Adamantyl-Substituted N-Heterocyclic Carbene Ligands in Second-Generation Grubbs-Type Metathesis Catalysts

Organometallics

Volumn 22, Issue 25, 2003, Pages 5291-5296

  Dinger, Maarten B ^a   Nieczypor, Piotr ^a   Mol, Johannes C ^a  

^a UNIVERSITY OF AMSTERDAM   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

MATATHESIS ACTIVITY; STERIC EFFECTS; X-RAY STRUCTURES;

CATALYSIS; CATALYST ACTIVITY; CHEMICAL BONDS; COMPLEXATION; ISOMERS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; REDUCTION; SINGLE CRYSTALS; STOICHIOMETRY; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL); THERMAL EFFECTS; X RAY CRYSTALLOGRAPHY; X RAY SPECTROSCOPY;

ORGANIC COMPOUNDS;

EID: 0347409106     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om034062k     Document Type: Article

References (38)

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28. When glyoxal was reacted with 2 equiv of 1-adamantamine, an intractable white precipitate formed that we were unable to characterize due to its poor solubility. This material did not reduce to N,N′-die(1-adamantyl)ethane-1,2-diamine (Ic) on treatment with sodium borohydride.
29. When glyoxal was reacted with 2 equiv of 1-adamantamine, an intractable white precipitate formed that we were unable to characterize due to its poor solubility. This material did not reduce to N,N′-die(1-adamantyl)ethane-1,2-diamine (Ic) on treatment with sodium borohydride.
30. NHC ligands on the second-generation Grubbs metathesis catalysts generally cannot rotate.
31. Obtained from supplementary crystallographic data CCDC-161995, courtesy of Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK.
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