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Volumn 60, Issue 34, 2004, Pages 7117-7140

Olefin metathesis

Author keywords

Carbene; Olefin metathesis; Polymerization

Indexed keywords

ALKENE; POLYMER; RUTHENIUM;

EID: 3343012187     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2004.05.124     Document Type: Conference Paper
Times cited : (1323)

References (106)
  • 3
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    • This is intended to be a personal account and reference will be made to that work that had a major influence on the progress of the research in my group and I apologize for any omissions. A few of the high-light papers that impacted the development of metathesis catalysts in our group will be discussed. I wish to thank the over 200 researchers who have contributed to my work over the years. The major emphasis will be on the path of catalyst development
    • This is intended to be a personal account and reference will be made to that work that had a major influence on the progress of the research in my group and I apologize for any omissions. A few of the high-light papers that impacted the development of metathesis catalysts in our group will be discussed. I wish to thank the over 200 researchers who have contributed to my work over the years. The major emphasis will be on the path of catalyst development
  • 7
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    • An out growth of our work with metallacyclopentanes lead to the detailed study of metallacyclopentanes of nickel and platinum by Professor Akira Miyashita, deceased November 2003
    • An out growth of our work with metallacyclopentanes lead to the detailed study of metallacyclopentanes of nickel and platinum by Professor Akira Miyashita, deceased November 2003 Grubbs R.H., Miyashita A., Liu M., Burk P. J. Am. Chem. Soc. 99:1977;3863
    • (1977) J. Am. Chem. Soc. , vol.99 , pp. 3863
    • Grubbs, R.H.1    Miyashita, A.2    Liu, M.3    Burk, P.4
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    • By measuring the cross over products as a function of time, the ratio of products could be obtained at zero time. In this publication, the mechanism for acetylene metathesis was also proposed
    • Katz T.J., McGinnis J. J. Am. Chem. Soc. 97:1975;1592-1594. By measuring the cross over products as a function of time, the ratio of products could be obtained at zero time. In this publication, the mechanism for acetylene metathesis was also proposed
    • (1975) J. Am. Chem. Soc. , vol.97 , pp. 1592-1594
    • Katz, T.J.1    McGinnis, J.2
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    • A footnote to the paper in Ref. 10 above was added in proof to this paper
    • Grubbs R.H., Burk P.L., Carr D.D. J. Am. Chem. Soc. 97:1975;3265. A footnote to the paper in Ref. 10 above was added in proof to this paper
    • (1975) J. Am. Chem. Soc. , vol.97 , pp. 3265
    • Grubbs, R.H.1    Burk, P.L.2    Carr, D.D.3
  • 18
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    • Alkoxide substitution on the systems converted a number of the early halide complexes into active metathesis catalysts
    • Schrock R.R. Acc. Chem. Res. 12:1979;98-104. Alkoxide substitution on the systems converted a number of the early halide complexes into active metathesis catalysts
    • (1979) Acc. Chem. Res. , vol.12 , pp. 98-104
    • Schrock, R.R.1
  • 41
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    • Diphenylcyclopropene would be an important reagent later in our development of the ruthenium based catalysts. My involvement with arylcyclopropenes goes back to my Master's research with Merle Battiste at the University of Florida
    • Diphenylcyclopropene would be an important reagent later in our development of the ruthenium based catalysts. My involvement with arylcyclopropenes goes back to my Master's research with Merle Battiste at the University of Florida
  • 53
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    • See for early demonstrations of ring closing metathesis using 'classical' catalysts
    • See for early demonstrations of ring closing metathesis using 'classical' catalysts Villemin D. Tetrahedron Lett. 1980;1715
    • (1980) Tetrahedron Lett. , pp. 1715
    • Villemin, D.1
  • 62
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    • Demonstrated that ruthenium(II) salts mixed with diazo alkanes would yield metathesis products in the presence of tricyclohexylphosphine
    • Demonceau A., Noels A.F., Saive E., Hubert A.J. J. Mol. Catal. 776:1992;123-132. Demonstrated that ruthenium(II) salts mixed with diazo alkanes would yield metathesis products in the presence of tricyclohexylphosphine
    • (1992) J. Mol. Catal. , vol.776 , pp. 123-132
    • Demonceau, A.1    Noels, A.F.2    Saive, E.3    Hubert, A.J.4
  • 66
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    • Charles Woodson started Advanced Polymer Technologies (now Cymetech) to develop ruthenium based polyDCPD technology. Commercial products are now being marketed based on this technology
    • Charles Woodson started Advanced Polymer Technologies (now Cymetech) to develop ruthenium based polyDCPD technology. Commercial products are now being marketed based on this technology
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    • R.H. Grubbs. New York: Wiley-VCH. Chapter 2.14
    • Grubbs R.H. Handbook of Metathesis. 2003;214 Wiley-VCH, New York. Chapter 2.14
    • (2003) Handbook of Metathesis , pp. 214
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    • Ref. 52, Chapter 3.12. For example a polymer reinforced baseball bat is being marketed by Easton Sports
    • Ref. 52, Chapter 3.12. For example a polymer reinforced baseball bat is being marketed by Easton Sports
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    • It is interesting that the earliest demonstration of a 'carbene' metathesis mechanism was by M.F. Lappert using N-heterocyclic carbenes. He also demonstrated that NHC's were ligands that showed many of the same features as phosphines
    • It is interesting that the earliest demonstration of a 'carbene' metathesis mechanism was by M.F. Lappert using N-heterocyclic carbenes Cardin D.J., Doyle M.J., Lappert M.F. Chem. Commun. 16:1972;927. He also demonstrated that NHC's were ligands that showed many of the same features as phosphines
    • (1972) Chem. Commun. , vol.16 , pp. 927
    • Cardin, D.J.1    Doyle, M.J.2    Lappert, M.F.3
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    • note
    • Ref. 47, Chapter 3.12.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.