 5296
- (2003) Organometallics , vol.22 , pp. 5291-5296
- Dinger, M.B.¹ Nieczypor, P.² Mol, J.C.³

121
- 0142088818
- W. A. Herrmann K. Öfele D. V. Preysing E. Herdtweck J. Organomet. Chem. 2003 684 235 248
- (2003) J. Organomet. Chem. , vol.684 , pp. 235-248
- Herrmann, W.A.¹ Öfele, K.² Preysing, D.V.³ Herdtweck, E.⁴

122
- 0001602606
- Angew. Chem., Int. Ed. Engl. 1996 35 1121 1123
- R. W. Alder P. R. Allen M. Murray A. G. Orpen Angew. Chem. 1996 108 1211 1213 Angew. Chem., Int. Ed. Engl. 1996 35 1121 1123
- (1996) Angew. Chem. , vol.108 , pp. 1211-1213
- Alder, R.W.¹ Allen, P.R.² Murray, M.³ Orpen, A.G.⁴

123
- 24344508137
- Angew. Chem., Int. Ed. 2004 43 5896 5911
- R. W. Alder M. E. Blake L. Chaker J. N. Harvey F. Paolini J. Schötz Angew. Chem. 2004 116 6020 6036 Angew. Chem., Int. Ed. 2004 43 5896 5911
- (2004) Angew. Chem. , vol.116 , pp. 6020-6036
- Alder, R.W.¹ Blake, M.E.² Chaker, L.³ Harvey, J.N.⁴ Paolini, F.⁵ Schötz, J.⁶

124
- 36749049684
- See ESI for deprotonation conditions and corresponding ¹H NMR data
- E. L. Rosen M. D. Sanderson S. Saravanakumar C. W. Bielawski Organometallics 2007 26 5774 5777
- (2007) Organometallics , vol.26 , pp. 5774-5777
- Rosen, E.L.¹ Sanderson, M.D.² Saravanakumar, S.³ Bielawski, C.W.⁴

125
- 77955803280
- M. S. Collins E. L. Rosen V. M. Lynch C. W. Bielawski Organometallics 2010 29 3047 3053
- (2010) Organometallics , vol.29 , pp. 3047-3053
- Collins, M.S.¹ Rosen, E.L.² Lynch, V.M.³ Bielawski, C.W.⁴

126
- 69249161723
- A. Binobaid M. Iglesias D. J. Beetstra B. Kariuki A. Dervisi A. A. Fallis K. J. Cavell Dalton Trans. 2009 7099 7112
- (2009) Dalton Trans. , pp. 7099-7112
- Binobaid, A.¹ Iglesias, M.² Beetstra, D.J.³ Kariuki, B.⁴ Dervisi, A.⁵ Fallis, A.A.⁶ Cavell, K.J.⁷

127
- 34748830314
- Parameters used for the calculation of %VBur were as follows: 3.5 Å sphere radius, 2.10 Å distance from the center of the sphere, and Bondii radii scaled by 1.17. In addition to removing the coordinates of the ligands and the coordinated Ir from the cif file prior to the calculation of the %VBur, we found it necessary to remove the coordinates of the Fe atom. See
- M. Iglesias D. J. Beetstra A. Stasch P. N. Horton M. B. Hursthouse S. J. Coles K. J. Cavell A. Dervisi I. A. Fallis Organometallics 2007 26 4800 4809
- (2007) Organometallics , vol.26 , pp. 4800-4809
- Iglesias, M.¹ Beetstra, D.J.² Stasch, A.³ Horton, P.N.⁴ Hursthouse, M.B.⁵ Coles, S.J.⁶ Cavell, K.J.⁷ Dervisi, A.⁸ Fallis, I.A.⁹

128
- 66149192545
- A. Poater B. Cosenza A. Correa S. Giudice F. Ragone V. Scarano L. Cavallo Eur. J. Inorg. Chem. 2009 1759 1766
- (2009) Eur. J. Inorg. Chem. , pp. 1759-1766
- Poater, A.¹ Cosenza, B.² Correa, A.³ Giudice, S.⁴ Ragone, F.⁵ Scarano, V.⁶ Cavallo, L.⁷

129
- 67650453812
- A. G. Tennyson E. L. Rosen M. S. Collins V. M. Lynch C. W. Bielawski Inorg. Chem. 2009 48 6924 6933
- (2009) Inorg. Chem. , vol.48 , pp. 6924-6933
- Tennyson, A.G.¹ Rosen, E.L.² Collins, M.S.³ Lynch, V.M.⁴ Bielawski, C.W.⁵

130
- 73949132408
- A. G. Tennyson R. J. Ono T. W. Hudnall D. M. Khramov J. A. V. Er J. W. Kamplain V. M. Lynch J. L. Sessler C. W. Bielawski Chem.-Eur. J. 2010 16 304 305
- (2010) Chem.-Eur. J. , vol.16 , pp. 304-305
- Tennyson, A.G.¹ Ono, R.J.² Hudnall, T.W.³ Khramov, D.M.⁴ Er, J.A.V.⁵ Kamplain, J.W.⁶ Lynch, V.M.⁷ Sessler, J.L.⁸ Bielawski, C.W.⁹

131
- 79955556127
- R. J. Ono Y. Suzuki D. M. Khramov M. Ueda J. L. Sessler C. W. Bielawski J. Org. Chem. 2011 76 3239 3245
- (2011) J. Org. Chem. , vol.76 , pp. 3239-3245
- Ono, R.J.¹ Suzuki, Y.² Khramov, D.M.³ Ueda, M.⁴ Sessler, J.L.⁵ Bielawski, C.W.⁶

132
- 11644311048
- TEP = 0.847[νCO(average)] + 336 cm^-1 The rates of RCM reactions catalyzed by Grubbs 2^nd generation type catalysts increase with the electron donating ability of the NHC ligand, see
- C. A. Tolman Chem. Rev. 1977 77 313 348
- (1977) Chem. Rev. , vol.77 , pp. 313-348
- Tolman, C.A.¹

133
- 53849139133
- For a more recent study, see
- S. Leuthäußer V. Schmidts C. M. Thiele H. Plenio Chem.-Eur. J. 2008 14 5465 5481
- (2008) Chem.-Eur. J. , vol.14 , pp. 5465-5481
- Leuthäußer, S.¹ Schmidts, V.² Thiele, C.M.³ Plenio, H.⁴

134
- 84877252061
- The effect of varying NHC backbone electronics on the performance of Grubbs 2^nd generation type indenylidene complexes has also been explored, see
- Y. Borguet G. Zaragoza A. Demonceau L. Delaude Dalton Trans. 2013 42 7287 7296
- (2013) Dalton Trans. , vol.42 , pp. 7287-7296
- Borguet, Y.¹ Zaragoza, G.² Demonceau, A.³ Delaude, L.⁴

135
- 78751518951
- We also synthesized and fully characterized complexes of the type (FcDAC)(PCy3)Cl2RuCHPh and (FcDAC)(SIMes)Cl 2RuCHPh (SIMes = 1,3-dimesitylimidazolinylidene) but did not study these catalysts for their redox-switchable properties, see the ESI. Conditions which favored the formation of exclusively one product could not be found. After extended reaction times (12 h) at ambient temperature, the final molar ratio of 17 to 18 was approximately 1:5 It has been previously reported that the purification of Ru benzylidene complexes using column chromatography on silica gel may cause rearrangements to occur, although the isomerization of 17 → 18 was observed prior to purification. See
- C. A. Urbina-Blanco X. Bantreil H. Clavier A. M. Slawin S. P. Nolan Beilstein J. Org. Chem. 2010 6 1120 1126
- (2010) Beilstein J. Org. Chem. , vol.6 , pp. 1120-1126
- Urbina-Blanco, C.A.¹ Bantreil, X.² Clavier, H.³ Slawin, A.M.⁴ Nolan, S.P.⁵

136
- 0942299066
- S. Prühs C. W. Lehmann A. Fürstner Organometallics 2004 23 280 287
- (2004) Organometallics , vol.23 , pp. 280-287
- Prühs, S.¹ Lehmann, C.W.² Fürstner, A.³

137
- 3342933323
- C. Slugovc B. Perner F. Stelzer K. Mereiter Organometallics 2004 23 3622 3626
- (2004) Organometallics , vol.23 , pp. 3622-3626
- Slugovc, C.¹ Perner, B.² Stelzer, F.³ Mereiter, K.⁴

138
- 33845273839
- T. Ritter A. Hejl A. G. Wenzel T. W. Funk R. H. Grubbs Organometallics 2006 25 5740 5745
- (2006) Organometallics , vol.25 , pp. 5740-5745
- Ritter, T.¹ Hejl, A.² Wenzel, A.G.³ Funk, T.W.⁴ Grubbs, R.H.⁵

139
- 0001557439
- N. D. Jones M. O. Wolf Organometallics 1997 16 1352 1354
- (1997) Organometallics , vol.16 , pp. 1352-1354
- Jones, N.D.¹ Wolf, M.O.²

140
- 0035809274
- K. R. J. Thomas J. T. Lin H.-M. Lin C.-P. Chang C.-H. Chuen Organometallics 2001 20 557 563
- (2001) Organometallics , vol.20 , pp. 557-563
- Thomas, K.R.J.¹ Lin, J.T.² Lin, H.-M.³ Chang, C.-P.⁴ Chuen, C.-H.⁵

141
- 13444274577
- T. K. Maishal B. Mondal V. G. Puranik P. P. Wadgaonkar G. K. Lahiri A. Sarkar J. Organomet. Chem. 2005 690 1018 1027
- (2005) J. Organomet. Chem. , vol.690 , pp. 1018-1027
- Maishal, T.K.¹ Mondal, B.² Puranik, V.G.³ Wadgaonkar, P.P.⁴ Lahiri, G.K.⁵ Sarkar, A.⁶

142
- 28044469657
- M. Süßner H. Plenio Chem. Commun. 2005 5417 5419
- (2005) Chem. Commun. , pp. 5417-5419
- Süßner, M.¹ Plenio, H.²

143
- 0000951398
- S. K. Pal K. Alagesan A. G. Samuelson J. Pebler J. Organomet. Chem. 1999 575 108 118
- (1999) J. Organomet. Chem. , vol.575 , pp. 108-118
- Pal, S.K.¹ Alagesan, K.² Samuelson, A.G.³ Pebler, J.⁴

144
- 0040695037
- J. S. Miller P. J. Krusic D. A. Dixon W. M. Reif J. H. Zhang E. C. Anderson A. J. Epstein J. Am. Chem. Soc. 1986 108 4459 4466
- (1986) J. Am. Chem. Soc. , vol.108 , pp. 4459-4466
- Miller, J.S.¹ Krusic, P.J.² Dixon, D.A.³ Reif, W.M.⁴ Zhang, J.H.⁵ Anderson, E.C.⁶ Epstein, A.J.⁷

145
- 0001344650
- V. J. Murphy D. O'Hare Inorg. Chem. 1994 33 1833 1841
- (1994) Inorg. Chem. , vol.33 , pp. 1833-1841
- Murphy, V.J.¹ O'Hare, D.²

146
- 7044260459
- The use of stronger oxidants such as silver salts, [NO][BF4], and [Ac2Fc][BF4] were also explored, but resulted in premature decomposition
- H. M. A. Salman M. R. Mahmoud M. H. M. Abou-El-Wafa U. M. Rabie R. H. Crabtree Inorg. Chem. Commun. 2004 7 1209 1212
- (2004) Inorg. Chem. Commun. , vol.7 , pp. 1209-1212
- Salman, H.M.A.¹ Mahmoud, M.R.² Abou-El-Wafa, M.H.M.³ Rabie, U.M.⁴ Crabtree, R.H.⁵

147
- 0003482420
- Elsevier, Amsterdam, 2nd edn
- A. B. P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 2nd edn, 1984
- (1984) Inorganic Electronic Spectroscopy
- Lever, A.B.P.¹

148
- 37049131721
- Although oxidation of the Ru and the Fe centers in were reversible (as determined from a scan-rate dependency study; see Fig. S9), the neutral complex was found to decompose in solution over time. As the extinction coefficient for the ferrocenium LCMT transition is relatively low (ε < 1000 M ^-1 cm^-1), the oxidized complex 18+ could not be formed in high enough concentration to be observed due to the competing decomposition of the starting material over the 30 min time scale of the experiment
- R. Prins J. Chem. Soc., Chem. Commun. 1970 280 281
- (1970) J. Chem. Soc., Chem. Commun. , vol.18 , pp. 280-281
- Prins, R.¹

149
- 0037347136
- S. Hartmann R. F. Winter B. M. Brunner B. Sarkar A. Knödler I. Hartenbach Eur. J. Inorg. Chem. 2003 876 891
- (2003) Eur. J. Inorg. Chem. , pp. 876-891
- Hartmann, S.¹ Winter, R.F.² Brunner, B.M.³ Sarkar, B.⁴ Knödler, A.⁵ Hartenbach, I.⁶

150
- 23844433929
- N. Das A. M. Arif P. Stang Inorg. Chem. 2005 44 5798 5804
- (2005) Inorg. Chem. , vol.44 , pp. 5798-5804
- Das, N.¹ Arif, A.M.² Stang, P.³

151
- 0035803655
- W. Kaim T. Sixt M. Weber J. Fiedler J. Organomet. Chem. 2001 637 167 171
- (2001) J. Organomet. Chem. , vol.637 , pp. 167-171
- Kaim, W.¹ Sixt, T.² Weber, M.³ Fiedler, J.⁴

152
- 33947293342
- H. B. Gray Y. S. Sohn D. N. Hendrickson J. Am. Chem. Soc. 1971 93 3603 3612
- (1971) J. Am. Chem. Soc. , vol.93 , pp. 3603-3612
- Gray, H.B.¹ Sohn, Y.S.² Hendrickson, D.N.³

153
- 0000211667
- C. Elschenbrolch E. Bilger Organometallics 1985 4 2068 2071
- (1985) Organometallics , vol.4 , pp. 2068-2071
- Elschenbrolch, C.¹ Bilger, E.²

154
- 0033834773
- T. Sixt J. Fiedler W. Kaim Inorg. Chem. Commun. 2000 3 80 82
- (2000) Inorg. Chem. Commun. , vol.3 , pp. 80-82
- Sixt, T.¹ Fiedler, J.² Kaim, W.³

155
- 0000853867
- R. F. Winter F. M. Hornung Organometallics 1999 18 4005 4014
- (1999) Organometallics , vol.18 , pp. 4005-4014
- Winter, R.F.¹ Hornung, F.M.²

156
- 39749091147
- T. Kojima D. Noguchi T. Nakayama Y. Inagaki Y. Shiota K. Yoshizawa K. Ohkubo S. Fukuzumi Inorg. Chem. 2008 47 886 895
- (2008) Inorg. Chem. , vol.47 , pp. 886-895
- Kojima, T.¹ Noguchi, D.² Nakayama, T.³ Inagaki, Y.⁴ Shiota, Y.⁵ Yoshizawa, K.⁶ Ohkubo, K.⁷ Fukuzumi, S.⁸

157
- 0001678850
- Complex 18 displayed limited solubility in non-polar solvents, including toluene and benzene It was determined that the use of four equivalents of DDQ was necessary to significantly affect the rate of polymerization, which may be attributed to slow electron-transfer kinetics under the conditions studied
- I. Noviandri K. N. Brown D. S. Fleming P. T. Gulyas P. A. Lay A. F. Masters L. Phillips J. Phys. Chem. B 1999 103 6713 6722
- (1999) J. Phys. Chem. B , vol.103 , pp. 6713-6722
- Noviandri, I.¹ Brown, K.N.² Fleming, D.S.³ Gulyas, P.T.⁴ Lay, P.A.⁵ Masters, A.F.⁶ Phillips, L.⁷

158
- 0030660076
- W. A. Herrmann C. Köcher Angew. Chem., Int. Ed. Engl. 1997 36 2163 2187
- (1997) Angew. Chem., Int. Ed. Engl. , vol.36 , pp. 2163-2187
- Herrmann, W.A.¹ Köcher, C.²

159
- 33745688099
- Springer-Verlag, Berlin, Germany
- N-Heterocyclic Carbenes in Transition Metal Catalysis, ed., F. Glorius, Springer-Verlag, Berlin, Germany, 2007
- (2007) N-Heterocyclic Carbenes in Transition Metal Catalysis
- Glorius, F.¹

160
- 36849065859
- Wiley-VCH, Weinheim
- N-Heterocyclic Carbenes in Synthesis, ed., S. P. Nolan, Wiley-VCH, Weinheim, 2006
- (2006) N-Heterocyclic Carbenes in Synthesis
- Nolan, S.P.¹

161
- 0035843056
- 1,1′-Diformamidoferrocene (10) has been previously prepared in situ and used without additional characterization; see
- M. S. Sanford J. A. Love R. H. Grubbs Organometallics 2001 20 5314 5318
- (2001) Organometallics , vol.20 , pp. 5314-5318
- Sanford, M.S.¹ Love, J.A.² Grubbs, R.H.³

162
- 0035121206
- The NMR data recorded for this compound are complex and similar to those reported for the monoformamide of ferrocene; see
- D. Leusen B. Hessen Organometallics 2001 20 224 226
- (2001) Organometallics , vol.20 , pp. 224-226
- Leusen, D.¹ Hessen, B.²

163
- 0025388180
- G. R. Knox P. L. Pauson D. Willison Organometallics 1990 9 301 306
- (1990) Organometallics , vol.9 , pp. 301-306
- Knox, G.R.¹ Pauson, P.L.² Willison, D.³

164
- 0034683268
- A. Shafir M. P. Power G. D. Whitener J. Arnold Organometallics 2000 19 3978 3982
- (2000) Organometallics , vol.19 , pp. 3978-3982
- Shafir, A.¹ Power, M.P.² Whitener, G.D.³ Arnold, J.⁴

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