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Considerable decomposition takes place at temperatures above 60°C such that temperature dependent quantification of rotation rates could not be performed.
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III isomers is governed by the difference of the respective redox potentials according to InK = zF/RT · ΔE. For ΔE = 219 mV the cathodic isomer is formed in >99% yield.
-
III isomers is governed by the difference of the respective redox potentials according to InK = zF/RT · ΔE. For ΔE = 219 mV the cathodic isomer is formed in >99% yield.
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Exchange-mediated ROE (or vice versa) can be excluded due to different temperature dependence see Figure S4
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Exchange-mediated ROE (or vice versa) can be excluded due to different temperature dependence (see Figure S4, Supporting Information).
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Supporting Information)
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